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The massive field theory approach in fixed space dimensions $d=3$ is applied to investigate a dilute solution of long-flexible polymer chains in a good solvent between two parallel repulsive walls, two inert walls and for the mixed case of…

软凝聚态物质 · 物理学 2009-10-08 D. Romeis , Z. Usatenko

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

软凝聚态物质 · 物理学 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

We develop a statistical model for a confined chain molecule based on a monomer grand canonical ensemble. The molecule is subject to an external chemical potential, a backbone interaction, and an attractive interaction between all monomers.…

统计力学 · 物理学 2015-05-13 S. Pasquali , J. K. Percus

The process of adsorption on a planar repulsive, "marginal" and attractive wall of long-flexible polymer chains with excluded volume interactions is investigated. The performed scaling analysis is based on formal analogy between the polymer…

软凝聚态物质 · 物理学 2009-10-08 Z. Usatenko

The depletion interaction between two parallel repulsive walls confining a dilute solution of long and flexible polymer chains is studied by field-theoretic methods. Special attention is paid to self-avoidance between chain monomers…

软凝聚态物质 · 物理学 2009-11-07 F. Schlesener , A. Hanke , R. Klimpel , S. Dietrich

The number of allowed configurations of a polymer is reduced by the presence of a repulsive surface resulting in an entropic force between them. We develop a method to calculate the entropic force, and detailed pressure distribution, for…

统计力学 · 物理学 2014-02-11 Yosi Hammer , Yacov Kantor

Taking into account the well known correspondence between the field theoretical O(n)-vector model in the limit $n\to 0$ and the behavior of long-flexible polymer chains in a good solvent the investigation of ideal polymer chains adsorption…

软凝聚态物质 · 物理学 2012-09-25 Zoryana Usatenko

Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…

软凝聚态物质 · 物理学 2016-05-25 Sergei A. Egorov , Andrey Milchev , Peter Virnau , Kurt Binder

Polymer networks formed by cross linking flexible polymer chains are ubiquitous in many natural and synthetic soft-matter systems. Current micromechanics models generally do not account for excluded volume interactions except, for instance,…

软凝聚态物质 · 物理学 2023-06-05 Pratik Khandagale , Timothy Breitzman , Carmel Majidi , Kaushik Dayal

We study the universal characteristics of the shape of a polymer chain in an environment with correlated structural obstacles, applying the field-theoretical renormalization group approach. Our results qualitatively indicate an increase of…

软凝聚态物质 · 物理学 2010-06-03 Viktoria Blavatska , Christian von Ferber , Yurij Holovatch

We consider a fully directed self-avoiding walk model on a cubic lattice to mimic the conformations of an infinitely long confined flexible polymer chain; and the confinement condition is achieved by two parallel athermal plates. The…

软凝聚态物质 · 物理学 2021-06-21 P K Mishra

We consider the complex polymer system, consisting of ring polymer connected to the $f_1$-branched star-like structure, in good solvent in presence of structural inhomogeneities. We assume, that structural defects are correlated at large…

软凝聚态物质 · 物理学 2018-03-14 K. Haydukivska , V. Blavatska

Using molecular dynamics simulation of a standard bead-spring model we investigate the density crossover scaling of strictly two-dimensional self-avoiding polymer chains focusing on properties related to the contact exponent set by the…

软凝聚态物质 · 物理学 2015-06-03 N. Schulmann , H. Meyer , J. P. Wittmer , A. Johner , J. Baschnagel

We consider the lattice model for an ideal-linear polymer chain to mimic the conformations of the semi-flexible homo-polymer chain. The polymer chain is assumed to confine in the fairly small area, such that the flexible chain conformations…

软凝聚态物质 · 物理学 2020-10-23 Pramod Kumar Mishra

We consider the properties of a self-avoiding polymer chain, adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a…

软凝聚态物质 · 物理学 2009-04-01 S. Bhattacharya , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

We present results of Monte Carlo study of the monomer-monomer correlation functions, static structure factor and asphericity characteristics of a single homopolymer in the coil and globular states for three distinct architectures of the…

软凝聚态物质 · 物理学 2009-11-07 Edward G. Timoshenko , Yuri A. Kuznetsov , Ronan Connolly

In this paper, we show how the method of field theoretical renormalization group may be used to analyze universal shape properties of long polymer chains in porous environment. So far such analytical calculations were primarily focussed on…

软凝聚态物质 · 物理学 2012-02-22 V. Blavatska , C. von Ferber , Yu. Holovatch

The absorption of free linear chains in a polymer brush was studied with respect to chain size $L$ and compatibility $\chi$ with the brush by means of Monte Carlo (MC) simulations and Density Functional Theory (DFT) / Self-Consistent Field…

软凝聚态物质 · 物理学 2015-05-18 A. Milchev , S. A. Egorov , K. Binder

In this paper we study the shape characteristics of a polymer chain in a good solvent using a mesoscopic level of modelling. The dissipative particle dynamics simulations are performed in the $3D$ space at a range of chain lengths $N$. The…

软凝聚态物质 · 物理学 2016-11-24 Ostap Kalyuzhnyi , Jaroslav Ilnytskyi , Yurij Holovatch , Christian von Ferber

Single two dimensional polymers confined to a strip are studied by Monte Carlo simulations. They are described by N-step self-avoiding random walks on a square lattice between two parallel hard walls with distance 1 << D << N^\nu (\nu = 3/4…

软凝聚态物质 · 物理学 2007-05-23 Hsiao-Ping Hsu , Peter Grassberger
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