相关论文: Damage in porous media due to salt crystallization
Humid hydrophobic ionic liquids, widely used as electrolytes, have narrowed electrochemical windows, because their water, absorbed on the electrode surface, gets involved in electrolysis. In this work, we performed molecular dynamics…
We study channelization and slope destabilization driven by subsurface (groundwater) flow in a laboratory experiment. The pressure of the water entering the sandpile from below as well as the slope of the sandpile are varied. We present…
The most abundant matrix minerals in chondritic meteorites, hydrated phyllosilicates and ferrous olivine crystals, formed predominantly in asteroids during fluid-assisted metamorphism. We infer that they formed from minerals present in…
We calculate the interaction potential between two colloids immersed in an aqueous mixture containing salt near or above the critical temperature. We find an attractive interaction far from the coexistence curve due to the combination of…
Solvation of ions is ubiquitous on our planet. Solvated ions have a profound effect on the behavior of ionic solutions, which is crucial in nature and technology. Experimentally, ions have been classified into "structure makers" or…
Although clays are crucial mineral phases in Earth's weathering engine, it is unclear how they form in surface environments under (near-)ambient pressures and temperature. Most synthesis routes, attempting to give insights into the…
A drop of aqueous potato starch gel with a certain mole fraction of NaCl, when dried on a glass slide, exhibits strong segregation and intricate pattern formation phenomena. The salt forms radial dendritic crystalline aggregates near the…
In this paper droplet evaporative crystallization of salicylic acid (SA) and acetylsalicylic acid (ASA) crystals on different surfaces, such as glass, polyvinyl alcohol (PVA), and paraffin was studied. The obtained crystals were analyzed…
Antagonistic salts are salts which consist of hydrophilic and hydrophobic ions. In a binary mixture of water and organic solvent, these ions preferentially dissolve into different phases. We investigate the effect of an antagonistic salt,…
Water inherently contains trace amounts of various salts, yet the microscopic processes by which salts influence some of its physical properties remain elusive. Notably, the mechanisms that reduce the dielectric constant of water upon salt…
CaSO4 minerals (i.e. gypsum, anhydrite and bassanite) are widespread in natural and industrial environments. During the last several years, a number of studies have revealed that nucleation in the CaSO4-H2O system is non-classical, where…
We study the Soret effect of charged polystyrene particles as a function of temperature and electrolyte composition. As a main result we find that the Soret coefficient is determined by charge effects, and that non-ionic contributions are…
Erosion and deposition during flow through porous media can lead to large erosive bursts that manifest as jumps in permeability and pressure loss. Here we reveal that the cause of these bursts is the re-opening of clogged pores when the…
The key kinetic barrier to dolomite formation is related to the surface Mg2+-H2O complex, which hinders binding of surface Mg2+ ions to the CO3 2- ions in solution. It has been proposed that this reaction can be catalyzed by dissolved…
In an externally imposed electrolyte (salt) concentration gradient, charged colloids drift at speeds of order one micrometre per second. This phenomenon is known as diffusiophoresis. In systems with multiple salts and 'crossed' salt…
In this work, we use large-scale molecular dynamics simulations coupled to free energy calculations to identify for the first time a limit of stability (spinodal) and a change in the nucleation mechanism in aqueous NaCl solutions. This is a…
The effect of added salt on the propulsion of Janus platinum-polystyrene colloids in hydrogen peroxide solution is studied experimentally. It is found that micromolar quantities of potassium and silver nitrate salts reduce the swimming…
We study the trapping of charged particles and macromolecules (such as DNA) in salt gradients in aqueous solutions. The source for the salt gradient can be as simple as a dissolving ionic crystal, as shown by McDermott et al. [Langmuir 28,…
Historical monuments, outdoor stone sculptures and artworks made of porous materials are exposed to chemical and physical degradation over time. Presently, the most promising route for consolidation of weakened porous materials is the…
We present a study of patterns, formed in drying drops of aqueous gelatin solution containing sodium sulphate. The patterns are highly complex, consisting of a hierarchical sequence of rings which form concentric bands as well as dendritic…