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We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on…

统计力学 · 物理学 2015-05-13 A. Andreanov , G. Biroli , J. -P. Bouchaud

Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression,…

统计力学 · 物理学 2018-10-03 Liesbeth M. C. Janssen

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

软凝聚态物质 · 物理学 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates

Many qualitative observations on the glass transition in classical fluids are well described by the mode coupling theory (MCT) but the extent of the non-ergodicity domain is often over-estimated by this theory. Making it more quantitative…

统计力学 · 物理学 2012-10-04 S. Amokrane , F. Tchangnwa Nya , J. M. Ndjaka

Mode coupling theory (MCT) has been successful in explaining the observed sequence of time relaxations in dense fluids. Previous expositions of this theory showing this sequence have required the existence of an ideal glass transition…

凝聚态物理 · 物理学 2009-10-22 Gene F. Mazenko , Joonhyun Yeo

The mode-coupling theory of the glass transition (MCT) has been at the forefront of fundamental glass research for decades, yet the theory's underlying approximations remain obscure. Here we quantify and critically assess the effect of each…

统计力学 · 物理学 2023-11-29 I. Pihlajamaa , V. E. Debets , C. C. L. Laudicina , L. M. C. Janssen

We consider the Mode Coupling Theory (MCT) of Glass transition for a Binary fluid. The Equations of Nonlinear Fluctuating Hydrodynamics are obtained with a proper choice of the slow variables corresponding to the conservation laws. The…

统计力学 · 物理学 2009-11-07 Upendra Harbola , Shankar P. Das

We present mode-coupling equations for the description of the slow dynamics observed in supercooled molecular liquids close to the glass transition. The mode-coupling theory (MCT) originally formulated to study the slow relaxation in simple…

软凝聚态物质 · 物理学 2009-10-31 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

The mode-coupling theory (MCT) of the glass transition ranks among the most successful first-principles kinetic theories to describe glassy dynamics. However, MCT does not fully account for crucial aspects of the dynamics near the glass…

软凝聚态物质 · 物理学 2024-08-22 Ilian Pihlajamaa , Liesbeth M. C. Janssen

In this set of lecture notes we review the mode-coupling theory of the glass transition from several perspectives. First, we derive mode-coupling equations for the description of density fluctuations from microscopic considerations with the…

软凝聚态物质 · 物理学 2010-04-16 David R. Reichman , Patrick Charbonneau

Mode coupling theory (MCT) appears to explain several, though not all, aspects of the glass transition in colloids (particularly when short-range attractions are present). Developments of MCT, from rational foundations in statistical…

软凝聚态物质 · 物理学 2007-05-23 M. E. Cates , C. B. Holmes , M. Fuchs , O. Henrich

We show that the glass transition predicted by the Mode-Coupling Theory (MCT) is a critical phenomenon with a diverging length and time scale associated to the cooperativity of the dynamics. We obtain the scaling exponents nu and z that…

统计力学 · 物理学 2009-11-10 Giulio Biroli , Jean-Philippe Bouchaud

Mode-coupling theory (MCT) constitutes one of the few first-principles-based approaches to describe the physics of the glass transition, but the theory's inherent approximations compromise its accuracy in the activated glassy regime. Here…

统计力学 · 物理学 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

The predictions of the mode-coupling theory of the glass transition (MCT) for the tagged-particle density-correlation functions and the mean-squared displacement curves are compared quantitatively and in detail to results from Newtonian-…

统计力学 · 物理学 2009-11-10 Th. Voigtmann , A. M. Puertas , M. Fuchs

Often the current mode coupling theory (MCT) of glass transitions is compared with mean field theories. We explore this possible correspondence. After showing a simple-minded derivation of MCT with some difficulties we give a concise…

统计力学 · 物理学 2009-11-07 Kyozi Kawasaki , Bongsoo Kim

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

统计力学 · 物理学 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

We present mode-coupling theory (MCT) results for densely packed hard-sphere fluids confined between two parallel walls and compare them quantitatively to computer simulations. The numerical solution of MCT is calculated for the first time…

软凝聚态物质 · 物理学 2023-05-10 Gerhard Jung , Thomas Franosch

We analyze the glassy dynamics of a binary mixtures of hard disks in two dimensions. Predictions of the Mode-Coupling theory(MCT) are tested with extensive Brownian dynamics simulations. Measuring the collective particle density correlation…

软凝聚态物质 · 物理学 2011-04-27 Fabian Weysser , David Hajnal

The emergence of glassy dynamics and the glass transition in dense disordered systems is still not fully understood theoretically. Mode-coupling theory (MCT) has shown to be effective in describing some of the non-trivial features of glass…

软凝聚态物质 · 物理学 2021-07-20 Simone Ciarella , Chengjie Luo , Vincent E. Debets , Liesbeth M. C. Janssen

We argue that the critical dynamical fluctuations predicted by the mode-coupling theory (MCT) of glasses provide a natural mechanism to explain the breakdown of the Stokes-Einstein relation. This breakdown, observed numerically and…

统计力学 · 物理学 2015-06-25 Giulio Biroli , Jean-Philippe Bouchaud
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