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Autoignition delay experiments for the isomers of butanol, including n-, sec-, tert-, and iso-butanol, have been performed using a heated rapid compression machine. For a compressed pressure of 15 bar, the compressed temperatures have been…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Kamal Kumar , Chih-Jen Sung

The autoignition delays of mixtures of methyl-cyclohexane (MCH), oxygen, nitrogen, and argon have been studied in a heated rapid compression machine under the conditions $P_C$ = 50 bar, $T_C$ = 690 - 910K. Three different mixture…

Ignition delay times of cyclohexane-oxygen-argon and cyclopentane-oxygen-argon mixtures have been measured in a shock tube, the onset of ignition being detected by OH radical emission. Mixtures contained 0.5 or 1 % of hydrocarbon for…

Methyl valerate (C$_6$H$_{12}$O$_2$, methyl pentanoate) is a methyl ester and a relevant surrogate component for biodiesel. In this work, we present ignition delays of methyl valerate measured using a rapid compression machine at a range of…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Justin Bunnell , Kamal Kumar , Chih-Jen Sung

Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the…

Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressure of 15 bar and low to intermediate temperatures of 725-870 K. Stoichiometric mixtures made in nitrogen/oxygen air were studied. For the…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Chih-Jen Sung

New experimental data are collected for methyl-cyclohexane (MCH) autoignition in a heated rapid compression machine (RCM). Three mixtures of MCH/O2/N2/Ar at equivalence ratios of $\phi$=0.5, 1.0, and 1.5 are studied and the ignition delays…

化学物理 · 物理学 2017-06-12 Bryan W. Weber , WIlliam J. Pitz , Marco Mehl , Emma Silke , Alexander C. Davis , Chih-Jen Sung

Autoignition experiments for n-butanol have been performed using a heated rapid compression machine at compressed pressures of 15 and 30 bar, in the compressed temperature range of 675-925 K, and for equivalence ratios of 0.5, 1.0, and 2.0.…

化学物理 · 物理学 2017-06-06 Bryan W. Weber , Kamal Kumar , Yu Zhang , Chih-Jen Sung

Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane…

This paper describes an experimental and modeling study of the oxidation of the three isomers of xylene (ortho-, meta- and para-xylenes). For each compound, ignition delay times of hydrocarbon-oxygen-argon mixtures with fuel equivalence…

Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressures of 15 bar and 30 bar and low to intermediate temperatures of 680-860 K. The reactivity of the stoichiometric isomers of butanol, in…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Chih-Jen Sung

The autoignition delays of iso-butanol, oxygen, and nitrogen mixtures have been measured in a heated rapid compression machine (RCM). At compressed pressures of 15 and 30 bar, over the temperature range 800-950 K, and for equivalence ratio…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Shamel Merchant , Chih-Jen Sung , William H. Green

Autoignition delay experiments were performed for n-butanol in a heated rapid compression machine. Experiments were performed at pressures of 15 and 30 bar, in the temperature range 650-900 K, and for equivalence ratios of 0.5, 1.0, and…

化学物理 · 物理学 2017-06-12 Bryan W. Weber

Ignition delay times of cyclopentene-oxygen-argon mixtures were measured behind reflected shock waves. Mixtures contained 0.5 or 1 % of hydrocarbons for equivalence ratios ranging from 0.5 to 1.5. Reflected shock waves conditions were:…

Autoignition experiments of stoichiometric mixtures of s-, t-, and i-butanol in air have been performed using a heated rapid compression machine (RCM). At compressed pressures of 15 and 30 bar and for compressed temperatures in the range of…

化学物理 · 物理学 2017-06-12 Bryan W. Weber , Chih-Jen Sung

This study focuses on the automatic generation by the software EXGAS of kinetic models for the oxidation of large methyl esters using a single set of kinetic parameters. The obtained models allow to well reproduce the oxidation of n-decane…

Ignition of Jet-A/air mixtures was studied behind reflected shock waves. Heating of shock tube at temperature of 150 C was used to prepare a homogeneous fuel mixture. Ignition delay times were measured from OH emission at 309 nm and from…

化学物理 · 物理学 2014-03-18 V. P. Zhukov , V. A. Sechenov , A. Yu. Starikovskiy

Auto-ignition process of stoichiometric mixture of methane-air is investigated using detailed chemical kinetics in a single-zone combustion chamber. Effect of initial temperature on start of combustion (SOC). The Arrhenius expression for…

化学物理 · 物理学 2017-12-08 Bagher Abareshi , Hassan Mohagheghi , Morteza Khosronia Kalalabadi

Reactivity Controlled Compression Ignition (RCCI) is a new advanced engine concept that uses a dual fuel mode of operation to achieve significant improvements in fuel economy and emissions output. The fuels that are typically used in this…

化学物理 · 物理学 2017-06-07 Hongfu Wang , Bryan W. Weber , Ruozhou Fang , Chih-Jen Sung

The delayed explosive desorption of particles from Ar matrices doped with methane stimulated by an electron irradiation was studied in the extended concentration range from 1% to 10% using emission spectroscopy methods. Registration of the…

化学物理 · 物理学 2022-12-06 E. Savchenko , I. Khyzhniy , S. Uyutnov , M. Bludov , V. Bondybey
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