相关论文: Thermodynamic Efficiency and Entropy Production in…
We challenge claims that the principle of maximum entropy production produces physical phenomenological relations between conjugate currents and forces, even beyond the linear regime, and that currents in networks arrange themselves to…
A diagram that represents both conservation of energy and constancy of entropy in Carnot cycle.
Cyclic classical and quantum thermal machines show higher efficiency when the strokes are carried out quasi-statically. Recent theoretical and experimental work on figures of merit for thermal machines show that they have an advantage when…
The Second Law of Thermodynamics states that the entropy of a closed system is non-decreasing. Discussing the Second Law in the quantum world poses new challenges and provides new opportunities, involving fundamental…
We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…
We consider thermodynamic systems with finitely many degrees of freedom and subject to an external control action. We derive some basic results on the dependence of the relative entropy production rate on the controlling force. Applications…
Dissipative structures are open dynamical systems that sustain coherent macroscopic organization by continuously exchanging energy and matter with their environment and generating entropy. A recent thermodynamic analysis of the paradigmatic…
We study the time evolution of a periodically driven quantum-mechanical system coupled to several reserviors of free fermions at different temperatures. This is a paradigm of a cyclic thermodynamic process. We introduce the notion of a…
We consider relaxation of an isolated system to the equilibrium using detailed balance condition and Onsager's fluctuation approximation. There is a small deviation from the equilibrium in two parameters. For this system, explicit…
A long standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investigated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with…
A short introduction on quantum thermodynamics is given and three new topics are discussed: 1) Maximal work extraction from a finite quantum system. The thermodynamic prediction fails and a new, general result is derived, the ``ergotropy''.…
A thermodynamic formalism describing the efficiency of information learning is proposed, which is applicable for stochastic thermodynamic systems with multiple internal degree of freedom. The learning rate, entropy production rate (EPR),…
In this note, the equilibrium curve of a thermodynamic system is used to depict entropy production in the process of thermalization with a reservoir. For the given initial and final equilibrium states of the system, the entropy production…
We establish a fundamental connection between score-based diffusion models and non-equilibrium thermodynamics by deriving performance limits based on entropy rates. Our main theoretical contribution is a lower bound on the negative…
Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…
This paper addresses fundamental aspects of statistical mechanics such as the motivation of a classical state space with spontaneous transitions, the meaning of non-equilibrium in the context of thermalization, and the justification of…
Entropy production for a system not in the thermodynamic limit is formulated using Hill's nanothermodynamics, in which a macroscopic ensemble of such systems is considered. External influence of the environment on the average nanosystem is…
Entropy serves as a central observable in equilibrium thermodynamics. However, many biological and ecological systems operate far from thermal equilibrium. Here we show that entropy production can characterize the behavior of such…
In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy…
We develop a perturbation theory of quantum (and classical) master equations with slowly varying parameters, applicable to systems which are externally controlled on a time scale much longer than their characteristic relaxation time. We…