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Fluctuation theorems are a generalization of thermodynamics on small scales and provide the tools to characterize the fluctuations of thermodynamic quantities in non-equilibrium nanoscale systems. They are particularly important for…

统计力学 · 物理学 2014-04-03 Jan Gieseler , Romain Quidant , Christoph Dellago , Lukas Novotny

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

统计力学 · 物理学 2012-12-06 Gatien Verley , David Lacoste

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

统计力学 · 物理学 2020-10-13 Jianzhong Wu

In this paper we formulate a dynamical fluctuation theory for stationary non equilibrium states (SNS) which covers situations in a nonlinear hydrodynamic regime and is verified explicitly in stochastic models of interacting particles. In…

统计力学 · 物理学 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

It will be shown, how the Boltzmannian ideas on statistical physics can be naturally applied to nonequilibrium thermodynamics. A similar approach for treating nonequilibrium phenomena has been successfully used by Einstein and Smoluchowski…

统计力学 · 物理学 2007-05-23 W. Pietsch

In the last ten years, a number of ``Conventional Fluctuation Theorems'' have been derived for systems with deterministic or stochastic dynamics, in a transient or in a non-equilibrium stationary state. These theorems gave explicit…

统计力学 · 物理学 2007-05-23 R. van Zon , E. G. D. Cohen

Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also…

统计力学 · 物理学 2022-02-02 Gianluca Francica

In this work a generalization of Onsager-Machlup's theory of time-dependent thermal fluctuations of equilibrium systems is proposed, to the case in which the system relaxes irreversibly along a non-equilibrium trajectory that can be…

统计力学 · 物理学 2009-08-05 M. Medina-Noyola

We generalize the Clausius (in)equality to overdamped mesoscopic and macroscopic diffusions in the presence of nonconservative forces. In contrast to previous frameworks, we use a decomposition scheme for heat which is based on an exact…

统计力学 · 物理学 2015-05-07 Christian Maes , Karel Netocny

The Fluctuation Theorems are a group of exact relations that remain valid irrespective of how far the system has been driven away from equilibrium. Other than having practical applications, like determination of equilibrium free energy…

统计力学 · 物理学 2016-11-04 Sourabh Lahiri , A. M. Jayannavar

A fluctuation theorem is proved for the macroscopic currents of a system in a nonequilibrium steady state, by using Schnakenberg network theory. The theorem can be applied, in particular, in reaction systems where the affinities or…

统计力学 · 物理学 2015-06-25 David Andrieux , Pierre Gaspard

The fluctuation-dissipation-theorem connects equilibrium to mildly (linearly) perturbed situations in a thermodynamic manner: It involves the observable of interest and the entropy production caused by the perturbation. We derive a relation…

统计力学 · 物理学 2021-03-24 Tristan Holsten , Matthias Krüger

This article traces the development of fluctuation theory and its deep connection to irreversibility, from equilibrium to near-equilibrium, and finally to far-from-equilibrium systems. Classical fluctuation theorems, which capture the…

量子物理 · 物理学 2025-12-30 Sounak Bandyopadhyay , Arnab Ghosh

A generalization of the Onsager-Machlup theory from equilibrium to nonequilibrium steady states and its connection with recent fluctuation theorems are discussed for a dragged particle restricted by a harmonic potential in a heat reservoir.…

统计力学 · 物理学 2007-05-23 Tooru Taniguchi , E. G. D. Cohen

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

统计力学 · 物理学 2009-09-25 Gavin E. Crooks

We demonstrate that the fluctuation theorem of Gallavotti and Cohen can be used to characterize the class of dynamics that arises in nonthermal systems of collectively interacting particles driven over random quenched disorder. By observing…

统计力学 · 物理学 2013-12-05 J. A. Drocco , C. J. Olson Reichhardt , C. Reichhardt

We introduce a finite-time detailed fluctuation theorem for the environmental entropy of the form $\tilde P(\Delta S_{env}) = e^{\Delta S_{env}} \tilde P(-\Delta S_{env})$ for an appropriately weighted probability density of the external…

统计力学 · 物理学 2013-04-22 David Luposchainsky , Andre Cardoso Barato , Haye Hinrichsen

We use a recently proved fluctuation theorem for the currents to develop the response theory of nonequilibrium phenomena. In this framework, expressions for the response coefficients of the currents at arbitrary orders in the thermodynamic…

统计力学 · 物理学 2015-05-13 D. Andrieux , P. Gaspard

The fluctuation theorem characterizes the distribution of the dissipation in nonequilibrium systems and proves that the average dissipation will be positive. For a large system with no external source of fluctuation, fluctuations in…

统计力学 · 物理学 2018-12-18 Guillaume Michel , Debra J. Searles

The second law of thermodynamics posits that in closed macroscopic systems the rate of entropy production must be positive. However, small systems can exhibit negative entropy production over short timescales, seemingly in contradiction…

量子气体 · 物理学 2023-08-08 Rama Sharma , Tapio P. Simula , Andrew J. Groszek
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