相关论文: Probing isotope effects in chemical reactions usin…
Direct dissociative recombination and resonant ion-pair formation reactions of $\mathrm{HeH^+}$ are theoretically studied using time-dependant wave-packets methods. The wave packets are propagated on potential energy curves that are in…
The reaction between He$^+$ and CH$_3$F forming predominantly CH$_2^+$ and CHF$^+$ has been studied at collision energies $E_{\rm coll}$ between 0 and $k_{\rm B}\cdot 10$~K in a merged-beam apparatus. To avoid heating of the ions by stray…
Replacement of hydrogen by deuterium in palladium hydride results in higher superconducting temperatures and an anomalous isotope effect that has not been yet fully explained. In this work, we try a new approach to the explanation of the…
We consider electron impact-driven single and double ionization of magnesium in the 10-100 eV energy range. Our classical Hamiltonian model of these (e, 2e) and (e, 3e) processes sheds light on their total cross sections and reveals the…
The kinetics of MgO$^+$ + CH$_4$ was studied experimentally using the variable ion source, temperature adjustable selected ion flow tube (VISTA-SIFT) apparatus from 300 $-$ 600 K and computationally by running and analyzing reactive…
The time-evolution and space-distribution of internal electromagnetic fields in heavy-ion reactions at beam energies between 200 and 2000 MeV/nucleon are studied within an Isospin-dependent Boltzmann-Uhling-Uhlenbeck transport model IBUU11.…
We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…
Hybrid atom-ion systems are a rich and powerful platform for studying chemical reactions, as they feature both excellent control over the electronic state preparation and readout as well as a versatile tunability over the scattering energy,…
A theoretical study of the polarization entanglement of two photons emitted in the decay of metastable ionic states is performed within the framework of density matrix theory and second-order perturbative approach. Particular attention is…
A highly effective approach to the search for hypothetical new interactions through isotope shift spectroscopy of hydrogen-like ions is presented. A weighted difference of the g factor and ground-state energy is shown to assist in the…
In 1954, Vogt and Wannier (Phys. Rev. 95, 1190) predicted that the capture rate of a polarizable neutral atom or molecule by an ion should increase by a factor of two compared to the classical Langevin rate as the collision energy…
Rate constants for the C(3P) + CH3OH reaction have been measured in a continuous supersonic flow reactor over the range 50 K to 296 K. C(3P) was created by the in-situ pulsed laser photolysis of CBr4, a multiphoton process which also…
Liquid atomic metallic hydrogen is the simplest, lightest, and most abundant of all liquid metals. The role of nucleon motions or ion dynamics has been somewhat ignored in relation to the dissociative insulator-metal transition. Almost all…
Theoretical and experimental studies of hot and/or dense matter, such as is created in high-energy heavy-ion collisions, and encountered in compact objects in astrophysics, constitute one of the most active frontiers in nuclear physics. In…
The hydrogen abstraction reaction between H and H$_2$S, yielding HS and H$_2$ as products, has been studied within the framework of interstellar surface chemistry. High-temperature rate constants up to 2000 K are calculated in the gas phase…
We simulate the central reactions of $^{20}$Ne+$^{20}$Ne, $^{40}$Ar+$^{45}$Sc, $^{58}$Ni+$^{58}$Ni, $^{86}$Kr+$^{93}$Nb, $^{129}$Xe+$^{118}$Sn, $^{86}$Kr+$^{197}$Au, and $^{197}$Au+$^{197}$Au at different incident energies for different…
Data for inelastic processes due to hydrogen atom collisions with manganese and titanium are needed for accurate modeling of the corresponding spectra in late-type stars. In this work excitation and charge transfer in low-energy Mn+H and…
Isotopic effects in spectator fragmentations following heavy-ion collisions at relativistic energies are investigated using data from recent exclusive experiments with SIS beams at GSI. Reactions of 12C on 112,124Sn at incident energies 300…
A close coupling quantum-mechanical calculation is performed for rotational energy transfer in a HD+HD collision at very low energy, down to the ultracold temperatures: $T \sim 10^{-8}$ K. A global six-dimensional H$_2$-H$_2$ potential…
Recent studies of neutral gas-phase reactions characterized by barriers show that certain complex forming processes involving light atoms are enhanced by quantum mechanical tunneling at low temperature. Here, we performed kinetic…