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Hydrogen segregation to vacancies in the surface and subsurface layers of (111) and (100) surfaces of Pd is studied in the density functional theory (DFT) approach. Adsorption energies and configurations of various clusters of H atoms at…

材料科学 · 物理学 2020-06-24 A. V. Subashiev , H. H. Nee

The ground and excited vibrational states for the three hydrogen isotopes on the Pd(111) surface have been calculated. Notable features of these states are the high degree of anharmonicity, which is most prominently seen in the weak…

chem-ph · 物理学 2009-10-22 Steven W. Rick , J. D. Doll

We present a combination of theoretical calculations and experiments for the low-lying vibrational excitations of H and D atoms adsorbed on the Pt(111) surface. The vibrational band states are calculated based on the full three-dimensional…

统计力学 · 物理学 2009-11-07 S. C. Badescu , P. Salo , T. Ala-Nissila , S. C. Ying , K. Jacobi , Y. Wang , K. Bedurftig , G. Ertl

Ground state energies for confined hydrogen (H) and helium (He) atoms, inside a penetrable/impenetrable compartment have been calculated using Diffusion Monte Carlo (DMC) method. Specifically, we have investigated spherical and ellipsoidal…

其他凝聚态物理 · 物理学 2009-11-13 M. Neek-Amal , G. Tayebirad , M. Molayem , M. E. Foulaadvand , L. Esmaeili Sereshki , A. Namiranian

Adsorption of hydrogen atoms to a carbon atom vacancy in graphene is investigated by means of periodic \emph{first principles} calculations, up to the fully hydrogenated state where six H atoms chemically bind to the vacancy. Addition of a…

材料科学 · 物理学 2013-12-30 M. Casartelli , S. Casolo , G. F. Tantardini , R. Martinazzo

The hydrogen dynamics on a graphene sheet is studied in the presence of carbon vacancies. We analyze the motion of atomic H by means of molecular dynamics (MD) simulations, using a tight-binding Hamiltonian fitted to density-functional…

化学物理 · 物理学 2022-09-29 Carlos P. Herrero , Jose A. Verges , Rafael Ramirez

By performing density functional theory-based calculations, we investigate how hydrogen atom interacts with the surfaces of monolayer PbI2 and how one and two side hydrogenation modify its structural, electronic, and magnetic properties.…

介观与纳米尺度物理 · 物理学 2016-07-22 C. Bacaksiz , H. Sahin

The atomic structures of clean and hydrogen-adsorbed Pd(001) are investigated by low energy electron diffraction (LEED) I/V analysis. Clean Pd(001) shows little surface relaxation in sharp contrast to previous reports. Adsorbing 1 monolayer…

其他凝聚态物理 · 物理学 2007-05-23 S. H. Kim , J. Barthel , H. L. Meyerheim , J. Kirschner , Jikeun Seo , J. -S. Kim

An H atom inserted into hydrogen monolayer on the Si(100)-2x1 surface has been studied using the density functional theory. Hydrogen-induced defects were considered in their neutral, negative, and positive charge states. It was found that…

介观与纳米尺度物理 · 物理学 2020-10-28 T. V. Pavlova

The position and momentum probability densities of a multidimensional quantum system are fully characterized by means of the radial expectation values $\langle r^\alpha \rangle$ and $\left\langle p^\alpha \right\rangle$, respectively. These…

量子物理 · 物理学 2021-06-18 J. S. Dehesa , D. Puertas-Centeno

We studied the hydrogen atom as a system of two quantum particles in different confinement conditions; a spherical-impenetrable-wall cavity and a fullerene molecule cage. The motion is referred to the center of spherical cavities, and the…

原子与分子团簇 · 物理学 2016-12-21 Juan M. Randazzo , Carlos A. Rios

We have studied the fundamental process of hydrogen binding at interstitial, vacancy and grain boundary (GB) in palladium crystals using Density-Functional Theory. It showed that hydrogen prefers to occupy the octahedral interstitial site…

材料科学 · 物理学 2015-06-02 Hieu H. Pham , Tahir Cagin

The behavior of a classical charged point particle under the influence of only a Coulombic binding potential and classical electromagnetic zero-point radiation, is shown to yield agreement with the probability density distribution of…

量子物理 · 物理学 2015-06-26 Daniel C. Cole , Yi Zou

A trial wave function is proposed for studying the instability of the two-dimensional Hubbard model with respect to d-wave superconductivity. Double occupancy is reduced in a similar way as in previous variational studies, but in addition…

强关联电子 · 物理学 2009-11-11 David Eichenberger , Dionys Baeriswyl

We have performed total-energy density-functional calculations using first-principles pseudopotentials to determine the atomic and electronic structure of neutral surface and subsurface vacancies at the GaP(110) surface. The cation as well…

材料科学 · 物理学 2009-10-30 G. Schwarz , A. Kley , J. Neugebauer , M. Scheffler

The internal disorder of a D-dimensional hydrogenic system, which is strongly associated to the non-uniformity of the quantum-mechanical density of its physical states, is investigated by means of the shape complexity in the two reciprocal…

量子物理 · 物理学 2009-07-09 Sheila Lopez-Rosa , Daniel Manzano , Jesus S. Dehesa

We consider a non-relativistic two-dimensional (2D) hydrogen-like atom in a weak, static, uniform magnetic field perpendicular to the atomic plane. Within the framework of the Rayleigh-Schr\"odinger perturbation theory, using the Sturmian…

量子物理 · 物理学 2018-06-12 Radosław Szmytkowski

We calculate the ground--state energy and other physical properties of the hydrogen atom inside a spherical box with an impenetrable wall. We apply the variational method and perturbation theory and compare both approximate results. We show…

量子物理 · 物理学 2015-05-19 Francisco M. Fernández , N. Aquino , A. Flores-Riveros

We investigate the atomic hydrogen adsorption on Mg(0001) by using density-functional theory within the generalized gradient approximation and a supercell approach. The coverage dependence of the adsorption structures and energetics is…

材料科学 · 物理学 2009-04-29 Yanfang Li , Ping Zhang , Bo Sun , Yu Yang , Yinghui Wei

A variational treatment for a two-electron quantum dot (the artificial helium atom) is proposed which leads to exact answer for the ground state energy. Depending on the magnetic field value the singlet-triplet and triplet-triplet…

介观与纳米尺度物理 · 物理学 2007-05-23 Subinoy Das , Pallab Goswami , J. K. Bhattacharjee
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