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The ground state energy of current carriers in graphene considered as a zero-gap semiconductor was calculated in the two-band approximation. The condition of the electronic (hole) system stability in graphene was obtained. The possibility…

Other Condensed Matter · Physics 2008-01-31 P. V. Ratnikov , A. P. Silin

We report the synthesis and evidence of graphene fluoride, a two-dimensional wide bandgap semiconductor derived from graphene. Graphene fluoride exhibits hexagonal crystalline order and strongly insulating behavior with resistance exceeding…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 S. -H. Cheng , K. Zou , F. Okino , H. R. Gutierrez , A. Gupta , N. Shen , P. C. Eklund , J. O. Sofo , J. Zhu

The results of X-ray photoemission (XPS) and valence bands spectroscopy, optically stimulated electron emission (OSEE) measurements and density functional theory based modeling of graphene oxide (GO) placed on Cu via an electrophoretic…

The dynamic covalent properties of graphene oxide (GO) are of fundamental interest to a broad range of scientific areas and technological applications. It remains a challenge to access the feasible dynamic reactions for reversibly…

Materials Science · Physics 2022-08-24 Zihan Yan , Wenjie Yang , Hao Yang , Chengao Ji , Shuming Zeng , Xiuyun Zhang , Liang Zhao , Yusong Tu

Most popular atomically thin carbon material, called graphene, has got no band gap and this particular property of graphene makes it less useful from the aspect of nanoscale transistor devices. The band gap can be introduced in the graphene…

Applied Physics · Physics 2019-11-15 Pankaj Kumar

We report valence band electronic structure evolution of graphene oxide (GO) upon its thermal reduction. Degree of oxygen functionalization was controlled by annealing temperatures, and an electronic structure evolution was monitored using…

Sub-10nm wide graphene nanoribbon field-effect transistors (GNRFETs) are studied systematically. All sub-10nm GNRs afforded semiconducting FETs without exception, with Ion/Ioff ratio up to 10^6 and on-state current density as high as…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Xinran Wang , Yijian Ouyang , Xiaolin Li , Hailiang Wang , Jing Guo , Hongjie Dai

Graphene oxide (GO) holds significant promise for electronic devices and nanocomposite materials. A number of models were proposed for GO structure, combining carboxyl, hydroxyl, carbonyl and epoxide groups at different locations. The…

Materials Science · Physics 2015-10-28 Vitaly V. Chaban , Oleg V. Prezhdo

The understanding of water transport in graphene oxide (GO) membranes stands out as a major theoretical problem in graphene research. Notwithstanding the intense efforts devoted to the subject in the recent years, a consolidated picture of…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 A. Montessori , C. A. Amadei , G. Falcucci , M. Sega , C. D. Vecitis , S. Succi

The type and distribution of oxygen functional groups in graphene oxide (GO) and reduced graphene oxide (RGO) remain still a subject of great debate. Local analytic techniques are required to access the chemistry of these materials at a…

Materials Science · Physics 2016-12-13 Anna Tararan , Alberto Zobelli , Ana M. Benito , Wolfgang K. Maser , Odile Stéphan

In the context of graphene-based composite applications, a complete understanding of charge conduction in multilayer reduced graphene oxides (rGO) is highly desirable. However, these rGO compounds are characterized by multiple and different…

We present evidence, from Lattice Monte Carlo simulations of the phase diagram of graphene as a function of the Coulomb coupling between quasiparticles, that graphene in vacuum is likely to be an insulator. We find a semimetal-insulator…

Strongly Correlated Electrons · Physics 2009-01-15 Joaquín E. Drut , Timo A. Lähde

One of the salient features of graphene is the very high carrier mobility that implies tremendous potential for use in electronic devices. Unfortunately, transport measurements find the expected high mobility only in freely suspended…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Søren Ulstrup , Marco Bianchi , Richard Hatch , Dandan Guan , Alessandro Baraldi , Dario Alfè , Liv Hornekær , Philip Hofmann

Reduced Graphene Oxide (RGO) is an electronically hybrid material that displays remarkable chemical sensing properties. Here, we present a quantitative analysis of the chemical gating effects in RGO-based chemical sensors. The gas sensing…

Materials Science · Physics 2015-06-16 Christopher E. Kehayias , Samuel MacNaughton , Sameer Sonkusale , Cristian Staii

Reports of metallic behavior in two-dimensional (2D) systems such as high mobility metal-oxide field effect transistors, insulating oxide interfaces, graphene, and MoS2 have challenged the well-known prediction of Abrahams, et al. that all…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 M. S. Osofsky , S. C. Hernández , A. Nath , V. D. Wheeler , S. Walton , C. M. Krowne , D. K. Gaskill

Graphene grown by chemical vapor deposition and supported on SiO2 and sapphire substrates was studied following controlled introduction of defects induced by 35 keV carbon ion irradiation. Changes in Raman spectra following fluences ranging…

A novel nanoelectronic device is constructed by graphyne that is robustly connected between graphene electrodes, where graphyne is composed of hexagonal carbon rings and carbon chains. Owing to similarities between the bond lengths and unit…

Mesoscale and Nanoscale Physics · Physics 2013-07-17 Young I. Jhon , Myung S. Jhon

The electronic transport properties of graphene-based superlattice structures are investigated. A graphene-based modulation-doped superlattice structure geometry is proposed and consist of periodically arranged alternate layers:…

Mesoscale and Nanoscale Physics · Physics 2013-11-25 Dima Bolmatov , Chung-Yu Mou

Pristine bilayer graphene behaves in some instances as an insulator with a transport gap of a few meV. This behaviour has been interpreted as the result of an intrinsic electronic instability induced by many-body correlations. Intriguingly,…

Mesoscale and Nanoscale Physics · Physics 2014-04-29 P. San-Jose , R. V. Gorbachev , A. K. Geim , K. S. Novoselov , F. Guinea

This work deals with the intrinsic and extrinsic properties of the graphene layers inside the graphite structure, in particular the influence of defects and interfaces. We discuss the evidence for ballistic transport found in mesoscopic…

Materials Science · Physics 2011-10-13 J. Barzola-Quiquia , A. Ballestar , S. Dusari , P. Esquinazi