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Structural and charge relaxation of nanoclusters of CdSe of diameter 1-2 nm are studied with first principle calculations. The relaxations cause significant distortions of smaller systems of ~ 1 nm in diameter and have very minimal effect…

Materials Science · Physics 2014-05-09 Anteneh G Tefera , Mogus D Mochena , Elijah Johnson , James Dickerson

We report the first principle theory-based study of stability, electronic structure and optical properties of cluster assembled materials in various 1D, 2D and 3D nanostructures using a cage-like Cd9Te9 cluster as the super-atom. The bulk…

Mesoscale and Nanoscale Physics · Physics 2022-05-27 Kashinath T Chavan , Sharat Chandra

The size-dependent structures and optical properties of CdSeS nanoclusters in water medium are investigated. The stability of different size-dependent Cd$_n$Se$_m$S$_p$ nanoclusters (up to n=6) is studied using density functional…

Materials Science · Physics 2020-11-10 Meenakshi Rana , Papia Chowdhury

In this work we study the structural stability and electronic properties of the Beryllium sulphide nanowires (NWs) in both zinc blende (ZB) and wurtzite (WZ) phases with triangle and hexagonal cross section, using first principle…

Materials Science · Physics 2015-05-14 Somayeh Faraji , Ali Mokhtari

We use density functional theory based first-principles method to investigate the bandstructure and phase stability in the laterally grown hexagonal C$_x$(BN)$_{1-x}$, two-dimensional Graphene and $h$-BN hybrid nanomaterials, which were…

Mesoscale and Nanoscale Physics · Physics 2016-03-21 Ransell D'Souza , Sugata Mukherjee

In this paper, we employ evolutionary algorithm along with the full-potential density functional theory (DFT) computations to perform a comprehensive search for the stable structures of stoichiometric (WS2)n nano-clusters (n=1-9), within…

In this paper we present a detailed analysis of the atomic and electronic structure of GaAs nanowires using first-principles pseudopotential calculations. We consider six different types of nanowires with different diameters all grown along…

Materials Science · Physics 2010-12-24 S. Cahangirov , S. Ciraci

Two dimensional allotropes of group IV substrates including silicene, germanene and stanene have recently attracted considerable attention in nanodevice fabrication industry. These materials involving the buckled structure have been…

Materials Science · Physics 2017-04-17 B Mortazavi , O Rahaman , M Makaremi , A Dianat , G Cuniberti , T Rabczuk

We study the electroacoustic properties of aluminum scandium nitride crystals Al$_{1-x}$Sc$_x$N with the metastable wurtzite structure by means of first-principles calculations based on density functional theory. We extract the material…

Materials Science · Physics 2021-03-17 Daniel F. Urban , Oliver Ambacher , Christian Elsässer

The energetic stability and electronic properties of hydrogenated silicon carbide nanowires (SiCNWs) with zinc blende (3C) and wurtzite (2H) structures are investigated using first-principles calculations within density functional theory…

Materials Science · Physics 2015-09-02 Zhenhai Wang , Mingwen Zhao , Tao He , Hongyu Zhang , Xuejuan Zhang , Zexiao Xi , Shishen Yan , Xiangdong Liu , Yueyuan Xia

Motivated by contradicting reports in the literature, we have investigated the structural stability of tungsten nanoparticles using density functional theory calculations. The comparison of BCC, FCC, A15, disordered, and icosahedral…

Materials Science · Physics 2024-04-08 Laurent Pizzagalli , Sandrine Brochard , Julien Godet , Julien Durinck

The theoretical formalism of the local density approximation (LDA) to density functional theory (DFT) has been used to study the electronic and geometric structures of SimCn (1<=m, n<=4;n<=m) clusters. An all electron 6-311++G** basis set…

Atomic and Molecular Clusters · Physics 2007-05-23 Prachi Pradhan , Asok K. Ray

The electronic and optical properties of spherical nanoheterostructures are studied within the semi-empirical $sp^{3}s^{*}$ tight-binding model including the spin-orbit interaction. We use a symmetry-based approach previously applied to…

Condensed Matter · Physics 2009-11-10 J. Perez-Conde , A. K. Bhattacharjee

The vibrational spectra of CdSe/CdS superlattices (SLs) with different layer thicknesses are calculated from first principles within the density functional theory. It is shown that, along with folded acoustic and confined optical modes, a…

Materials Science · Physics 2023-02-27 A. I. Lebedev

Employing density functional theory based calculations, we investigate structural, vibrational and strain-dependent electronic properties of an ultra-thin CdTe crystal structure that can be de- rived from its bulk counterpart. It is found…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 Fadil Iyikanat , Baris Akbali , Jun Kang , R. Tugrul Senger , Yusuf Selamet , Hasan Sahin

We report an unusual evolution of structure and magnetism in stoichiometric MnO clusters based on an extensive and unbiased search through the potential energy surface within density functional theory. The smaller clusters, containing up to…

Mesoscale and Nanoscale Physics · Physics 2011-11-11 Shreemoyee Ganguly , Mukul Kabir , Biplab Sanyal , Abhijit Mookerjee

Nanoparticles have become increasingly interesting for a wide range of applications, because in principle it is possible to tailor their properties by controlling size, shape and composition. One of these applications is heterogeneous…

Materials Science · Physics 2021-06-22 Jan Weinreich , Martín Leandro Paleico , Jörg Behler

The kinetics and thermodynamics of structural transformations under pressure depend strongly on particle size due to the influence of surface free energy. By suitable design of surface structure, composition, and passivation it is possible,…

Materials Science · Physics 2017-04-05 Michael Grünwald , Katie Lutker , A. Paul Alivisatos , Eran Rabani , Phillip L. Geissler

CdS nanotubes with wall thickness comparable to excitonic diameter of the bulk material are synthesized by a chemical route. A change in experimental conditions result in formation of nanowires, and well-separated nanoparticles. The…

Materials Science · Physics 2009-02-16 A. K. Mahapatra

The size-dependent structure of CdSe nanoparticles, with diameters ranging from 2 to 4 nm, has been studied using the atomic pair distribution function (PDF) method. The core structure of the measured CdSe nanoparticles can be described in…

Soft Condensed Matter · Physics 2009-11-13 A. S. Masadeh , E. Bozin , C. L. Farrow , G. Paglia , P. Juhas , A. Karkamkar , M. G. Kanatzidis , S. J. L. Billinge
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