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We report the effects of variation in length on the electronic structure of CdSe nanorods derived from atomic clusters and passivated by fictitious hydrogen atoms. These nanorods are augmented by attaching gold clusters at both the ends to…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Deepashri Saraf , Anjali Kshirsagar

We present first-principles calculations on bulk CdSe and CdSe nanowires with diameters of up to 22 \AA. Density functional linear combination of atomic orbitals and plane wave calculations of the electronic and structural properties are…

Materials Science · Physics 2009-06-04 M. Mohr , C. Thomsen

The structural, electronic, and vibrational thermodynamic properties of the (ZnO)$_n$ (n=2-16) clusters are studied using density functional - full potential computations. The results show, small clusters up to $n=9$ stabilize in the 2D…

Materials Science · Physics 2013-05-28 I. Abdolhosseini Sarsari , S. Javad Hashemifar , Hadi Salamati , Hadi Akbarzadeh

We have carried out a first principles study of the elastic properties and electronic structure for two room-temperature stable Pt silicide phases, tetragonal alpha-Pt_2Si and orthorhombic PtSi. We have calculated all of the equilibrium…

Materials Science · Physics 2009-10-31 O. Beckstein , J. E. Klepeis , G. L. W. Hart , O. Pankratov

In order to control and tailor the properties of nanodots, it is essential to separate the effects of quantum confinement from those due to the surface, and to gain insight into the influence of preparation conditions on the dot physical…

Materials Science · Physics 2009-10-31 Laurent Pizzagalli , Giulia Galli , John E. Klepeis , Francois Gygi

Pseudobinary heterostructural alloys of ZnO with MgO or CdO are studied by composing the system locally of clusters with varying ratio of cations. We investigate fourfold (wurtzite structure) and sixfold (rocksalt structure) coordination of…

Materials Science · Physics 2010-06-18 A. Schleife , M. Eisenacher , C. Rödl , F. Fuchs , J. Furthmüller , F. Bechstedt

Taking into considerations the wide compositional stretch of Heusler alloys, the first principles density functional theory based calculations are excellently suitable for estimating the multifaceted properties of alkali metal based LiVSb…

Materials Science · Physics 2024-07-03 Diwaker , Shyam L. Gupta , Anupam , Sumit Kumar , Aadil Fayaz , Ashwani Kumar

At ambient pressure, sodium, chlorine, and their only known compound NaCl, have well-understood crystal structures and chemical bonding. Sodium is a nearly-free-electron metal with the bcc structure. Chlorine is a molecular crystal,…

Patchy nanocubes are intriguing materials with simple shapes and space-filling and multidirectional bonding properties. Previous studies have revealed various mesoscopic structures such as colloidal crystals in the solid regime and rod-like…

Soft Condensed Matter · Physics 2024-07-09 Takahiro Ikeda , Yusei Kobayashi , Masashi Yamakawa

Spin-polarized DFT has been used to perform a comprehensive study of the geometric structures and electronic properties for isolated M4X4 nano-clusters between their two stable isomers - a planar rhombus-like 2D structure and a cubane-like…

Mesoscale and Nanoscale Physics · Physics 2015-12-29 Soumendu Datta , Badiur Rahaman

Extensive first-principle calculations on embedded clusters containing few O, Y, Ti, and Cr atoms as well as vacancies are performed to obtain interaction parameters to be applied in Metropolis Monte Carlo simulations, within the framework…

Materials Science · Physics 2014-11-05 M. Posselt , D. Murali , B. K. Panigrahi

A novel stable crystallographic structure is discovered in a variety of ABO3, ABF3 and A2O3 compounds (including materials of geological relevance, prototypes of multiferroics, exhibiting strong spin-orbit effects, etc...), via the use of…

Materials Science · Physics 2015-01-20 Changsong Xu , Bin Xu , Yurong Yang , Huafeng Dong , A. R. Oganov , Shanying Wang , Wenhui Duan , Binglin Gu , L. Bellaiche

We report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High resolution transmission electron…

We present results of a study of small stoichiometric $Cd_{n}Te_{n}$ ($1{\leq}n{\leq}6$) clusters and few medium sized non-stoichiometric $Cd_{m}Te_{n}$ [($m,n= 13, 16, 19$); ($m{\neq}n$)] clusters using the Density Functional formalism and…

Materials Science · Physics 2013-05-29 Somesh Kr. Bhattacharya , Anjali Kshirsagar

Electronic structures for InxGa1-xAs nanowires with [100], [110], and [111] orientations and critical dimensions of approximately 2 nm are treated within the framework of density functional theory. Explicit band structures are calculated…

Mesoscale and Nanoscale Physics · Physics 2018-02-23 Pedram Razavi , James C. Greer

The magnetic structures of small clusters of Fe, Mn, and Cr supported on a Cu(111) surface have been studied with non-collinear first principles theory. Different geometries such as triangles, pyramids and wires are considered and the…

The structural, electronic, optical and vibrational properties of the collapsed (10,10) single-walled carbon nanotube bundle under hydrostatic pressure have been studied by the first-principles calculations. Some features are observed in…

Materials Science · Physics 2009-11-13 Xiaoping Yang , Gang Wu , Jinming Dong

We present a critical theoretical study of electronic properties of silicon nanoclusters, in particular the roles played by symmetry, relaxation, and hydrogen passivation on the the stability, the gap states and the energy gap of the system…

Materials Science · Physics 2009-10-31 Lei Liu , C. S. Jayanthi , S. Y. Wu

We predict the existence of new two dimensional silicon carbide nanostructure employing ab initio density-functional theory calculations. These structures are composed of tetragonal and hexagonal rings with C-C and Si-C bonds arranged in a…

Materials Science · Physics 2020-12-16 Qun Wei , Ying Yang , Guang Yang , Xihong Peng

Using first-principles density functional theory based calculations, we analyze the structural stability of small clusters of 3$d$ late transition metals. We consider the relative stability of the two structures - layer-like structure with…

Mesoscale and Nanoscale Physics · Physics 2011-08-15 Soumendu Datta , Mukul Kabir , Tanusri Saha-Dasgupta