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We describe the ground- and excited-state electronic structure of bulk MnO and NiO, two prototypical correlated electron materials, using coupled cluster theory with single and double excitations (CCSD). As a corollary, this work also…

The newly synthesized ultrathin carbon nanothreads have drawn great attention from the carbon community. Here, based on first-principles calculations, we investigate the electronic properties of carbon nanothreads under the influence of two…

Materials Science · Physics 2018-03-14 Weikang Wu , Bo Tai , Shan Guan , Shengyuan A. Yang , Gang Zhang

The properties of neutral and anionic Pd_N clusters were investigated with spin-density-functional calculations. The ground state structures are three-dimensional for N>3 and they are magnetic with a spin-triplet for 2<=N<=7 and a spin…

Atomic and Molecular Clusters · Physics 2009-11-07 M. Moseler , H. Hakkinen , R. N. Barnett , U. Landman

The structural and magnetic properties of Co$_{18-m}$Cu$_m$ ($0\leq m\leq 18$) clusters are investigated with a genetic algorithm and a $spd$-band model Hamiltonian in the unrestricted Hartree-Hock approximation respectively. In general, Cu…

Atomic and Molecular Clusters · Physics 2007-05-23 Jinlan Wang , Guanghou Wang , Xiaoshuang Chen , Wei Lu , Jijun Zhao

We investigate the effects of "dynamic structural disorder" (DSD) on the behavior of supported nano-scale catalysts. DSD refers to the intrinsic fluctuating, inhomogeneous structure of such nano-scale systems. In contrast to bulk materials,…

Chemical Physics · Physics 2013-09-09 J. J. Rehr , F. D. Vila

We investigate by scattering techniques the structure of water-based soft composite materials comprising a crystal made of Pluronic block-copolymer micelles arranged in a face-centered cubic lattice and a small amount (at most 2% by volume)…

Soft Condensed Matter · Physics 2012-06-07 Elisa Tamborini , Neda Ghofraniha , Julian Oberdisse , Luca Cipelletti , Laurence Ramos

We study the composition dependent evolution of geometric and magnetic structures of MnO clusters within density functional theory. A systematic and extensive search through the potential energy surface is performed to identify the correct…

Materials Science · Physics 2018-10-16 Shreemoyee Ganguly , Mukul Kabir , Carmine Autieri , Biplab Sanyal

We numerically simulate mechanically stable packings of soft-core, frictionless, bidisperse disks in two dimensions, above the jamming packing fraction $\phi_J$. For configurations with a fixed isotropic global stress tensor, we compute the…

Soft Condensed Matter · Physics 2015-03-18 Yegang Wu , S. Teitel

Nanoindentation, a common technique for probing the mechanical properties of crystalline materials, exhibits both surface and bulk-dominated responses that are linked to the parent crystal's elasticity and plasticity. For FCC crystals, the…

Materials Science · Physics 2020-02-04 Michail Tzimas , John Michopoulos , Giacomo Po , Andrew C. E. Reid , Stefanos Papanikolaou

Periodicity is usually assumed to be the necessary and sufficient condition for the formation of band gaps, i.e., energy bands with a suppressed density of states. Here, we check this premise by analyzing the band gap properties of three…

The electronic structure of crystalline CdTe, CdO, $\alpha$-TeO$_2$, CdTeO$_3$ and Cd$_3$TeO$_6$ is studied by means of first principles calculations. The band structure, total and partial density of states, and charge densities are…

Materials Science · Physics 2009-11-10 Eduardo Ariel Menendez Proupin , Gonzalo Gutierrez , Ernesto Palmero , J. L. Peña

The new structures, Cmc2$_1$-Si$_2$P$_2$X (X=S, Se, Te, and Po), are predicted, and their mechanical, electronic and optical properties are investigated with the density functional theory, by first principles calculations. The elastic…

Materials Science · Physics 2021-12-21 R. Yang , X. Gao , F. Wu , Q. Wei , M. Xue

The four most stable structures of Ni$_N$ clusters with $N$ from 2 to 150 have been determined using a combination of the embedded-atom method in the version of Daw, Baskes and Foiles, the {\it variable metric/quasi-Newton} method, and our…

Atomic and Molecular Clusters · Physics 2016-09-08 V. G. Grigoryan , M. Springborg

In this paper we propose a tight-binding molecular dynamics with parameters fitted to first-principles calculations on the smaller clusters and with an environment correction, to be a powerful technique for studying large transition/noble…

Atomic and Molecular Clusters · Physics 2009-11-10 Mukul Kabir , Abhijit Mookerjee , A. K. Bhattacharya

Ternary semiconductor CuYS2 is studied by using the first-principles methods in the density functional theory (DFT) framework. The structural, electronic, optical and elastic properties were calculated at the ambient and elevated…

Materials Science · Physics 2013-09-13 M. G. Brik

Using the density functional theory (DFT) based first-principles investigation, the structural, mechanical, hardness, elastic anisotropy, optoelectronic, and thermal properties of cubic KB2H8 have been studied within the uniform pressure…

Materials Science · Physics 2023-11-14 Md. Ashraful Alam , F. Parvin , S. H. Naqib

While growth and dissolution of surface nanobubbles has been widely studied in recent years, their stability under pressure changes or a temperature increase has not received the same level of scrutiny. Here, we present theoretical…

Soft Condensed Matter · Physics 2020-07-10 Yawei Liu , Stefano Bernardi , Asaph Widmer-Cooper

Fine complex light structure, optical singularities and electroconductivty of nematic 5CB doped by multi-walled carbon nanotubes (MWCNTs) were investigated. MWCNTs gather spontaneously to system of micro scale clusters with random fractal…

Motivated by the variation in reported lattice parameters of floating-zone-grown Nd$_{2}$Zr$_{2}$O$_{7}$ crystals, we have performed a detailed study of the relationship between synthesis environment, structural disorder, and magnetic…

Novel physical phenomena emerge in ultra-small sized nanomaterials. We study the limiting small-size-dependent properties of MoS$_{2}$ monolayer rhombic nanoflakes using density-functional theory on structures of size up to…

Applied Physics · Physics 2017-05-08 M. Javaid , Daniel W. Drumm , Salvy P. Russo , Andrew D. Greentree
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