相关论文: Exciton Transfer Integrals Between Polymer Chains
Coupling of quantum emitters in a semiconductor relies, generally, on short-range dipole-dipole or electronic exchange type interactions. Consistently, energy transfer between exciton states, that is, electron-hole pairs bound by Coulomb…
The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially then there is an adsorption transition…
We report on small-cluster exact-diagonalization calculations which prove the formation of electron-hole pairs (excitons) as prerequisite for spontaneous interlayer phase coherence in bilayer systems described by the extended…
We quantify the excitonic coupling in the homodimer of dimeric Venus fluorescent protein using a quantum-classical hybrid workflow. Employing a transition-density coupling formalism, we calculate $J = 74.38~\mathrm{cm^{-1}}$, which is 5.6…
We report on high-dimensional quantum dynamical simulations of torsion-induced exciton migration in a single-chain oligothiophene segment comprising twenty repeat units, using a first-principles parametrized Frenkel J-aggregate Hamiltonian.…
Self-assembled aggregates of pigment molecules are potential building blocks for excitonic circuits that find their application in energy conversion and optical signal processing. Recent experimental studies of one-dimensional…
Strong light--matter interactions forming hybrid quasiparticles termed polaritons can specifically tailor molecular photophysics. In this spirit, enhancing energy transport has recently been of special interest. Exciton--exciton…
Attachment of chemical substituents (such as polar moieties) constitutes an efficient and convenient way to modify physical and chemical properties of conjugated polymers and oligomers. Associated modifications in the molecular electronic…
We present a study of the charge transmission behavior of a series of dithiol polyenes in the context of molecular junctions. Using the Landauer theory and zero voltage approximation the Green's functions of the inserted molecules are…
The Transfer Matrix Method (TMM) is a widely used technique for modeling linear propagation of electromagnetic waves through stratified layered media. However, since its extension to inhomogeneous and nonlinear systems is not…
We theoretically analyze the excitation energy transfer between two closely spaced linear molecular J-aggregates, whose excited states are Frenkel excitons. The aggregate with the higher (lower) exciton band edge energy is considered as the…
We consider the properties of a self-avoiding polymer chain, adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a…
Several methods for preparing well equilibrated melts of long chains polymers are studied. We show that the standard method in which one starts with an ensemble of chains with the correct end-to-end distance arranged randomly in the…
Transport of elementary excitations is a fundamental property of 2D semiconductors, important for wide-ranging emergent phenomena and device applications. While exciton transport reported in 2D materials barely exceeds 1-2 $\mu$m, coherent…
The electronic properties of macromolecular semiconductor thin films depend profoundly on their solid-state microstructure, which in turn is governed, among other things, by the processing conditions selected and the polymer chemical nature…
Large coupling strengths in exciton-photon interactions are important for quantum photonic network, while strong cavity-quantum-dot interactions have been focused on s-shell excitons with small coupling strengths. Here we demonstrate strong…
Conjugated polymers are complex multi-chromophore systems, with emission properties strongly dependent on the electronic energy transfer through active sub-units. Although the packing of the conjugated chains in the solid state is known to…
We consider the scenario of excitons in a semiconductor bilayer that are strongly coupled to cavity photons, leading to the formation of dipolar exciton polaritons (dipolaritons). Using a realistic pseudopotential for the dipolar…
We develop a general theory for how an exciton in an atomically thin transition metal dichacogenide (TMD) monolayer couples to spin and charge correlations in an adjacent moire lattice created by a TMD bi-layer. Virtual tunneling of charge…
We study exciton quantum transfer along a molecular chain whilst accounting for the effects of permanent dipoles that are induced by charge displacements in the molecular orbitals. These effects are typically neglected as they do not arise…