相关论文: Exciton Transfer Integrals Between Polymer Chains
Using electric dipoles to describe light-matter interactions between two entities is a conventional approximation in physics, chemistry, and material sciences. However, the lack of material structures makes the approximation inadequate when…
Component of photoexcited states with large spatial extent is investigated for optical absorption spectra of the electroluminescent conjugated polymers by using the intermediate exciton theory. We calculate the ratio of oscillator strengths…
Theoretically, Josephson junction (JJ) arrays can exhibit either a superconducting or insulating state, separated by a quantum phase transition (QPT). In this work, we analyzed published data on QPTs in three one-dimensional arrays and two…
Evaporation and condensation at a liquid/vapor interface are ubiquitous interphase mass and energy transfer phenomena that are still not well understood. We have carried out large scale molecular dynamics simulations of Lennard-Jones (LJ)…
Exciton transport in molecular aggregates with magic-angle orientation is expected to be strongly suppressed due to their negligible dipole-dipole interactions. However, recent reports show that light-matter interactions can significantly…
The performance of various quantum devices is fundamentally linked to the control of exciton transport. To explore this, we study the exciton transport of the two-dimensional multi-chain systems with different coupling configurations in an…
A microscopic theory for cation diffusion in polymer electrolytes is presented. Based on a thorough analysis of molecular dynamics simulations on PEO with LiBF$_4$ the mechanisms of cation dynamics are characterised. Cation jumps between…
Excitons are spin integer particles that are predicted to condense into a coherent quantum state at sufficiently low temperature, and exciton condensates can be realized at much higher temperature than condensates of atoms because of strong…
Non-Markovian and non-equilibrium phonon effects are believed to be key ingredients in the energy transfer in photosynthetic complexes, especially in complexes which exhibit a regime of intermediate exciton-phonon coupling. In this work, we…
We show that an exciton on a discrete chain of sites can be guided by effective measurements induced by an ambient, non-equilibrium medium that is synchronised to the exciton transport. For experimental verification, we propose a hybrid…
Exciton formation leads to J-bands in solid pentacene. Describing these exciton bands represents a challenge for both time-dependent (TD) density-functional theory (DFT) and for its semiempirical analogue, namely for TD density-functional…
Photosynthetic light harvesting provides a natural blueprint for bioengineered and biomimetic solar energy and light detection technologies. Recent evidence suggests some individual light harvesting protein complexes (LHCs) and LHC subunits…
A polymer network fractures by breaking covalent bonds, but the experimentally measured strength of the polymer network is orders of magnitude lower than the strength of covalent bonds. We investigate the effect of statistical variation of…
Excitons, composite electron-hole quasiparticles, are known to play an important role in optoelectronic phenomena in many semiconducting materials. Recent experiments and theory indicate that the band-gap optics of the newly discovered…
We study exciton energy spectrum and their propagation in moir\'e superlattices formed in transition metal dichalcogenide heterobilayers. In such structures, as a result of weak interlayer interaction, an effective, moir\'e, potential…
We consider a semiconductor polymer chain coupled to a single electromagnetic mode in a cavity. The excitations of the chain have a mixed exciton-photon character and are described as polaritons. Polaritons are coupled to the lattice by the…
The Davydov model of energy transfer in molecular chains is reconsidered assuming the distance dependence of the exciton hopping term. New equations of motion for phonons and excitons are derived within the coherent state approximation.…
We develop a theory of polarized photoluminescence of interface excitons localized at lateral heterojunctions between transition metal dichalcogenide monolayers. We show that the circular selection rules governing interband optical…
Recently, we have derived the changes in the absorption spectrum of an exciton when this exciton is photocreated close to a metal. The resolution of this problem -- which has similarities with Fermi edge singularities -- has been made…
The dispersion energy between extended molecular chains (or equivalently infinite wires) with non-zero band gaps is generally assumed to be expressible as a pair-wise sum of atom-atom terms which decay as $R^{-6}$. Using a model system of…