相关论文: Intramolecular vibrational energy redistribution a…
We develop the formulation of turbulence in terms of the functional integral over the phase space configurations of the vortex cells. The phase space consists of Clebsch coordinates at the surface of the vortex cells plus the Lagrange…
We use the framework of sample space reducing processes (SSR) as an alternative to Boltzmann equation based approaches, to derive the energy and velocity distribution functions of an inelastic gas in a box as an example for a dissipative,…
We extract the dynamics implicit in an algebraic fitted model Hamiltonian for the hydrogen chromophore's vibrational motion in the molecule $CF_3CHFI$. The original model has 4 degrees of freedom, three positions and one representing…
The ultrafast dynamics of azulene have been debated for decades, with reported picosecond decay constants variously attributed to intramolecular vibrational redistribution (IVR), internal conversion, or rotational dephasing. Using…
The two-fluid Interacting Vector Boson Model (IVBM) with the U(6) as a dynamical group possesses a rich algebraic structure of physical interesting subgroups that define its distinct exactly solvable dynamical limits. The classical images…
Quantum dynamics of the Harper model with self-duality exhibits localized, diffusive, and ballistic states depending on the potential strength $V$. By adding time-dependent harmonic perturbations composed of $M$ incommensurate frequencies,…
A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…
A local and distributive algorithm is proposed to find an optimal trial wave-function minimizing the Hamiltonian expectation in a quantum system. To this end, the quantum state of the system is connected to the Gibbs state of a classical…
We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…
In this paper we study continuous time random walks (CTRWs) such that the holding time in each state has a distribution depending on the state itself. For such processes, we provide integro-differential (backward and forward) equations of…
We observe and control a molecular vibrational wave packet in an electronically excited state of the neutral hydrogen molecule. In an extreme-ultraviolet (XUV) transient-absorption experiment we launch a vibrational wave packet in the $D…
Hybrid ion-atom systems provide an excellent platform for studies of state-resolved quantum chemistry at low temperatures, where quantum effects may be prevalent. Here we study theoretically the process of vibrational relaxation of an…
The evolution of the interface propagation in a slowly rotating half-filled horizontal cylinder is studied using MRI. Initially, the cylinder contains two axially segregated bands of small and large particles with a sharp interface. The…
The effect of intermolecular interactions on intensity redistribution between individual electronic transitions in different polymorphs of fluorene and dibenzofuran was studied by transmittance electronic spectroscopy in the energy range…
Heat transport has large potentialities to unveil new physics in mesoscopic systems. A striking illustration is the integer quantum Hall regime, where the robustness of Hall currents limits information accessible from charge transport.…
Two types of spontaneous breaking of the space translational symmetry in distributed chaos have been considered for turbulent thermal convection at large values of Rayleigh number. First type is related to boundaries and second type is…
Observation of internal quantum dynamics relies on correlations between the system being observed and the measurement apparatus. We propose using the center-of-mass (c.m.) degrees of freedom of atoms and molecules as a "built-in" monitoring…
We study the absorbing state transition in particulate systems under spatially inhomogeneous driving using a modified random organization model. For smoothly varying driving the steady state results map onto the homogeneous absorbing state…
We investigate how neutral-ion collisional damping modifies the spectral properties and energy partition of compressible MHD turbulence using a suite of 3D two-fluid simulations. By systematically varying the neutral-ion coupling strength…
The Relativistic Mean Field (RMF) approach describing the motion of independent particles in effective meson fields is extended by a microscopic theory of particle vibrational coupling. It leads to an energy dependence of the relativistic…