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We theoretically explore the effect of a transverse electric field on the frictional response of a bi-layer of packed zwitterionic molecules. The dipole-moment reorientation promoted by the electric field can lead to either stick-slip or…

软凝聚态物质 · 物理学 2024-04-16 Melisa M. Gianetti , Roberto Guerra , Andrea Vanossi , Michael Urbakh , Nicola Manini

Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

We study the fully itinerant dynamics of ultracold but nondegenerate polar molecules with a spin-$1/2$ degree of freedom encoded into two of their electric field dressed rotational states. Center of mass molecular motion is constrained to…

量子气体 · 物理学 2025-06-10 Reuben R. W. Wang , John L. Bohn

We propose a scheme to realize a pseudospin-$1/2$ model of the $^{1}\Sigma(v=0)$ bialkali polar molecules with the spin states corresponding to two sublevels of the first excited rotational level. We show that the effective dipole-dipole…

量子气体 · 物理学 2015-09-30 Y. Deng , S. Yi

Ultracold collisions of the polyatomic species CaOH are considered, in internal states where the collisions should be dominated by long-range dipole-dipole interactions. The computed rate constants suggest that evaporative cooling can be…

化学物理 · 物理学 2019-06-25 Lucie D. Augustovičová , John L. Bohn

Controlling interactions between cold molecules using external fields can elucidate the role of quantum mechanics in molecular collisions. We create a new experimental platform in which ultracold rubidium atoms and cold ammonia molecules…

原子物理 · 物理学 2011-05-24 L. P. Parazzoli , N. J. Fitch , P. S. Zuchowski , J. M. Hutson , H. J. Lewandowski

We report the investigation on dipolar collisions in rotational state mixtures of ultracold bosonic $^{23}$Na$^{87}$Rb molecules. The large resonant dipole-dipole interaction between molecules in rotational states of opposite parities…

原子物理 · 物理学 2021-01-13 Junyu He , Xin Ye , Junyu Lin , Mingyang Guo , Goulven Quéméner , Dajun Wang

Collisions between ultracold calcium monohydroxide (CaOH) molecules are realized and studied. Inelastic collision rate constants are measured for CaOH prepared in ground and excited vibrational states, and the electric field dependence of…

We propose a general protocol for on-demand generation of robust entangled states of nuclear and/or electron spins of ultracold $^1\Sigma$ and $^2\Sigma$ polar molecules using electric dipolar interactions. By encoding a spin-1/2 degree of…

量子物理 · 物理学 2023-04-10 Timur V. Tscherbul , Jun Ye , Ana Maria Rey

Understanding the sources of losses and chemical reactions of ultracold alkali-metal molecules is among the critical elements needed for their application in precision measurements and quantum technologies. Recent experiments with…

量子气体 · 物理学 2022-11-11 Krzysztof Jachymski , Marcin Gronowski , Michał Tomza

Molecules are the building blocks of matter and their control is key to the investigation of new quantum phases, where rich degrees of freedom can be used to encode information and strong interactions can be precisely tuned. Inelastic…

量子气体 · 物理学 2021-01-27 Giacomo Valtolina , Kyle Matsuda , William G. Tobias , Jun-Ru Li , Luigi De Marco , Jun Ye

Trapped samples of ultracold molecules are often short-lived, because close collisions between them result in trap loss. We investigate the use of shielding with static electric fields to create repulsive barriers between polar molecules to…

量子气体 · 物理学 2024-02-20 Bijit Mukherjee , Jeremy M. Hutson

It has recently become possible to form molecules in ultracold gases of trapped alkali metal atoms. Once formed, the molecules may undergo elastic, inelastic and reactive collisions. Inelastic and reactive collisions are particularly…

原子物理 · 物理学 2010-03-09 Jeremy M. Hutson , Pavel Soldan

This paper reviews recent advances in the study of strongly interacting systems of dipolar molecules. Heteronuclear molecules feature large and tunable electric dipole moments, which give rise to long-range and anisotropic dipole-dipole…

量子气体 · 物理学 2016-07-14 Bryce Gadway , Bo Yan

We carry out quantum inelastic scattering calculations of collisions of Rb atoms with inverting NH3 and ND3 molecules in the energy range between 0 and 100 cm-1, which are important for experiments using velocity-controlled molecular beams…

化学物理 · 物理学 2013-05-29 Piotr S. Żuchowski , Jeremy M. Hutson

The observation of significant dipolar effects in gases of ultra-cold polar molecules typically demands a strong external electric field to polarize the molecules. We show that even in the absence of a significant polarization, dipolar…

量子气体 · 物理学 2011-12-20 A. Pikovski , M. Klawunn , A. Recati , L. Santos

We investigate the scattering cross section of aligned dipolar molecules in low-temperature gases. Over a wide range of collision energies relevant to contemporary experiments, the cross section declines in inverse proportion to the…

原子物理 · 物理学 2015-05-13 J. L. Bohn , M. Cavagnero , C. Ticknor

Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

Cold collisions of $^{14}$N$^{16}$O molecules in the $^{2}\Pi_{1/2}$ ground state, subject to electric and magnetic fields, are investigated. It is found that elastic collision rates significantly exceed state-changing inelastic rates only…

原子物理 · 物理学 2017-10-25 Lucie D. Augustovičová , John L. Bohn