相关论文: Supercooled Water: Contradiction to Thermodynamics
The frequent misunderstanding of information entropy is pointed out. It is shown that, contrary to fortuitous situations and common beliefs, there is no general interrelation between the information entropy and the thermodynamical entropy.…
In this paper a thermodynamical derivation of the quantum potential is pro- posed. Within the framework of Bohmian mechanics we show how the quantum potential can be derived, by adding an additional informational degree of freedom to the…
A revised phase diagram for water shows three distinct fluid phases. There is no continuity of liquid and gas and no critical point on Gibbs density surface. A liquid state, water, spans all temperatures. A thermodynamic rigidity function,…
According to conventional wisdom, a system placed in an environment with a different temperature tends to relax to the temperature of the latter, mediated by the flows of heat and/or matter that are set solely by the temperature difference.…
Supercooled first order phase transitions are typical of theories where conformal symmetry is predominantly spontaneously broken. In these theories the fate of the flat scalar direction is highly sensitive to the size and the scaling…
We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal, but have an amount of coherence proportional to a…
Diverse material classes exhibit practically identical behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. The first-principles scaling laws that have been proposed to describe the…
The second law of thermodynamics places a limitation into which states a system can evolve into. For systems in contact with a heat bath, it can be combined with the law of energy conservation, and it says that a system can only evolve into…
Local thermal equilibrium generally implies the absence of heat flux within a fluid. We find the relations between a set of thermodynamic variables of a fluid on a general spacetime and those defined on a conformally connected spacetime,…
We show that a generalized fluctuation-dissipation relation applies upon instantaneously increasing the temperature of a deeply supercooled liquid. This has the same two-step shape of the relation found upon cooling the liquid, but with…
The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…
We investigate the thermodynamic behaviour of a Bose gas interacting with repulsive forces and confined in a harmonic anisotropic trap. We develop the formalism of mean field theory for non uniform systems at finite temperature, based on…
Analysis of power spectrum profiles for various tagged particle quantities in bulk SPC/E water is used to demonstrate that variations in mobility associated with the diffusional anomaly are mirrored in the exponent of the \onebyf\ region.…
On the one hand, the dissipated heat of a thermodynamic work extraction process upper bounds the non-predictive information, which the associated system encodes about its environment. Thus, emergent information processing capabilities can…
The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime,…
A theory accounting for the dynamical aspects of the superfluid response of one dimensional (1D) quantum fluids is reported. In long 1D systems the onset of superfluidity is related to the dynamical suppression of quantum phase slips at low…
One of the most promising frameworks for understanding the anomalies of cold and supercooled water postulates the existence of two competing, interconvertible local structures. If the non-ideality in the Gibbs energy of mixing overcomes the…
We discuss peculiar aspects of the first law of thermodynamics for systems characterized by the presence of meta-equilibrium quasi-stationary states for which the pertinent phase/configuration spaces is generally inhomogeneous. As a…
We investigate an explicit example of how spatial decoherence can lead to hydrodynamic behavior in the late-time, long-wavelength regime of open quantum systems. We focus on the case of a single non-relativistic quantum particle linearly…
This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…