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The classical Second Law of Thermodynamics demands that an isolated system evolves with a non-diminishing entropy. This holds as well in quantum mechanics if the evolution of the energy-isolated system can be described by a unital quantum…
In earlier work we presented a foundation for the Second Law of Classical Thermodynamics in terms of the Entropy Principle. More precisely, we provided an empirically accessible axiomatic derivation of an entropy function defined on all…
In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…
We apply the generalized second law of thermodynamics to discriminate among quantum corrections (whether logarithmic or power-law) to the entropy of the apparent horizon in spatially Friedmann-Robertson-Walker universes. We use the…
Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we…
There are several formulations of the second law, and they may, in principle, have different domains of validity. Here a simple mathematical theorem is proven which serves as the most general basis for the second law, namely the Thomson…
I give a self-contained introduction to the resource theory approach to quantum thermodynamics. I will introduce in an elementary manner the technical machinery necessary to unpack and prove the core statements of the theory. The topics…
The second law of thermodynamics is the cornerstone of physics, characterizing the convertibility between thermodynamic states through a single function, entropy. Given the universal applicability of thermodynamics, a fundamental question…
The physical meaning of entropy is analyzed in the context of statistical, nuclear, atomic physics and cosmology. Only the microcanonical Boltzmann entropy leads to no contradictions in several simple, elementary and for thermodynamics…
If a macroscopic (random) classical system is put into a random state in phase space, it will of course the most likely have an almost maximal entropy according to second law of thermodynamics. We will show, however, the following theorem:…
We design a heat engine with multi-heat-reservoir, ancillary system and quantum memory. We then derive an inequality related with the second law of thermodynamics, and give a new limitation about the work gain from the engine by analyzing…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
A scheme for treating the Second Law of thermodynamics as a constraint and accounting for the approximate nature of constitutive assumptions in continuum thermomechanics is discussed. An unconstrained, concave, variational principle is…
We formulate thermodynamical relations based on the field degrees of freedom by introducing a work induced by the volume change in the function space, in addition to the usual work associated with the spatial volume change. The first and…
We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…
The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…
Majorization is a fundamental model of uncertainty with several applications in areas ranging from thermodynamics to entanglement theory, and constitutes one of the pillars of the resource-theoretic approach to physics. Here, we improve on…
Although its practical efficiency is unquestionable, it is well known that thermodynamics presents conceptual difficulties from the theoretical point of view. It is shown that the problem comes from an imperfect compatibility between the…
Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…
The principle of maximum entropy is a broadly applicable technique for computing a distribution with the least amount of information possible constrained to match empirical data, for instance, feature expectations. We seek to generalize…