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We study the relaxation process of two driven colloidal suspensions in diffusive contact to a steady state, similar to thermalization. We start by studying a single suspension, subjecting it to random driving forces via holographic optical…

软凝聚态物质 · 物理学 2025-05-01 Galor Geva , Tamir Admon , Maayan Levin , Yael Roichman

We discuss phase coexistence of polydisperse colloidal suspensions in the presence of adhesion forces. The combined effect of polydispersity and Baxter's sticky-hard-sphere (SHS) potential, describing hard spheres interacting via strong and…

统计力学 · 物理学 2009-11-11 Domenico Gazzillo , Achille Giacometti , Riccardo Fantoni

We investigate experimentally and theoretically thin layers of colloid particles held adjacent to a solid substrate by gravity. Epifluorescence, confocal, and holographic microscopy, combined with Monte Carlo and hydrodynamic simulations,…

Charged colloidal dispersions make up the basis of a broad range of industrial and commercial products, from paints to coatings and additives in cosmetics. During drying, an initially liquid dispersion of such particles is slowly…

软凝聚态物质 · 物理学 2019-01-07 Lucas Goehring , Joaquim Li , Pree-Cha Kiatkirakajorn

The simplicity of hard spheres as a model system is deceptive. Although the particles interact solely through volume exclusion, that nevertheless suffices for a wealth of static and dynamical phenomena to emerge, making the model an…

Using a carefully justified development of Debye-Huckel theory for highly asymmetric electrolytes, one finds that a region of expanded phase instability, or miscibility gap, can appear for charge-stabilised colloidal suspensions at high…

统计力学 · 物理学 2007-05-23 Patrick B. Warren

Applying an electric field to an aqueous colloidal dispersion establishes a complex interplay of forces among the highly mobile simple ions, the more highly charged but less mobile colloidal spheres, and the surrounding water. This…

软凝聚态物质 · 物理学 2007-05-23 Yilong Han , David G. Grier

The settling of colloidal particles with short-ranged attractions is investigated via highly resolved immersed boundary simulations. At modest volume fractions, we show that inter-colloid attractions lead to clustering that reduces the…

软凝聚态物质 · 物理学 2018-03-29 Andrew M. Fiore , Gang Wang , James W. Swan

We present a theory of effective electrostatic interactions in polydisperse suspensions of charged macroions, generalizing to mixtures a theory previously developed for monodisperse suspensions. Combining linear response theory with a…

软凝聚态物质 · 物理学 2013-08-20 Jun Kyung Chung , Alan R. Denton

A microemulsion of decane droplets stabilized by a non-ionic surfactant film is progressively charged by substitution of a non-ionic surfactant molecule by a cationic surfactant. We check that the microemulsion droplets remain identical…

软凝聚态物质 · 物理学 2016-08-16 Jacqueline Appell , Grégoire Porte , Eric Buhler

The addition of co-solutes to colloidal suspensions is often employed to induce tunable depletion interactions. In this work we investigate effective colloidal interactions arising from binary co-solute mixtures of hard spheres and patchy…

软凝聚态物质 · 物理学 2021-08-25 Philip H. Handle , Emanuela Zaccarelli , Nicoletta Gnan

In charge-stabilized colloidal suspensions, highly charged macroions, dressed by strongly correlated counterions, carry an effective charge that can be substantially reduced (renormalized) from the bare charge. Interactions between dressed…

软凝聚态物质 · 物理学 2011-06-28 Ben Lu , Alan R. Denton

In this article we report on a study of the near-wall dynamics of suspended colloidal hard spheres over a broad range of volume fractions. We present a thorough comparison of experimental data with predictions based on a virial…

A model of shear thickening in dense suspensions of Brownian soft sphere colloidal particles is established. It suggests that shear thickening in soft sphere suspensions can be interpreted as a shear induced phase transition. Based on a…

软凝聚态物质 · 物理学 2015-01-12 Joachim Kaldasch , Bernhard Senge , Jozua Laven

We use a mesoscopic simulation technique to study the effect of short-ranged inter-particle attraction on the steady-state sedimentation of colloidal suspensions. Attractions increase the average sedimentation velocity $v_s$ compared to the…

软凝聚态物质 · 物理学 2010-02-19 A. Moncho Jordá , A. A. Louis , J. T. Padding

We investigate the structure and equilibrium linear-response dynamics of suspensions of hard colloidal dumbbells using Brownian Dynamics computer simulations. The focus lies on the dense fluid and plastic crystal states of the colloids with…

软凝聚态物质 · 物理学 2015-07-10 Nils Heptner , Joachim Dzubiella

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

软凝聚态物质 · 物理学 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

We investigate the rheology, microscopic structure, and dynamics of an industrially relevant dispersion made of cationic surfactant vesicles, from dilute to concentrated conditions. We find that these suspensions exhibit a shear-thinning…

软凝聚态物质 · 物理学 2025-04-29 Nikolaos Kolezakis , Stefano Aime , Raffaele Pastore , Vincenzo Guida , Gaetano D Avino , Paolo Edera

At the surfaces of autophoretic colloids, slip velocities arise from local chemical gradients that are many-body functions of particle configuration and activity. For rapid chemical diffusion, coupled with slip-induced hydrodynamic…

软凝聚态物质 · 物理学 2019-07-29 Rajesh Singh , R. Adhikari , M. E. Cates

The effect of fixed discrete colloidal charges in the primitive model is investigated for spherical macroions. Instead of considering a central bare charge, as it is traditionally done, we distribute \textit{discrete} charges randomly on…

软凝聚态物质 · 物理学 2009-10-31 Rene Messina , Christian Holm , Kurt Kremer