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The structural behaviour of CsCdF3 under pressure is investigated by means of theory and experiment. High-pressure powder x-ray diffraction experiments were performed up to a maximum pressure of 60 GPa using synchrotron radiation. The cubic…

A detailed study of the high-pressure structural properties, lattice dynamics and band structures of perovskite structured fluorides KZnF3, CsCaF3 and BaLiF3 has been carried out by means of density functional theory. The calculated…

材料科学 · 物理学 2016-09-05 Vaitheeswaran G , Kanchana V , Zhang X , Ma Y , Svane A , Christensen NE

First principles study of structural, elastic, and electronic properties of the cubic perovskitetype BaHfO$_3$ has been performed using the plane wave ultrasoft pseudo-potential method based on density functional theory with revised…

材料科学 · 物理学 2008-09-23 Hongsheng Zhao , Aimin Chang , Yunlan Wang

The structural, electronic, optical and vibrational properties of LiN$_3$ under high pressure have been studied using plane wave pseudopotentials within the generalized gradient approximation for the exchange and correlation functional. The…

材料科学 · 物理学 2013-11-07 K. Ramesh Babu , Ch. Bheema Lingam , Surya P. Tewari , G. Vaitheeswaran

Constant-pressure constant-temperature {\it ab initio} molecular dynamics simulations at high temperatures have been used to study MgSiO$_3$ liquid, the major constituent of the Earth's lower mantle to conditions of the Earth's core-mantle…

地球物理 · 物理学 2007-05-23 Jones T. K. Wan , Thomas S. Duffy , Sandro Scandolo , Roberto Car

We have investigated the structural, mechanical, electronic and optical properties of Rb-based cubic perovskite RbBaX$_3$ (X = F, Cl, Br, I) under hydrostatic pressure, using first-principle density functional theory (DFT). All RbBaX$_3$…

材料科学 · 物理学 2024-09-17 Pranti Saha , In Jun Park , Protik Das , Fariborz Kargar

The first-principles calculations have been performed to investigate the ground state properties of cubic scandium trifluoride (ScF$_3$) perovskite. Using modified hybrid exchange-correlation functionals within the density functional theory…

材料科学 · 物理学 2012-11-27 P. Zhgun , D. Bocharov , S. Piskunov , A. Kuzmin , J. Purans

Using the density functional theory (DFT) based first-principles investigation, the structural, mechanical, hardness, elastic anisotropy, optoelectronic, and thermal properties of cubic KB2H8 have been studied within the uniform pressure…

材料科学 · 物理学 2023-11-14 Md. Ashraful Alam , F. Parvin , S. H. Naqib

\emph{Ab-initio} calculations were performed on the scheelite type MGeO$_4$ (M = Hf, and Zr) compounds which find wide range of applications such as in x-ray imaging. We have studied the high pressure structural stability, elastic…

材料科学 · 物理学 2014-05-30 G. Shwetha , V. Kanchana , K. Ramesh Babu , G. Vaitheeswaran , M. C. Valsakumar

Structural stability and vibrational properties of KN$_3$ have been studied under pressure using the first principles calculations based on the density functional theory (DFT) as well as with semi empirical dispersion correction to the DFT…

材料科学 · 物理学 2013-11-08 K. Ramesh Babu , G. Vaitheeswaran

We present a comparative study of the unfilled CoSb3 and FeSb3 skutterudites and report on their compressibility studied by high-pressure synchrotron X-ray diffraction. The equation of state for FeSb3 was received for the first time. The…

材料科学 · 物理学 2016-02-22 P. Alexeev , K. Glazyrin , I. Sergeev , J. Bednarcik , R. P. Hermann

The elastic, thermodynamic, and electronic properties of fluorite RuO_2 under high pressure are investigated by plane-wave pseudopotential density functional theory. The optimized lattice parameters, elastic constants, bulk modulus, and…

材料科学 · 物理学 2017-08-23 Z. J. Yang , A. M. Guo , Y. D. Guo , J. Li , Z. Wang , Q. Liu , R. F. Linghu , X. D. Yang

Germanates are often used as structural analogs of planetary silicates. We have explored the high-pressure phase relations in Mg$_2$GeO$_4$ using diamond anvil cell experiments combined with synchrotron x-ray diffraction and computations…

地球物理 · 物理学 2024-03-06 R. V. Divya , G. Kumar , R. E. Cohen , S. J. Tracy , Y. Meng , S. Chariton , V. B. Prakapenka , R. Dutta

The compression behavior of delafossite compound CuCrO2 has been investigated by in-situ x-ray diffraction and Raman spectroscopic measurements upto 23.2 and 34 GPa respectively. X-ray diffraction data shows the stability of ambient…

材料科学 · 物理学 2015-06-22 Alka B. Garg , A. K. Mishra , K. K. Pandey , Surinder M. Sharma

Antiferromagnetic intermetallic compound EuRhGe3 crystalizes in a non-centrosymmetric BaNiSn3-type (I4mm) structure. We studied its pressure-dependent crystal structure by using synchrotron powder x-ray diffraction at room temperature. Our…

Chalcogenide perovskites offer superior thermal and aqueous stability as well as a benign elemental composition compared to organic halide perovskites for optoelectronic applications. In this study, the structural, electrical, elastic,…

材料科学 · 物理学 2023-05-26 M. D. Kassa , N. G. Debelo , M. M. Woldemariam

We present first-principles density functional theory (DFT) investigations of mechanical, thermodynamic and optical properties of synthesized inverse-perovskites Sc3InX (X = B, C, N). The elastic constants at zero pressure and temperature…

材料科学 · 物理学 2012-11-27 M. A. Hossain , M. S. Ali , F. Parvin , A. K. M. A. Islam

High-pressure phases of the hybrid perovskite MAPbBr3 have been investigated in detail using a novel machine learning force field (MLFF). MLFF simulations successfully reproduce the sequence of pressure-induced phase transitions from the…

材料科学 · 物理学 2025-11-21 Rashid Rafeek V Valappil , Sayan Maity , Varadharajan Srinivasan

We report the pressure dependence of the structural parameters of the non-oxide perovskite superconductor MgCNi$_{3}$ up to 32 GPa using a diamond anvil cell and synchrotron x-rays at room temperature. The structure of the compound remains…

We report on the structural properties of ScAlMgO4 studied under quasi-hydrostatic pressure using synchrotron high-pressure x-ray diffraction up to 40 GPa. We also report on single-crystal studies of ScAlMgO4 performed at 300 K and 100 K.…

材料科学 · 物理学 2011-05-19 D. Errandonea , R. S. Kumar , J. Ruiz-Fuertes , A. Segura , E. Haussuehl
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