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Tunneling of electrons through rotor-stator anthracene aldehyde molecular interfaces is studied with a combined ab initio and model approach. Molecular electronic structure calculated from first principles is utilized to model different…

化学物理 · 物理学 2016-05-27 Irina Petreska , Vladimir Ohanesjan , Ljupco Pejov , Ljupco Kocarev

On-demand control of molecular actions is essential for realizing single-molecule functional devices. Such a control can be achieved by manipulating interactions between individual molecules and their nanoscale environment. In this study,…

化学物理 · 物理学 2024-10-04 Weike Quan , Zihao Wang , Yueqing Shi , Kangkai Liang , Liya Bi , Hao Zhou , Zhiyuan Yin , Wanlu Li , Shaowei Li

We present measurements of magnetic tunnel junctions made using a self-assembled-monolayer molecular barrier. Ni/octanethiol/Ni samples were fabricated in a nanopore geometry. The devices exhibit significant changes in resistance as the…

介观与纳米尺度物理 · 物理学 2010-10-05 J. R. Petta , S. K. Slater , D. C. Ralph

A model describing spin-polarized current via discrete energy levels of a metallic nanoparticle, which has strongly asymmetric tunnel contacts to two ferromagnetic leads, is presented. In absence of spin-relaxation, the model leads to a…

介观与纳米尺度物理 · 物理学 2009-11-13 Y. G. Wei , C. E. Malec , D. Davidović

We report transport measurements through a single-molecule magnet, the Mn12 derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor geometry. Thiol groups connect the molecule to gold electrodes that are fabricated by…

介观与纳米尺度物理 · 物理学 2009-11-11 H. B. Heersche , Z. de Groot , J. A. Folk , H. S. J. van der Zant , C. Romeike , M. R. Wegewijs , L. Zobbi , D. Barreca , E. Tondello , A. Cornia

Using an atomic force microscope we have created nanotube junctions such as buckles and crossings within individual single-wall metallic carbon nanotubes connected to metallic electrodes. The electronic transport properties of these…

介观与纳米尺度物理 · 物理学 2009-10-31 Henk W. Ch. Postma , Mark de Jonge , Zhen Yao , Cees Dekker

The effect on molecular transport due to chemical modification of the metal-molecule interface is investigated, using as an example the prototypical molecular device formed by attaching a p-disubstituted benzene molecule onto two gold…

介观与纳米尺度物理 · 物理学 2009-11-10 Yongqiang Xue , Mark A. Ratner

Molecular-scale components are expected to be central to nanoscale electronic devices. While molecular-scale switching has been reported in atomic quantum point contacts, single-molecule junctions provide the additional flexibility of…

In this article, we report a theoretical analysis of a nanoelectromechanical shuttle based on a multiscale model that combines microscopic electronic structure data with macroscopic dynamics. The microscopic part utilizes a (static) density…

介观与纳米尺度物理 · 物理学 2009-11-11 C. Huldt , J. M. Kinaret

Electron tunneling through a single magnetic barrier in a HgTe topological insulator has been theoretically investigated. We find that the perpendicular magnetic field would not lead to spin-flip of the edge states due to the conservation…

介观与纳米尺度物理 · 物理学 2016-07-21 L. Lin , X. Wu , W. Low , D. Zhang , Zhenhua Wu

Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of…

介观与纳米尺度物理 · 物理学 2011-03-15 R. Härtle , C. Benesch , M. Thoss

Three terminal single-electron transistor devices utilizing Al/Al2O3 gate electrodes were developed for the study of electron transport through individual single-molecule magnets. The devices were patterned via multiple layers of optical…

介观与纳米尺度物理 · 物理学 2009-11-13 J. J. Henderson , C. M. Ramsey , E. del Barco , A. Mishra , G. Christou

It is demonstrated that non-equilibrium vibrational effects are enhanced in molecular devices for which the effective potential for vibrations is sensitive to the charge state of the device. We calculate the electron tunneling current…

介观与纳米尺度物理 · 物理学 2007-05-23 Maarten R. Wegewijs , Katja C. Nowack

For investigation of electron transport on the nanoscale, a system possessing a simple to interpret electronic structure is composed of alkane chains bridging two electrodes via end groups; to date the majority of experiments and…

材料科学 · 物理学 2007-10-01 Giorgos Fagas , James C. Greer

Gold-molecule-gold junctions can be formed by carefully breaking a gold wire in a solution containing dithiolated molecules. Surprisingly, there is little understanding on the mechanical details of the bridge formation process and…

Tunnel transport of interacting spin-polarized electrons through a single-level vibrating quantum dot in external magnetic field is studied. By using density matrix method, the current-voltage characteristics and the dependence of…

介观与纳米尺度物理 · 物理学 2021-03-23 A. D. Shkop , O. M. Bahrova , S. I. Kulinich , I. V. Krive

Scanning tunnelling microscopy and break-junction experiments realize metallic and molecular nanocontacts that act as ideal one-dimensional channels between macroscopic electrodes. Emergent nanoscale phenomena typical of these systems…

介观与纳米尺度物理 · 物理学 2016-06-22 Ryan Requist , Pier Paolo Baruselli , Alexander Smogunov , Michele Fabrizio , Silvio Modesti , Erio Tosatti

We explore theoretically the spin transport in nanostructures consisting of a gold quantum dot bridging nonmagnetic electrodes and two Mn12-Ph single molecule magnets (SMMs) that are thiol-bonded to the dot but are not in direct contact…

介观与纳米尺度物理 · 物理学 2015-06-15 Fatemeh Rostamzadeh Renani , George Kirczenow

The continuing miniaturization of microelectronics raises the prospect of nanometre-scale devices with mechanical and electrical properties that are qualitatively different from those at larger dimensions. The investigation of these…

介观与纳米尺度物理 · 物理学 2009-10-31 A. I. Yanson , G. Rubio Bollinger , H. E. van den Brom , N. Agrait , J. M. van Ruitenbeek

With recent advances in the areas of nanostructure fabrication and molecular spintronics the idea of using single molecule magnets as building blocks for the next generation electronic devices becomes viable. A particular example represents…

介观与纳米尺度物理 · 物理学 2020-03-10 Ivan I. Vrubel , Anastasiia A. Pervishko , Heike Herper , Barbara Brena , Olle Eriksson , Dmitry Yudin