相关论文: Theory of Aging in Structural Glasses
The Adam-Gibbs view of the glass transition relates the relaxation time to the configurational entropy, which goes continuously to zero at the so-called Kauzmann temperature. We examine this scenario in the context of a dimer model with an…
As in the preceding paper we aim at identifying the effective theory that describes the fluctuations of the local overlap with an equilibrium reference configuration close to a putative thermodynamic glass transition. We focus here on the…
The nonexponential relaxation and aging inherent to complex dynamics manifested in a wide variety of dissipative systems is analyzed through a model of diffusion in phase space in the presence of a nonconservative force. The action of this…
Recent progresses in the description of glassy relaxation and ageing are reviewed for the wide class of network-forming materials such as $GeO_2$, Ge$_x$Se$_{1-x}$, silicates (SiO$_2$-Na$_2$O) or borates (B$_2$O$_3$-Li$_2$O), all of them…
We discuss a theoretical approach to structural glasses as they happen in real situations. Older ideas based on `configurational entropy', on `fictive temperatures' and on Edwards' `compactivity' are sharpened and unified in an out of…
Theoretical approaches are formulated to investigate the molecular mobility under various cooling rates of amorphous drugs. We describe the structural relaxation of a tagged molecule as a coupled process of cage-scale dynamics and…
A microscopically motivated theory of glassy dynamics based on an underlying random first order transition is developed to explain the magnitude of free energy barriers for glassy relaxation. A variety of empirical correlations embodied in…
Using a general model for the equilibrium dynamics of supercooled liquids, I compute from molecular properties the emergent length and time scales that govern the nonequilibrium relaxation behavior of amorphous ice prepared by rapid…
We report a novel approach based on the non-equilibrium self-consistent generalized Langevin equation (NESCGLE) theory that allows for the first principles prediction of the zero-shear viscosity in glass- and- gel-forming materials. This…
A popular Adam--Gibbs scenario has suggested that the excess entropy of glass and liquid over crystal dominates the dynamical arrest at the glass transition with exclusive contribution from configurational entropy over vibrational entropy.…
We numerically analyze the statistics of the heat flow between an aging system and its thermal bath, following a method proposed and tested for a spin-glass model in a recent Letter (P. Sibani and H.J. Jensen, Europhys. Lett.69, 563…
We demonstrate that the application of any external uniform non-abelian gauge background, no matter how small, leads to a greatly enhanced degeneracy. This degeneracy is so large that even a non-abelian background field of infinitesimal…
We study the growing time scales and length scales associated with dynamical slow down for a realistic glass former, using computer simulations. We perform finite size scaling to evaluate a length scale associated with dynamical…
The presence of dynamical heterogeneities, i.e. nanometer-scale regions containing molecules rearranging cooperatively at very different rates compared to the bulk, is increasingly being recognized as crucial in our understanding of the…
The slow non-equilibrium dynamics of the Edwards-Anderson spin glass model on a hierarchical lattice is studied by means of a coarse-grained description based on renormalization concepts. We evaluate the isothermal aging properties and show…
A spin glass is a diluted magnetic material in which the magnetic moments are randomly interacting, with a huge number of metastable states which prevent reaching equilibrium. Spin-glass models are conceptually simple, but require very…
The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…
Among amorphous states, glass is defined by relaxation times longer than the observation time. This nonergodic nature makes the understanding of glassy systems an involved topic, with complex aging effects or responses to further…
We have recently applied the second law to an isolated system, consisting of a system {\Sigma} such as a glass surrounded by an extremely large medium {\Sigma}, to show that the instantaneous temperature T(t), thermodynamic entropy S(T_0,t)…
We study numerically temperature-shift and field-shift aging protocols on the 3-dimensional (3D) Ising Edwards-Anderson (EA) spin-glass (SG) model focusing on respectively the temperature-chaos nature and the stability under a static field…