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Electron energy loss near edge spectra (ELNES) has been calculated for two different Fe based superconducting material FeSe and FeTe using density functional theory (DFT). Fe K-edge absorption spectra consist of several features, origins of…

超导电性 · 物理学 2021-08-11 Soumyadeep Ghosh , Haranath Ghosh

We present XANE(3), a physics-based E(3)-equivariant graph neural network for predicting X-ray absorption near-edge structure (XANES) spectra directly from atomic structures. The model combines tensor-product message passing with spherical…

机器学习 · 计算机科学 2026-04-15 Vitor F. Grizzi , Luke N. Pretzie , Jiayi Xu , Cong Liu

In this work we present an interpretation of experimental O K-edge x-ray absorption near edge structure (XANES) in perovskite-type WO3 and AWO3 compounds (A = H and Na) using three different first principles approaches: (i)…

材料科学 · 物理学 2010-09-01 Dmitry Bocharov , Alexei Kuzmin , Juris Purans , Yuri Zhukovskii

Rare-earth L$_{3}$-edge X-ray absorption near edge structure (XANES) spectroscopy has been used to study REOFeAs (RE=La, Pr, Nd, Sm) oxypnictides. The Nd L$_{3}$ XANES due to 2p$_{3/2}\to5\epsilon$d transition shows a substantial change in…

超导电性 · 物理学 2009-10-13 B. Joseph , A. Iadecola , M. Fratini , A. Bianconi , A. Marcelli , N. L. Saini

X-ray absorption near edge structure (XANES) is an essential tool for elucidating the atomic-scale, local three-dimensional (3D) structure of given materials and molecules. The rapid computation of XANES based on molecular 3D structures…

化学物理 · 物理学 2026-02-24 Fei Zhan , Zhi Geng

We present a reciprocal-space pseudopotential scheme for calculating X-ray absorption near-edge structure (XANES) spectra. The scheme incorporates a recursive method to compute absorption cross section as a continued fraction. The continued…

凝聚态物理 · 物理学 2009-11-07 Mathieu Taillefumier , Delphine Cabaret , Anne-Marie Flank , Francesco Mauri

X-ray absorption fine-structure (XAFS) measurements supported by {\em ab initio} computations within the density functional theory (DFT) are employed to systematically characterize Fe-doped as well as Fe and Si-co-doped films grown by…

X-ray absorption near edge structure (XANES) spectroscopy is a powerful technique for characterizing the chemical state and symmetry of individual elements within materials, but requires collecting data at many energy points which can be…

应用物理 · 物理学 2025-04-25 Ming Du , Mark Wolfman , Chengjun Sun , Shelly D. Kelly , Mathew J. Cherukara

This paper presents the X-ray absorption near edge structure (XANES) and X-ray photoelectron spectroscopic (XPS) studies of Nd doped phosphate glasses before and after gamma irradiation. The intensity and location of LIII edge white line…

材料科学 · 物理学 2015-01-16 V. N. Rai , Parasmani Rajput , S. N. Jha , D. Bhattacharya , B. N. Raja Shekhar

Fe K-edge and Se K-edge x-ray absorption near edge structure (XANES) measurements are used to study FeSe$_{1-x}$Te$_{x}$ electronic structure of chalcogenides. An intense Fe K-edge pre-edge peak due to Fe 1s$\to$3d (and admixed Se/Te $p$…

超导电性 · 物理学 2010-12-08 B. Joseph , A. Iadecola , L. Simonelli , Y. Mizuguchi , Y. Takano , T. Mizokawa , N. L. Saini

X-ray absorption spectroscopy is a premier element-specific technique for materials characterization. Specifically, the x-ray absorption near-edge structure (XANES) encodes important information about the local chemical environment of an…

材料科学 · 物理学 2019-03-27 Matthew R. Carbone , Shinjae Yoo , Mehmet Topsakal , Deyu Lu

This paper provides a brief overview of applications of advanced X-ray spectroscopic techniques that take advantage of the resonant inelastic X-ray scattering (RIXS) in the hard and tender x-ray range and have recently become available for…

材料科学 · 物理学 2014-01-08 K. O. Kvashnina , S. M. Butorin

X-ray absorption spectroscopy (XAS) is a commonly-employed technique for characterizing functional materials. In particular, x-ray absorption near edge spectra (XANES) encodes local coordination and electronic information and machine…

We determine the structural relaxations around paramagnetic impurities (Ti, Cr, Fe) in corundum (alpha-Al2O3), by combining x-ray absorption near edge structure (XANES) experiments and ab initio calculations. The structural relaxations are…

Developing characterization techniques and analysis methods adapted to the investigation of nanoparticles (NPs) is of fundamental importance considering the role of these materials in many fields of research. The study of actinide based…

X-ray absorption fine structure (XAFS) and x-ray emission spectroscopy (XES) are advanced x-ray spectroscopies that impact a wide range of disciplines. However, unlike the majority of other spectroscopic methods, XAFS and XES are…

Widely employed Near-Edge X-Ray Absorption Fine Structure (NEXAFS) spectroscopy probes a system by excitation of core electrons to unoccupied states. A variety of different methodologies are available to simulate corresponding spectra from…

化学物理 · 物理学 2019-02-14 Georg S. Michelitsch , Karsten Reuter

The theoretical description of photoemission spectra of transition metals was greatly improved recently by accounting for the correlations between the d electrons within the local spin density approximation (LSDA) plus dynamical mean field…

强关联电子 · 物理学 2013-03-22 O. Sipr , J. Minar , A. Scherz , H. Wende , H. Ebert

A new technical method is developed for soft x-ray spectroscopy of near-edge x-ray absorption fine structure (NEXAFS). The measurement is performed with continuously rotating linearly polarized light over 2$\pi$, generated by a segmented…

仪器与探测器 · 物理学 2021-11-10 Yoshiki Kudo , Yasuyuki Hirata , Masafumi Horio , Masahito Niibe , Iwao Matsuda

We report the near-edge x-ray absorption fine structure (NEXAFS) spectrum of a single layer of graphite (graphene) obtained by micromechanical cleavage of Highly Ordered Pyrolytic Graphite (HOPG) on a SiO2 substrate. We utilized a…

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