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Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…

统计力学 · 物理学 2026-04-15 Haim Diamant , Gil Ariel

The problem of estimating entropy production from incomplete information in stochastic thermodynamics is essential for theory and experiments. Whereas a considerable amount of work has been done on this topic, arguably, most of it is…

统计力学 · 物理学 2024-12-17 Pedro E. Harunari , Carlos E. Fiore , Andre C. Barato

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

统计力学 · 物理学 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

We give meaning to the first and second laws of thermodynamics in case of mesoscopic out-of-equilibrium systems which are driven by diffusion processes. The notion of the entropy production is analyzed. The role of the Helmholtz extremum…

统计力学 · 物理学 2008-11-26 Piotr Garbaczewski

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

统计力学 · 物理学 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…

数据分析、统计与概率 · 物理学 2007-05-23 Xiaochun Mei

During a spontaneous change, a macroscopic physical system will evolve towards a macro-state with more realizations. This observation is at the basis of the Statistical Mechanical version of the Second Law of Thermodynamics, and it provides…

统计力学 · 物理学 2020-04-22 Mengjie Zu , Arunkumar Bupathy , Daan Frenkel , Srikanth Sastry

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

统计力学 · 物理学 2007-05-23 Giovanni Gallavotti

A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…

统计力学 · 物理学 2016-11-23 Robert H. Swendsen

The deep connection between entropy and information is discussed in terms of both classical and quantum physics. The mechanism of information transfer between systems via entanglement is explored in the context of decoherence theory. The…

量子物理 · 物理学 2021-01-05 Martin Paul Vaughan

There is a relation between the irreversibility of thermodynamic processes as expressed by the breaking of time-reversal symmetry, and the entropy production in such processes. We explain on an elementary mathematical level the relations…

统计力学 · 物理学 2007-05-23 C. Maes , K. Netocny

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

数学物理 · 物理学 2015-06-19 Elliott H. Lieb , Jakob Yngvason

Different notions of entropy play a fundamental role in the classical theory of dynamical systems. Unlike many other concepts used to analyze autonomous dynamics, both measure-theoretic and topological entropy can be extended quite…

动力系统 · 数学 2017-08-03 Christoph Kawan

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

统计力学 · 物理学 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…

chao-dyn · 物理学 2008-02-03 Z. Hens , X. de Hemptinne

It is well known that entropy production is a proxy to the detection of non-equilibrium, i.e. of the absence of detailed balance; however, due to the global character of this quantity, its knowledge does not allow to identify spatial…

统计力学 · 物理学 2021-09-01 Camilla Sarra , Marco Baldovin , Angelo Vulpiani

Entropy is a very useful concept from physics that tries to explain how a system behaves from a point of view of the thermodynamics. However, there are two ways to explain entropy, and it depends on if we are studying a microsystem or a…

综合金融 · 定量金融 2024-07-02 Martin Pomares Calero

Fluctuating entropy production is studied for a set of linearly coupled complex fields. The general result is applied to non-equilibrium fluctuating hydrodynamic equations for coarse-grained fields (density, temperature and velocity), in…

统计力学 · 物理学 2012-07-09 Giacomo Gradenigo , Andrea Puglisi , Alessandro Sarracino

Information entropy is applied to the analysis of time series generated by dynamical systems. Complexity of a temporal or spatio-temporal signal is defined as the difference between the sum of entropies of the local linear regions of the…

混沌动力学 · 物理学 2009-11-10 Milan Rajkovic

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

统计力学 · 物理学 2020-08-28 Philipp Strasberg
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