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相关论文: Predicting phase equilibria in polydisperse system…

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Large-scale Monte Carlo simulations of a phase-separating colloid-polymer mixture are performed and compared to recent experiments. The approach is based on effective interaction potentials in which the central monomers of self-avoiding…

软凝聚态物质 · 物理学 2007-05-23 R. L. C. Vink , A. Jusufi , J. Dzubiella , C. N. Likos

Colloid-polymer mixtures may undergo either fluid-fluid phase separation or gelation. This depends on the depth of the quench (polymer concentration) and polymer-colloid size ratio. We present a real-space study of dynamics in phase…

软凝聚态物质 · 物理学 2012-09-19 Isla Zhang , C. Patrick Royall , Paul Bartlett , Malcolm A. Faers

We investigate both ensemble and time-averaged mean-squared displacements of particles in a polydisperse granular system in a homogeneous cooling state. The system contains an arbitrary number of species of different sizes and masses. The…

软凝聚态物质 · 物理学 2024-09-20 Anna S. Bodrova , Alexander I. Osinsky

Colloidal suspensions with free polymer coils which are larger than the colloidal particles are considered. The polymer-colloid interaction is modeled by an extension of the Asakura-Oosawa model. Phase separation occurs into dilute and…

软凝聚态物质 · 物理学 2009-10-31 Richard P. Sear

We use a Fundamental-Measure density functional for hard board-like polydisperse particles, in the restricted-orientation approximation, to explain the phase behaviour of platelet colloidal suspensions studied in recent experiments. In…

软凝聚态物质 · 物理学 2015-06-05 Yuri Martinez Raton , Enrique Velasco

We present a generalized hydrodynamic stability theory for interacting particles in polydisperse particle-laden flows. The addition of dispersed particulate matter to a clean flow can either stabilize or destabilize the flow, depending on…

流体动力学 · 物理学 2022-04-20 Zhixuan Liu , Yuval Dagan

By analytically solving some simple models of phase-ordering kinetics, we suggest a mechanism for the onset of non-equilibrium behaviour in colloid-polymer mixtures. These mixtures can function as models of atomic systems; their physics…

软凝聚态物质 · 物理学 2016-08-31 R. M. L. Evans , W. C. K. Poon

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

软凝聚态物质 · 物理学 2020-05-27 Efe Ilker , Jean-François Joanny

We study the theoretical phase behavior of an asymmetric binary mixture of hard spheres, of which the smaller component is monodisperse and the larger component is polydisperse. The interactions are modelled in terms of the second virial…

统计力学 · 物理学 2019-12-09 Luka Sturtewagen , Erik van der Linden

Both polydispersity and the presence of a gravitational field are inherent to essentially any colloidal experiment. While several theoretical works have focused on the effect of polydispersity on the bulk phase behavior of a colloidal…

软凝聚态物质 · 物理学 2022-12-28 Tobias Eckert , Matthias Schmidt , Daniel de las Heras

The presence of nanoparticles in a diblock copolymer leads to changes in the morphology and properties of the matrix and can produce highly organized hybrid materials. The resulting material properties depend not only on the polymer…

软凝聚态物质 · 物理学 2018-05-30 Javier Diaz , Marco Pinna , Andrei Zvelindovsky , Adelchi Asta , Ignacio Pagonabarraga

Polydispersity is inevitable in industrially produced polymers. Established theories of polymer dynamics and rheology, however, were mostly built on monodisperse linear polymers. Dynamics of polydisperse polymers is yet to be fully explored…

软凝聚态物质 · 物理学 2021-06-29 Oluseye Adeyemi , Shiping Zhu , Li Xi

The phase behavior of a system composed of spherical particles with a monomodal size distribution is investigated theoretically within the context of the van der Waals approximation for polydisperse fluids. It is shown how the binodals,…

统计力学 · 物理学 2009-10-31 L. Bellier-Castella , H. Xu , M. Baus

Progress in the research area of colloidal dispersions in external fields within the last years is reviewed. Colloidal dispersions play a pivotal role as model systems for phase transitions in classical statistical mechanics. In recent…

软凝聚态物质 · 物理学 2013-11-26 Hartmut Löwen

We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter's one is considered. The choice of factorizable…

统计力学 · 物理学 2009-11-07 Domenico Gazzillo , Achille Giacometti

A new type of phase separation in the polyelectrolyte solutions consisting of several types of charged macromolecules differing in their degree of ionization is predicted via a general thermodynamic consideration. We show that even a small…

软凝聚态物质 · 物理学 2011-11-09 Igor Erukhimovich , Monica Olvera de la Cruz

The addition of enough non-adsorbing polymer to an otherwise stable colloidal suspension gives rise to a variety of phase behavior and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a…

软凝聚态物质 · 物理学 2024-06-19 Sam E Griffiths , Nick Koumakis , Aidan T Brown , Teun Vissers , Patrick B Warren , Wilson C K Poon

We describe how Monte Carlo simulation within the grand canonical ensemble can be applied to the study of phase behaviour in polydisperse fluids. Attention is focused on the case of fixed polydispersity in which the form of the `parent'…

统计力学 · 物理学 2009-11-10 Nigel B. Wilding , Peter Sollich

A polydisperse system contains particles with at least one attribute $\sigma$ (such as particle size in colloids or chain length in polymers) which takes values in a continuous range. It therefore has an infinite number of conserved…

软凝聚态物质 · 物理学 2007-05-23 Peter Sollich , Patrick B Warren , Michael E Cates

Partitioning of (bio)materials in polymeric mixtures is a key phenomenon both in cellular environments, as well as in industrial applications. In cells, several macromolecules are suspended within different biomolecular phases. On the other…

软凝聚态物质 · 物理学 2025-10-15 Vikki Anand Varma , Alberto Scacchi