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The enormous structural and chemical diversity of metal-organic frameworks (MOFs) forces researchers to actively use simulation techniques on an equal footing with experiments. MOFs are widely known for outstanding adsorption properties, so…

材料科学 · 物理学 2021-11-22 Vadim V. Korolev , Yurii M. Nevolin , Thomas A. Manz , Pavel V. Protsenko

Widely employed Near-Edge X-Ray Absorption Fine Structure (NEXAFS) spectroscopy probes a system by excitation of core electrons to unoccupied states. A variety of different methodologies are available to simulate corresponding spectra from…

化学物理 · 物理学 2019-02-14 Georg S. Michelitsch , Karsten Reuter

This paper investigates the critical problem of representation similarity evolution during cross-domain transfer learning, with particular focus on understanding why pre-trained models maintain effectiveness when adapted to medical imaging…

计算机视觉与模式识别 · 计算机科学 2025-03-12 Wenqiang Zu , Shenghao Xie , Hao Chen , Lei Ma

A classical density functional theory is applied to study solvation of solutes in water. An approx- imate form of the excess functional is proposed for water. This functional requires the knowledge of pure solvent direct correlation…

化学物理 · 物理学 2014-09-01 Guillaume Jeanmairet

Motivated by multi-task and meta-learning approaches, we consider the problem of learning structure shared by tasks or users, such as shared low-rank representations or clustered structures. While all previous works focus on well-specified…

机器学习 · 计算机科学 2025-02-14 Mathieu Even , Laurent Massoulié

Among many current data processing systems, the objectives are often not the reproduction of data, but to compute some answers based on the data resulting from queries. The similarity identification task is to identify the items in a…

信号处理 · 电气工程与系统科学 2020-01-23 Hanwei Wu , Qiwen Wang , Markus Flierl

Empirical fitting of parameters in approximate density functionals is common. Such fits conflate errors in the self-consistent density with errors in the energy functional, but density-corrected DFT (DC-DFT) separates these two. We…

化学物理 · 物理学 2020-12-02 Suhwan Song , Stefan Vuckovic , Eunji Sim , Kieron Burke

Neural networks can emulate nonlinear physical systems with high accuracy, yet they may produce physically-inconsistent results when violating fundamental constraints. Here, we introduce a systematic way of enforcing nonlinear analytic…

计算物理 · 物理学 2021-03-10 Tom Beucler , Michael Pritchard , Stephan Rasp , Jordan Ott , Pierre Baldi , Pierre Gentine

Current sparse autoencoder (SAE) approaches to neural network interpretability assume that activations can be decomposed through linear superposition into sparse, interpretable features. Despite high reconstruction fidelity, SAEs…

神经元与认知 · 定量生物学 2025-12-10 Omar Claflin

Coupled cluster theory with a Kohn-Sham reference (KS-CC) can dramatically outperform its Hartree-Fock counterpart for strongly correlated systems, but the origin of these improvements has remained unclear. Here we demonstrate that these…

Most existing works on continual learning (CL) focus on overcoming the catastrophic forgetting (CF) problem, with dynamic models and replay methods performing exceptionally well. However, since current works tend to assume exclusivity or…

计算机视觉与模式识别 · 计算机科学 2022-10-13 Sijia Wang , Yoojin Choi , Junya Chen , Mostafa El-Khamy , Ricardo Henao

We identify the key property that the exchange-correlation (XC) kernel of time-dependent density functional theory must have in order to describe long-range charge-transfer excitations. We show that the discontinuity of the XC potential as…

介观与纳米尺度物理 · 物理学 2015-05-30 M. Hellgren , E. K. U. Gross

Having similar code fragments, also called clones, in software systems can lead to unnecessary comprehension, review and change efforts. Syntactically similar clones can often be encountered in practice. The same is not clear for only…

软件工程 · 计算机科学 2018-05-23 Verena Käfer , Stefan Wagner , Rainer Koschke

New density functional theory approach based on a complete active space self-consistent field (CASSCF) reference function in Extended Koopmans' approximation is discussed. Recently, the number of generalizations of density functional theory…

化学物理 · 物理学 2018-02-15 Sergey Gusarov , Yurii Dmitriev

We have developed and implemented a self-consistent density functional method using standard norm-conserving pseudopotentials and a flexible, numerical LCAO basis set, which includes multiple-zeta and polarization orbitals. Exchange and…

We assess the accuracy of common hybrid exchange-correlation (XC) functionals (PBE0, PBE0-1/3, HSE06, HSE03, and B3LYP) within Kohn-Sham density functional theory (KS-DFT) for the harmonically perturbed electron gas at parameters relevant…

化学物理 · 物理学 2023-03-08 Zhandos A. Moldabekov , Mani Lokamani , Jan Vorberger , Attila Cangi , Tobias Dornheim

Approximate functionals used in practical density functional theory (DFT) deviate from the piecewise linear behavior of the exact functional for fractional charges. This deviation causes excess charge delocalization, which leads to…

化学物理 · 物理学 2018-10-23 Diptarka Hait , Martin Head-Gordon

We study the ability of foundation models to learn representations for classification that are transferable to new, unseen classes. Recent results in the literature show that representations learned by a single classifier over many classes…

机器学习 · 计算机科学 2022-01-05 Tomer Galanti , András György , Marcus Hutter

Detecting semantically similar functions -- a crucial analysis capability with broad real-world security usages including vulnerability detection, malware lineage, and forensics -- requires understanding function behaviors and intentions.…

密码学与安全 · 计算机科学 2021-04-28 Kexin Pei , Zhou Xuan , Junfeng Yang , Suman Jana , Baishakhi Ray