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The conventional approaches to the inverse density functional theory problem typically assume non-degeneracy of the Kohn-Sham (KS) eigenvalues, greatly hindering their use in open-shell systems. We present a generalization of the inverse…

化学物理 · 物理学 2024-01-09 Bikash Kanungo , Jeffrey Hatch , Paul M. Zimmerman , Vikram Gavini

Weak-memory models are standard formal specifications of concurrency across hardware, programming languages, and distributed systems. A fundamental computational problem is consistency testing: is the observed execution of a concurrent…

编程语言 · 计算机科学 2023-11-16 Soham Chakraborty , Shankaranarayanan Krishna , Umang Mathur , Andreas Pavlogiannis

A learning task, understood as the problem of fitting a parametric model from supervised data, fundamentally requires the dataset to be large enough to be representative of the underlying distribution of the source. When data is limited,…

We present the covariance analysis of two successful nuclear energy density functionals, (i) a non-relativistic Skyrme functional built from a zero-range effective interaction, and (ii) a relativistic nuclear energy density functional based…

核理论 · 物理学 2016-11-25 X. Roca-Maza , N. Paar , G. Colò

The accuracy of density-functional theory (DFT) is determined by the quality of the approximate functionals, such as exchange-correlation in electronic DFT and the excess functional in the classical DFT formalism of fluids. The exact…

In this work, we explore the intersection of sparse coding theory and deep learning to enhance our understanding of feature extraction capabilities in advanced neural network architectures. We begin by introducing a novel class of Deep…

机器学习 · 计算机科学 2025-12-05 Jianfei Li , Han Feng , Ding-Xuan Zhou

The key feature of nonlocal kinetic energy functionals is their ability to reduce to the Thomas-Fermi functional in the regions of high density and to the von Weizs\"acker functional in the region of low density/high density gradient. This…

材料科学 · 物理学 2021-03-31 Xuecheng Shao , Wenhui Mi , Michele Pavanello

The cloning of quantum variables with continuous spectra is investigated. We define a Gaussian 1-to-2 cloning machine, which copies equally well two conjugate variables such as position and momentum or the two quadrature components of a…

量子物理 · 物理学 2007-05-23 N. J. Cerf , S. Iblisdir , G. Van Assche

The prominence of density functional theory (DFT) in the field of electronic structure computation stems from its ability to usefully balance accuracy and computational effort. At the base of this ability is a functional of the electron…

We study model one-dimensional chemical systems (representative of their three-dimensional counterparts) using the strictly-correlated electrons (SCE) functional, which, by construction, becomes asymptotically exact in the limit of infinite…

A new framework is presented for evaluating the performance of self-consistent field methods in Kohn-Sham density functional theory. The aims of this work are two-fold. First, we explore the properties of Kohn-Sham density functional theory…

计算物理 · 物理学 2019-07-18 Nick Woods , Phil Hasnip , Mike Payne

Density scaling has a rich history in density functional theory, providing exact conditions for use in the construction of ever more accurate approximations to the unknown exchange-correlation functional. We define a conjugate potential…

其他凝聚态物理 · 物理学 2009-06-02 Peter Elliott , Kieron Burke

The solution of complex many-body lattice models can often be found by defining an energy functional of the relevant density of the problem. For instance, in the case of the Hubbard model the spin-resolved site occupation is enough to…

强关联电子 · 物理学 2019-02-20 James Nelson , Rajarshi Tiwari , Stefano Sanvito

The electron density of a molecule or material has recently received major attention as a target quantity of machine-learning models. A natural choice to construct a model that yields transferable and linear-scaling predictions is to…

化学物理 · 物理学 2022-06-29 Andrea Grisafi , Alan M. Lewis , Mariana Rossi , Michele Ceriotti

Clustering analysis of functional data, which comprises observations that evolve continuously over time or space, has gained increasing attention across various scientific disciplines. Practical applications often involve functional data…

统计方法学 · 统计学 2024-06-19 Tingyu Zhu , Lan Xue , Carmen Tekwe , Keith Diaz , Mark Benden , Roger Zoh

Convolutional neural networks use pooling and other downscaling operations to maintain translational invariance for detection of features, but in their architecture they do not explicitly maintain a representation of the locations of the…

计算机视觉与模式识别 · 计算机科学 2021-03-16 Prem Nair , Rohan Doshi , Stefan Keselj

Understanding the functional (dis)-similarity of source code is significant for code modeling tasks such as software vulnerability and code clone detection. We present DISCO(DIS-similarity of COde), a novel self-supervised model focusing on…

编程语言 · 计算机科学 2022-03-22 Yangruibo Ding , Luca Buratti , Saurabh Pujar , Alessandro Morari , Baishakhi Ray , Saikat Chakraborty

In principle, machine learning (ML) can be used to obtain any electronic property of a many-body system from its electron density within density functional theory. However, some physical quantities are highly sensitive to small variations…

材料科学 · 物理学 2026-02-19 L. Arnstein , J. Wetherell , R. Lawrence , P. J. Hasnip , M. J. P. Hodgson

Neural operators are capable of capturing nonlinear mappings between infinite-dimensional functional spaces, offering a data-driven approach to modeling complex functional relationships in classical density functional theory (cDFT). In this…

In this work, we extend the source-free (SF) exchange correlation (XC) functional developed by Sangeeta Sharma and co-workers to plane-wave density functional theory (DFT) based on the projector augmented wave (PAW) method. This constraint…