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We show how thermodynamic properties of molecular models can be computed over a large, multidimensional parameter space by combining multistate reweighting analysis with a linear basis function approach. This approach reduces the…

化学物理 · 物理学 2016-05-18 Levi N. Naden , Michael R. Shirts

The free energy of a system is central to many material models. Although free energy data is not generally found directly, its derivatives can be observed or calculated. In this work, we present an Integrable Deep Neural Network (IDNN) that…

材料科学 · 物理学 2019-06-26 G. H. Teichert , A. R. Natarajan , A. Van der Ven , K. Garikipati

The multistate Bennett acceptance ratio (MBAR) method is a prevalent approach for computing free energies of thermodynamic states. In this work, we introduce BayesMBAR, a Bayesian generalization of the MBAR method. By integrating…

化学物理 · 物理学 2024-02-16 Xinqiang Ding

We present a differentiable formalism for learning free energies that is capable of capturing arbitrarily complex model dependencies on coarse-grained coordinates and finite-temperature response to variation of general system parameters.…

A common approach to study nucleation rates is the estimation of free-energy barriers. This usually requires knowledge about the shape of the forming droplet, a task that becomes notoriously difficult in macromolecular setups starting with…

统计力学 · 物理学 2017-03-28 Johannes Zierenberg , Philipp Schierz , Wolfhard Janke

Recent development in computer processing power leads to new paradigms of how problems in many-body physics and especially polymer physics can be addressed. GPU parallel processors can be employed to generate millions of independent…

软凝聚态物质 · 物理学 2019-05-01 Marco Werner , Yachong Guo , Vladimir A. Baulin

Accurate, yet computationally efficient energy functions are essential for state-of-the art molecular dynamics (MD) studies of condensed phase systems. Here, a generic workflow based on a combination of machine learning-based and empirical…

化学物理 · 物理学 2025-07-01 Eric D. Boittier , Silvan Käser , Markus Meuwly

Machine learning techniques including neural networks are popular tools for materials and chemical scientists with applications that may provide viable alternative methods in the analysis of structure and energetics of systems ranging from…

统计力学 · 物理学 2022-03-02 James Andrews , Olga Gkountouna , Estela Blaisten-Barojas

In this PhD thesis, we explore and apply methods inspired by the free energy principle to two important areas in machine learning and neuroscience. The free energy principle is a general mathematical theory of the necessary…

人工智能 · 计算机科学 2021-08-31 Beren Millidge

A new approach for efficiently exploring the configuration space and computing the free energy of large atomic and molecular systems is proposed, motivated by an analogy with reinforcement learning. There are two major components in this…

化学物理 · 物理学 2018-04-18 Linfeng Zhang , Han Wang , Weinan E

We describe the development of machine-learned potentials of atmospheric gases with flexible monomers for molecular simulations. A recently suggested permutationally invariant polynomial neural network (PIP-NN) approach is utilized to…

化学物理 · 物理学 2025-04-21 Artem Finenko

This report presents the application of polynomial regression for estimating free energy differences using thermodynamic integration. We employ linear regression to construct a polynomial that optimally fits the thermodynamic integration…

计算物理 · 物理学 2008-10-02 Conrad Shyu , F. Marty Ytreberg

Polymer-surface interactions are crucial to many biological processes and industrial applications. Here we propose a machine-learning method to connect a model polymer's sequence with its adhesion to decorated surfaces. We simulate the…

软凝聚态物质 · 物理学 2021-10-08 Jiale Shi , Michael J. Quevillon , Pedro H. Amorim Valença , Jonathan K. Whitmer

The conformational free energy landscape of a system is a fundamental thermodynamic quantity of importance particularly in the study of soft matter and biological systems, in which the entropic contributions play a dominant role. While…

生物物理 · 物理学 2015-10-13 N. Ramakrishnan , Richard W. Tourdot , Ravi Radhakrishnan

During fast diffusion-influenced polymerization, nonequilibrium behavior of the polymer chains and the surrounding reactive monomers has been reported recently. Based on the laws of thermodynamics, the emerging nonequilibrium structures…

软凝聚态物质 · 物理学 2022-03-14 Michael Bley , Joachim Dzubiella

The free energy plays a fundamental role in descriptions of many systems in continuum physics. Notably, in multiphysics applications, it encodes thermodynamic coupling between different fields. It thereby gives rise to driving forces on the…

机器学习 · 计算机科学 2023-07-19 Gregory Teichert , Anirudh Natarajan , Anton Van der Ven , Krishna Garikipati

Computational modeling is an integral part of catalysis research. With it, new methodologies are being developed and implemented to improve the accuracy of simulations while reducing the computational cost. In particular, specific…

材料科学 · 物理学 2024-08-28 Alexandre Boucher , Cameron Beevers , Bertrand Gauthier , Alberto Roldan

Evaluating the mechanical response of fiber-reinforced composites can be extremely time consuming and expensive. Machine learning (ML) techniques offer a means for faster predictions via models trained on existing input-output pairs and…

材料科学 · 物理学 2024-10-03 Yixuan Sun , Imad Hanhan , Michael D. Sangid , Guang Lin

A machine learning approach is presented to accelerate the computation of block polymer morphology evolution for large domains over long timescales. The strategy exploits the separation of characteristic times between coarse-grained…

化学物理 · 物理学 2023-09-01 Hyun Park , Boyuan Yu , Juhae Park , Ge Sun , Emad Tajkhorshid , Juan J. de Pablo , Ludwig Schneider

Many important multi-component crystalline solids undergo mechanochemical spinodal decomposition: a phase transformation in which the compositional redistribution is coupled with structural changes of the crystal, resulting in dynamically…

计算工程、金融与科学 · 计算机科学 2023-07-19 Xiaoxuan Zhang , Krishna Garikipati
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