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Molecular polaritons arise from electronic or vibrational strong coupling (ESC and VSC) with confined electromagnetic fields. While these have been widely studied, the influence of electron-nuclear dynamics in driven cavities remains…

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

化学物理 · 物理学 2022-10-05 Bingyu Cui , Abraham Nitzan

Strong cavity coupling of gas-phase molecules will enable studies of benchmark chemical processes under strong light-matter interactions with a high level of experimental control and no solvent effects. We recently demonstrated the…

化学物理 · 物理学 2023-10-26 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

We create exciton-polaritons in a zero-dimensional (0D) microcavity filled with organic ladder-type conjugated polymer in the strong light-matter interaction regime. Photonic confinement at wavelength scale is realized in the longitudinal…

介观与纳米尺度物理 · 物理学 2019-01-23 Fabio Scafirimuto , Darius Urbonas , Ullrich Scherf , Rainer F. Mahrt , Thilo Stöferle

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

化学物理 · 物理学 2021-07-08 Nguyen Thanh Phuc

Coherent light-matter interaction at the single photon and electronic qubit level promises the remarkable potential for nonclassical information processing. Against the efforts of improving the figure of merit of the cavities, here we…

量子物理 · 物理学 2015-06-19 Yong-Chun Liu , Xingsheng Luan , Hao-Kun Li , Qihuang Gong , Chee Wei Wong , Yun-Feng Xiao

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

化学物理 · 物理学 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

We theoretically designed and experimentally demonstrated a mechanism to protect a spatially segregated mixed light-matter state, known as intercavity exciton-polariton in strongly coupled optical cavities. This excitation, shared across…

Polaritons are quasiparticles arising from the strong coupling of electromagnetic waves in cavities and dipolar oscillations in a material medium. In this framework, localized surface plasmon in metallic nanoparticles defining optical…

Integrated photonics has been a promising platform for analog quantum simulation of condensed matter phenomena in strongly correlated systems. To that end, we explore the implementation of all-photonic quantum simulators in coupled cavity…

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

量子气体 · 物理学 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

Polaritons are compositional light-matter quasiparticles that arise as a result of strong coupling between a vacuum field of a resonant optical cavity and electronic excitations in quantum emitters. Reaching such a regime is often hard, as…

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

化学物理 · 物理学 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

The ultrafast non-radiative relaxation of a molecular ensemble coupled to a cavity mode is considered theoretically and by real-time quantum dynamics. For equal coupling strength of single molecules to the cavity mode, the non-radiative…

化学物理 · 物理学 2018-12-26 Oriol Vendrell

Phase transitions, where observable properties of a many-body system change discontinuously, can occur in both open and closed systems. Ultracold atoms have provided an exemplary model system to demonstrate the physics of closed-system…

Realizing nonlinear coupling across space can enable new scientific and technological advances, including ultrafast operation and propagation of information in IR photonic circuitry, remote triggering or catalyzing of chemical reactions,…

光学 · 物理学 2019-12-13 Jiaxi Wang , Bo Xiang , Wei Xiong

The experimental observation of quantum phenomena in strongly correlated many particle systems is difficult because of the short length- and timescales involved. Obtaining at the same time detailed control of individual constituents appears…

量子物理 · 物理学 2007-05-23 Michael J. Hartmann , Fernando G. S. L. Brandao , Martin B. Plenio

Motivated by the dramatic success of realizing cavity exciton-polariton condensation in experiment we consider the formation of polaritons from cavity photons and the amplitude or Higgs mode of a superconductor. Enabled by the recently…

超导电性 · 物理学 2020-02-19 Zachary M. Raines , Andrew A. Allocca , Mohammad Hafezi , Victor M. Galitski

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

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