相关论文: Geometric mechanisms enabling spin- and enantio-se…
Chirality describes the asymmetry between an object and its mirror image and manifests itself in diverse functionalities across all scales of matter - from molecules and aggregates to thin films and bulk chiral materials. A particularly…
Chiral molecules are instrumental for molecular recognition in living organisms. Distinguishing between two opposite enantiomers, the mirror twins of the same chiral molecule, is both vital and challenging. Photoelectron circular dichroism…
Chiral molecular structures enable time-odd pseudotensor that controls correlations between photoelectron spin and molecular orientation in photoionization (arXiv:2505.22433). We show that chiral structures also support time-even…
The discovery of the chiral induced spin selectivity effect has provided a novel tool to study how active physical and chemical mechanism may differ in chiral enantiomers, however, the origin of the effect itself is yet an open question. In…
Here we propose a mechanism by which spin polarization can be generated dynamically in chiral molecular systems undergoing photo-induced electron transfer. The proposed mechanism explains how spin polarization emerges in systems where…
We develop a mathematical formalism underlying the emergence of enantio-sensitive molecular orientation due to photoionization or photoexitation of chiral molecules. We consider geometric quantities such as the Berry connection and Berry…
Chiral induced spin selectivity is a phenomenon that has been attributed to chirality, spin-orbit interactions, and non-equilibrium conditions, while the role of electron exchange and correlations have been investigated only marginally…
Spin polarization in chiral molecules is a magnetic molecular response associated with electron transport and enantioselective bond polarization that occurs even in the absence of an external magnetic field. An unexpected finding by Santos…
Charge and spin dynamics is addressed in chiral molecules immediately after the instantaneous coupling to an external metallic reservoir. It is shown how a spin-polarization is induced in the chiral structure as a response to the charge…
Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…
Spin-resolved photoelectron spectroscopy (PES) is a major experimental probe of chirality-induced spin selectivity (CISS), yet it remains unclear whether the measured spin polarization reflects molecular chirality itself or the broader…
Photoelectron circular dichroism results from one-photon ionization of chiral molecules by circularly polarized light and manifests itself in forward-backward asymmetry of electron emission in the direction orthogonal to the light…
We present a unified description of several methods of chiral discrimination based exclusively on electric-dipole interactions. It includes photoelectron circular dichroism (PECD), enantio-sensitive microwave spectroscopy (EMWS),…
Most large molecules are chiral in their structure: they exist as two enantiomers, which are mirror images of each other. Whereas the rovibronic sublevels of two enantiomers are almost identical, it turns out that the photoelectric effect…
Chiral matter acting as a spin-selective device in biased electron transport is attracting attention for the quantum-technological design of miniaturized electronics. To date, however, experimental reports on spin selectivity are not…
Evanescent electromagnetic waves possess spin-momentum locking, where the direction of propagation (momentum) is locked to the inherent polarization of the wave (transverse spin). We study the optical forces arising from this universal…
Despite generally lacking ferromagnetic properties or strong spin-orbit coupling, electrons in chiral molecules exhibit unique spin-dependent transport behavior, known as chiral-induced spin selectivity (CISS). This phenomenon implies a…
Chirality induced spin selectivity, discovered about two decades ago in helical molecules, is a non-equilibrium effect that emerges from the interplay between geometrical helicity and spin-orbit interactions. Several model Hamiltonians…
The spinterface mechanism was suggested as a possible origin for the chirality induced spin-selectivity (CISS) effect, and was used to explain and reproduce, with remarkable accuracy, experimental data from transport experiments showing the…
In the framework of the perturbation theory of the nonrelativistic quantum electrodynamics, a theory of spontaneous emission of a chiral molecule located near a chiral (bi-isotropic) spherical particle is developed. It is shown that the…