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Aqueous zinc (Zn)-ion batteries (AZIB) are promising candidates for the next-generation energy store systems due to their high capacity and low cost. Despite their nominal performance, Zn anodes tend to rapidly develop dendrite and…

材料科学 · 物理学 2022-09-20 Musanna Galib , Okan K. Orhan , Mauricio Ponga

Aqueous zinc (Zn) batteries provide many benefits, including high theoretical capacity, a low redox potential, and the abundance of Zn in Earth's crust. However, the benefits are often compromised by severe side reactions and dendrite…

材料科学 · 物理学 2025-12-18 I. Al Kathemi , J. Caroni , T. Dehne , M. Souto , M. Antonietti , R. Bouchal

Lithium-ion batteries have attracted enormous interests recently as promising power sources. However, the safety issue associated with the employment of highly flammable liquid electrolyte impedes the further development of next-generation…

应用物理 · 物理学 2019-09-25 Yun Zhao , Yuqing Chen , Yuqiong Kang , Li Wang , Shaobin Yang , Zheng Liang , Yanxi Li

Corrosion and the formation of by-products resulting from parasitic side reactions, as well as random dendrite growth, pose significant challenges for aqueous zinc-ion batteries (AZIBs). In this study, phytate ammonium is introduced into…

应用物理 · 物理学 2024-09-04 Fangyuan Xiao , Xiaoke Wang , Kaitong Sun , Qian Zhao , Cuiping Han , Hai-Feng Li

Efficient energy storage systems are crucial to address the intermittency of renewable energy sources. As multivalent batteries, Zn-ion batteries (ZIBs), while inherently low voltage, offer a promising low cost alternative to Li-ion…

材料科学 · 物理学 2025-04-17 Roberta Pascazio , Qian Chen , Haoming Howard Li , Aaron D. Kaplan , Kristin A. Persson

Dendrite formation is a long-standing problem for the commercial application of aqueous zinc (Zn)-ion batteries (AZIB). Here, we investigate the effect of hetero-epitaxial residual stresses due to layered coatings on dendrite suppression.…

材料科学 · 物理学 2025-02-07 Musanna Galib , Amardeep Amardeep , Jian Liu , Mauricio Ponga

Aqueous zinc-air batteries (ZABs) are a low-cost, safe, and sustainable technology for stationary energy storage. ZABs with pH-buffered near-neutral electrolytes have the potential for longer lifetime compared to traditional alkaline ZABs…

Polymer electrolytes present a promising solution to the challenges posed by aqueous electrolytes in energy storage systems, offering the flexibility needed for wearable electronics. Despite the increasing interest in polymer…

材料科学 · 物理学 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

This paper presents a combined theoretical and experimental investigation of aqueous near-neutral electrolytes based on chloride salts for rechargeable zinc-air batteries (ZABs). The resilience of near-neutral chloride electrolytes in air…

Zinc-ion batteries are promising alternatives to lithium-ion batteries, offering advantages in safety, cost, and environmental impact. However, their performance is often limited by the functioning of the zinc anode. This study employs…

材料科学 · 物理学 2025-03-31 Xinxin Hu , Shivam Dangwal , Xucheng Wang , Fan Zhang , Haijuan Kong , Jun Li , Kaveh Edalati

This study presents a comprehensive Multiphysics model for zinc-ion batteries (ZIBs), incorporating electrochemical aspects. The model integrates the mass transport of Zn2+ ions, charge transfer, and solid diffusion to predict performance…

材料科学 · 物理学 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

Growing energy storage demands on lithium-ion batteries necessitate exploration of new electrochemical materials as next-generation battery electrode materials. In this work, we investigate the previously unexplored electrochemical…

材料科学 · 物理学 2022-07-18 M Brooks Tellekamp , Anna Osella , Karen N Heinselman , Adele C Tamboli , Chunmei Ban

Electrochemical water electrolysis, which produces clean energy carriers to mitigate carbon emissions, lacks suitable, low-cost electrodes for efficient oxygen evolution reaction (OER) in alkaline water splitting. To address this challenge,…

Zinc-based batteries offer good volumetric energy densities and are compatible with environmentally friendly aqueous electrolytes. Zinc-ion batteries (ZIBs) rely on a lithium-ion-like Zn$^{2+}$-shuttle, which enables higher roundtrip…

化学物理 · 物理学 2023-12-11 Niklas J. Herrmann , Holger Euchner , Axel Groß , Birger Horstmann

Rechargeable Zn batteries offer safe, inexpensive energy storage, but when deeply discharged to compete with lithium-ion batteries, they are plagued by parasitic reactions at the Zn anodes. We apply super-concentrated alkaline electrolytes…

Rechargeable aqueous zinc-ion batteries (RAZIBs) attract considerable scientific and commercial interest for deployment in grid-scale energy storage due to higher safety and lower manufacturing cost when compared to lithium-ion batteries.…

材料科学 · 物理学 2026-02-12 Caio Miranda Miliante , Brian D. Adams , Drew Higgins , Oleg Rubel

Organic/inorganic hybrid systems offer great potential for novel solar cell design combining the tunability of organic chromophore absorption properties with high charge carrier mobilities of inorganic semiconductors. However, often such…

We report the synthesis, physical properties and electrochemical performance of Zn substituted Na$_{0.44}$Mn$_{1-x}$Zn$_x$O$_2$ ($x=$ 0 -- 0.02) nanostructures as cathode in Na-ion batteries for energy storage applications. These samples…

材料科学 · 物理学 2018-10-18 Mahesh Chandra , Rishabh Shukla , Rakesh Saroha , A. K. Panwar , Amit Gupta , S. Basu , R. S. Dhaka

"Anode-free" lithium-metal batteries promise significantly higher energy density than conventional graphite-based lithium-ion batteries; however, lithium dendrite growth can lead to internal short circuits with associated safety risks.…

Electrochemical cells employing Sodium (Na) and Zinc (Zn) electrodes and a chloride salt electrolyte have been imaged by neutron radiography during cycling. The use of such abundant raw materials confers a very low energy-normalised cost to…

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