相关论文: Capillary condensation between parallel walls of u…
In this article we calculate the surface phase diagram of a two-dimensional hard-rod fluid confined between two hard lines. In a first stage we study the semi-infinite system consisting of an isotropic fluid in contact with a single hard…
The dynamics of phase-separated interfaces shape the behavior of both passive and active condensates. While surface tension in equilibrium systems minimizes interface length, non-equilibrium fluxes can destabilize flat or constantly curved…
Symmetric mixtures characterized by high negative geometric and energetic non-additivity do not exhibit phase separation in the bulk. However, the phase separation occurs when such mixtures are confined in slit pores with selective walls.…
The capillary condensation for fluids into spherical nano-cavities is analyzed within the frame of two theoretical approaches. One description is based on a widely used simplified version of the droplet model formulated for studying atomic…
The electrostatic interaction between pairs of spherical or macroscopically long, parallel cylindrical colloids trapped at fluid interfaces is studied theoretically for the case of small inter-particle separations. Starting from the…
Liquid-liquid-solid systems are becoming increasingly common in everyday life with many possible applications. Here, we focus on a special case of such liquid-liquid-solid systems, namely, capillary suspensions. These capillary suspensions…
The lattice gas model of condensation in a heterogeneous pore system, represented by a random graph of cells, is studied using an exact analytical solution. A binary mixture of pore cells with different coordination numbers is shown to…
We study the breakup of confined fluid threads at low flow rates to understand instability mechanisms. To determine the critical conditions between the earlier quasi-stable necking stage and the later unstable collapse stage, simulations…
This paper discusses wetting and capillary condensation transitions on a line and a rectangular array of cylinders using an interface potential formalism. For a line of cylinders, there is a capillary condensation transition followed by…
We consider the location and order of capillary condensation transitions occurring in deep grooves of width $L$ and depth $D$. For walls that are completely wet by liquid (contact angle $\theta=0$) the transition is continuous and its…
A scaling theory is developed for diffusion-limited cluster aggregation in a porous medium, where the primary particles and clusters stick irreversibly to the walls of the pore space as well as to each other. Three scaling regimes are…
We investigate the formation of condensates in a binary lattice gas in the presence of chiral interactions. These interactions differ between a given microscopic configuration and its mirror image. We consider a two dimensional lattice gas…
Capillary attraction between identical millimeter sized spheres floating at a liquid-air interface and the resulting aggregation is investigated at low Reynolds number. We show that the measured capillary forces between two spheres as a…
Step-emulsification is a microfluidic technique for droplet generation which relies on the abrupt decrease of confinement of a liquid filament surrounded by a continuous phase. A striking feature of this geometry is the transition between…
We study the interplay between hysteresis and equilibrium behavior in capillary condensation of fluids in mesoporous disordered materials via a mean-field density functional theory of a disordered lattice-gas model. The approach reproduces…
We develop a theory that predicts the equilibrium states of a fluid contained in a capillary which has corners. Each section of the tube can take three states: completely wet state where the tube section is completely occupied by the fluid,…
We consider an interface between two demixed A and B phases, confined in a thin film between two antisymmetric walls, one of which prefers A and the other B. Above the wetting transition, the interface is stabilized in the center of the…
We show using computer simulations and mean field theory that a system of particles in two dimensions, when confined laterally by a pair of parallel hard walls within a quasi one dimensional channel, possesses several anomalous structural…
We employ a simple model to describe the phase behavior of 4He and Ar in a hypothetical porous material consisting of a regular array of infinitely long, solid, parallel cylinders. We find that high porosity geometries exhibit two…
We image the flow of a nearly random close packed, hard-sphere colloidal suspension (a `paste') in a square capillary using confocal microscopy. The flow consists of a `plug' in the center while shear occurs localized adjacent to the…