相关论文: On the First Quantum Correction to the Second Viri…
An exact analytic form for the second virial coefficient, valid for the entire range of temperature, is presented for the Lennard-Jones fluid in this paper. It is derived by making variable transformation that gives rise to the Hamiltonian…
This note examines the second virial coefficient for an imperfect gas subject to a 2n-n interparticle potential in any dimension d between 0 and n. A compact analytic expression is presented for this quantity which shows that, apart from a…
Liquids displaying strong virial-potential energy correlations conform to an approximate density scaling of their structural and dynamical observables. This scaling property does not extend to the entire phase diagram, in general. The…
Quantum corrections to the classical pressure are obtained for Lennard-Jones models of argon, neon, and helium using classical Metropolis algorithm computer simulations. The corrections for non-commutativity are obtained to fourth order in…
The quantum states representing classical phase space are given, and these are used to formulate quantum statistical mechanics as a formally exact double perturbation expansion about classical statistical mechanics. One series of quantum…
This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…
In this paper, we generally expressed the virial expansion of ideal quantum gases by the heat kernel coefficients for the corresponding Laplace type operator. As examples, we give the virial coefficients for quantum gases in $d$-dimensional…
From the static polarization function of electrons in the random phase approximation the quantum Bohm potential for the quantum hydrodynamic description of electrons, and the density gradient correction to the Thomas-Fermi free energy at a…
Attempts to construct a low-temperature version of the fluid/gravity correspondence have faced obstacles manifested in the form of logarithmic terms in the frequency, $\log(\omega)$, leading to non-local in time constitutive relations for…
A result from Dodd and Gibbs[1] for the second virial coefficient of particles in 1 dimension, subject to delta-function interactions, has been obtained by direct integration of the wave functions. It is shown that this result can be…
In this paper we apply the global isomorphism approach [V.~L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] between the Lennard-Jones fluids and Lattice Gas model to the study of the liquid-vapor equilibrium for the systems with the…
Divergence exponents of the first-order quantum correction of a two-dimensional hard-sphere Bose atoms are obtained by an effective field theory method. The first-order correction to the ground-state energy density with respect to the…
In recent years, a second fluid-fluid phase transition has been reported in several materials at pressures far above the usual liquid-gas phase transition. In this paper, we introduce a new model of this behavior based on the Lennard-Jones…
This paper investigates the relation between the density-scaling exponent $\gamma$ and the virial potential-energy correlation coefficient $R$ at several thermodynamic state points in three dimensions for the generalized $(2n,n)$…
The interest in the description of the properties of fluids of restricted dimensionality is growing for theoretical and practical reasons. In this work, we have firstly developed an analytical expression for the Helmholtz free energy of the…
It was recently shown that vapor-liquid coexistence densities derived from Mie and Yukawa models collapse to define a single master curve when represented against the difference between the reduced second virial coefficient at the…
In this paper we give a closed form expression for the $1/d$ corrections to the self-energy characterizing the correction function of a manifold in random media. This amounts to the first correction beyond the variational approximation. At…
The equation of state and, more generally, the thermodynamics of the Lennard-Jones fluid have long served as a benchmark problem in the statistical theory of fluids. Among available theoretical approaches, first-order perturbation theory…
The van-der-Waals version of the second virial coefficient is not far from being exact if the model parameters are appropriately chosen. It is shown how the van-der-Waals resemblance originates from the interplay of thermal averaging and…
When a fluid is constrained to a fixed, finite volume, the conditions for liquid-vapor equilibrium are different from the infinite volume or constant pressure cases. There is even a range of densities for which no bubble can form, and the…