相关论文: Mixed-Valent Ce Disrupts Magnetic Ordering in CeFe…

We report on the electronic band structure, structural, magnetic and thermal properties of Ce$_2$Rh$_3$Sn$_5$. Ce $L_{\mathrm{III}}$-edge XAS spectra give direct evidence for an intermediate valence behaviour. Thermodynamic measurements…

We report on the valence fluctuation of Ce in CeMo$_{2}$Si$_{2}$C as studied by means of magnetic susceptibility $\chi(T)$, specific heat $C(T)$, electrical resistivity $\rho(T)$ and x-ray absorption spectroscopy. Powder x-ray diffraction…

Neutron and synchrotron resonant X-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in single crystal CeFeAsO. The RXMS of…

We have measured the magnetic properties of a mixed valency iron phosphate. It presents an original structure with crossed chains containing Fe II and orthogonal to the longest direction of the crystallites. Microstructural investigations…

Polycrystalline samples of ternary rare earth germanides R$_{2}$Co$_{3}$Ge$_{5}$(R = La, Ce and Pr) have been prepared and investigated by means of magnetic susceptibility, isothermal magnetization, electrical resistivity and specific heat…

We have synthesized two new interstitial compounds (RPd3)8Mn (R = La and Ce). The Mn ions present in "dilute" concentration of just 3 molar percent form a sublattice with an unusually large Mn-Mn near neighbor distance of ~ 85 nm. While the…

CeIrSn with a quasikagome Ce lattice in the hexagonal basal plane is a strongly valence fluctuating compound, as we confirm by hard x-ray photoelectron spectroscopy and inelastic neutron scattering, with a high Kondo temperature of…

Cerium and its technologically relevant compounds are examples of anomalous mixed valency, originating from two competing oxidation states -- itinerant Ce$^{3+}$ and localized Ce$^{4+}$. Under applied stress, anomalous transitions are…

We report the discovery of Ce$_3$Ir$_4$Ge$_{13}$, a new Remeika phase compound with a complex array of structural, electronic, and magnetic properties. Our single crystal x-ray diffraction measurements show that Ce$_3$Ir$_4$Ge$_{13}$ forms…

We report the discovery of pressure-induced superconductivity in a semimetallic magnetic material CeTe$_{1.82}$. The superconducting transition temperature $T_{SC}$ = 2.7 K (well below the magnetic ordering temperatures) under pressure ($>$…

The discovery of superconductivity in the 122 iron selenide materials above 30 K necessitates an understanding of the underlying magnetic interactions. We present a combined experimental and theoretical investigation of magnetic and…

We investigate the novel intermetallic ternary compounds \emph{R}Co$_{9}$Ge$_{4}$ with \emph{R} = La and Ce by means of $X$-ray diffraction, susceptibility and specific heat measurements. CeCo$_{9}$Ge$_{4}$ crystallizes in the space group…

We report a systematic study of the $5d$-electron-doped system Ce(Fe$_{1-x}$Ir$_x$)$_2$Al$_{10}$ ($0 \leq x \leq 0.15$). With increasing $x$, the orthorhombic $b$~axis decreases slightly while accompanying changes in $a$ and $c$ leave the…

Single crystals of $R$Cd$_{3}$P$_{3}$ ($R$ = La and Ce) have been investigated by magnetization, electrical resistivity, Hall coefficient, and specific heat. Magnetization measurements of CeCd$_{3}$P$_{3}$ demonstrate clear quasi-2D…

Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural…

The physical properties of an intermetallic compound CeRh2Ga2 have been investigated by magnetic susceptibility \chi(T), isothermal magnetization M(H), heat capacity C_p(T), electrical resistivity \rho(T), thermal conductivity \kappa(T) and…

We report the effects of Ce substitution on structural, electronic, and magnetic properties of layered bismuth-chalcogenide La1-xCexOBiSSe (x = 0-0.9), which are newly obtained in this study. Metallic conductivity was observed for x > 0.1…

In mixed-valence or heavy-fermion systems, the hybridization between local $f$ orbitals and conduction band states can cause the suppression of long-range magnetic order, which competes with strong spin fluctuations. Ce- and Yb-based…

We report on detailed low temperature measurements of the magnetization, the specific heat and the electrical resistivity on high quality CeRuSn single crystals. The compound orders antiferromagnetically at $T_{\rm N} = 2.8$ K with the…

We study the effects of Cu substitution in Fe1.1Te, the non-superconducting parent compound of the iron-based superconductor, Fe1+yTe1-xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions,…