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Li$_{10}$Ge(PS$_6$)$_2$ (LGPS) is a highly concentrated solid electrolyte, in which Coulombic repulsion between neighboring cations is hypothesized as the underlying reason for concerted ion hopping, a mechanism common among superionic…

材料科学 · 物理学 2022-11-29 Gavin Winter , Rafael Gómez-Bombarelli

Superionic conductors, or solid-state ion-conductors surpassing 0.01 S/cm in conductivity, can enable more energy dense batteries, robust artificial ion pumps, and optimized fuel cells. However, tailoring superionic conductors require…

仪器与探测器 · 物理学 2024-07-23 Kim H. Pham , Scott K. Cushing

Phonon liquid-like thermal conduction in the solid state enables superionic conductors to serve as efficient thermoelectric device candidates. While liquid-like motion of ions effectively suppresses thermal conductivity (\kappa), their high…

Cu2Se and Cu2S are excellent model systems of superionic conductors with large diffusion coefficients that have been reported to exhibit different solid-liquid-like Cu-ion diffusion. In this paper, we clarify the atomic dynamics of these…

Quasielastic neutron scattering (QENS) measurements combined with first principles based moleculardynamics calculations were conducted to study the dynamics of Li$^+$ ions in a solid-state electrolyte La$_{2/3-x}$Li$_{3x}$TiO$_{3}$ (LLTO)…

材料科学 · 物理学 2021-10-01 Masato Matsuura , Yasuyuki Fujiwara , Hiroki Moriwake , Koji Ohara , Yukinobu Kawakita

We present a systematic characterization of the fractal conduction pathways governing ionic transport in a non-crystalline solid below the glass-transition temperature. Using classical molecular dynamics simulations of lithium metasilicate,…

软凝聚态物质 · 物理学 2026-01-01 J. L. Iguain , F. O. Sanchez-Varreti , M. A. Frechero

Na-ion conduction, and correlations between Na-ion conduction pathways and crystal structure have been investigated as a function of temperature in the layered battery material Na2Ni2TeO6 by impedance spectroscopy and neutron diffraction,…

材料科学 · 物理学 2020-07-15 A. K. Bera , S. M. Yusuf

In the quest of green energy, Solid Oxide Fuel Cells (SOFC) have drawn considerable attention for chemical-to-electric energy conversion. In the present paper, we report an enhancement of ionic conductivity in Cu2P2-xVxO7 by vanadium…

We report on the study of the electrical current flowing in weakly coupled superlattice (SL) structures under an applied electric field at very low temperature, i.e. in the tunneling regime. This low temperature transport is characterized…

介观与纳米尺度物理 · 物理学 2010-05-12 E. Lhuillier , I. Ribet-Mohamed , A. Nedelcu , V. Berger , E. Rosencher

High transition temperature (high-Tc) superconductivity is associated with layered crystal structures. This work considers superconductivity in ultra-thin crystals (of thickness equal to the transverse structural periodicity distance d for…

超导电性 · 物理学 2012-02-03 Dale R. Harshman , Anthony T. Fiory

Solid-state electrolytes (SSEs) require ionic conductivities that are competitive with liquid electrolytes to realize applications in all-solid state batteries. Although numerous materials have been discovered, the underlying mechanisms…

We study the thermodynamical properties of crystals of trapped ions which are laser cooled to two different temperatures in two separate regions. We show that these properties strongly depend on the structure of the ion crystal. Such…

量子物理 · 物理学 2015-12-21 Nahuel Freitas , Esteban Martinez , Juan Pablo Paz

The electride Sr$_3$CrN$_3$ has a one-dimensional channel of electron density, which is a rare feature that offers great potential for fast ion conduction. Using density functional theory, we find that Sr$_3$CrN$_3$ is an excellent hydride…

材料科学 · 物理学 2021-12-07 Xu Miaoting , Cuicui Wang , Benjamin J. Morgan , Lee A. Burton

We review recent experimental and theoretical progress made in the scope of swift highly charged ion channelling in crystals. The usefulness of such studies is their ability to yield impact parameter information on charge transfer…

原子物理 · 物理学 2009-07-23 D. Dauvergne

The quasiparticle method, which has achieved a great success in solid state electronics and crystal lattice vibration, is adopted to study the solid state ion transport. A general recipe is put forward to map the classical solid state ion…

材料科学 · 物理学 2024-02-13 Jiaming Hu

Quantum correlation and hot-carrier transport represent two fundamentally distinct regimes of electronic conduction, rarely accessible within the same device. Here, we report a state-of-the-art monolayer transition metal dichalcogenides…

介观与纳米尺度物理 · 物理学 2025-11-11 Debottam Daw , Houcine Bouzid , Sung-Gyu Lee , Wujoon Cha , Ki Kang Kim , Min-kyu Joo , Yan Wang , Manish Chhowalla , Young Hee Lee

Within the framework of the unified theory thermal transport model, the competing contributions of coherent and incoherent terms create a trade-off relationship, posing substantial challenges to achieving a reduction in overall $\rm…

材料科学 · 物理学 2025-04-04 Wenjie Xiong , Hao Huang , Yu Wu , Xinji Xu , Geng Li , Zonglin Gu , Shuming Zeng

Quasi-one-dimensional $A_2\text{Cr}_3\text{As}_3$ (with $A = \text{K, Cs, Rb}$) is an intriguing new family of superconductors which exhibit many similar features to the cuprate and iron-based unconventional superconductor families. Yet in…

超导电性 · 物理学 2017-11-29 K. M. Taddei , Q. Zheng , A. S. Sefat , C. de la Cruz

Although there is no complete theory of high temperature superconductivity, the importance of CuO$_2$ planes in cuprate superconductors is confirmed from both theory and experiments. Strong Coulomb repulsion between electrons on the CuO$_2$…

Lithium chloride LiCl is widely used as a prototype system to study the strongly dissociated 1-1 electrolyte solution. Here, we combined experimental measurements and classical molecular dynamics simulations to study the ion conduction in…

软凝聚态物质 · 物理学 2019-05-14 Are Yllö , Chao Zhang
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