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Devices possessing the ability to sense both electrically and optically molecular targets are of fundamental and technological interest. Towards this end, it has been shown that covering the ends of gapped gold-nanorod-dimer nanoantennas…

Illuminated gapped-gold-nanorod dimers hold surface plasmon polaritons (SPPs) that can be engineered, by an appropriate choice of geometrical parameters, to enhance the electromagnetic field at the gap, allowing applications in molecular…

Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…

光学 · 物理学 2016-09-19 Jing Long , Hui Yi , Hongquan Li , Tian Yang

Electromagnetic theory predicts that the optimal value of the localized plasmon resonance (LPR) wavelength for the maximal SERS enhancement factor (EF) is half the sum of the laser and Raman wavelengths. For small Raman shifts, the…

Nanofibers functionalized by metal nanostructures and particles are exploited as effective flexible substrates for SERS analysis. Their complex three-dimensional structure may provide Raman signals enhanced by orders of magnitude compared…

材料科学 · 物理学 2016-03-16 A. Camposeo , D. Spadaro , D. Magrì , M. Moffa , P. G. Gucciardi , L. Persano , O. M. Maragò , D. Pisignano

Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…

光学 · 物理学 2008-06-19 Sanshui Xiao , Niels Asger Mortensen , Antti-Pekka Jauho

Surface enhanced Raman spectroscopy (SERS) has the capacity of detecting trace amount of biological or chemical matter, even single molecules, through the use of metallic nanostructures such as nanorods. Silver (Ag) and gold (Au) nanorods…

材料科学 · 物理学 2014-05-06 Stephen P. Stagon , Xuefei Tan , Yongmin Liu , Hanchen Huang

We present experimental demonstration of a recently predicted path interference phenomenon [Nanophotonics 7, 1687 (2018)]. A SERS process becomes resonant when both incident and the converted frequencies match with two plasmon resonances --…

Giant field enhancement and field singularities are a natural consequence of the commonly employed local-response framework. We show that a more general nonlocal treatment of the plasmonic response leads to new and possibly fundamental…

Nowadays, Au dimer-based nanostructures are exhaustively studied due to their outstanding potential as plasmonic nanoantennas for future applications in high-sensitivity molecular sensing by Surface-Enhanced Raman Spectroscopy (SERS). In…

Surface Enhanced Raman Spectroscopy (SERS) is a well-established technique for enhancing Raman signals. Recently photonic integrated circuits have been used, as an alternative to microscopy based excitation and collection, to probe SERS…

The Raman scattering of light by molecular vibrations offers a powerful technique to 'fingerprint' molecules via their internal bonds and symmetries. Since Raman scattering is weak, methods to enhance, direct and harness it are highly…

We theoretically investigate the enhancement of surface enhanced Raman spectroscopy (SERS) using hyperbolic stratified nanostructures and compare to metal nanoresonators. The photon Green function of each nanostructure within its…

Surface-enhanced Raman scattering (SERS) is a critical tool for chemical sensing and spectroscopy, and a key question is how to optimally design nanostructures for maximizing SERS. We present fundamental limits on spatially-averaged SERS…

光学 · 物理学 2025-02-17 Pengning Chao , Ian M. Hammond , Steven G. Johnson

The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…

材料科学 · 物理学 2015-06-12 V. I. Kukushkin , A. B. Van'kov , I. V. Kukushkin

Plasmonic nanostructures have wide applications in photonics including pathogen detection and diagnosis via Surface-Enhanced Raman Spectroscopy (SERS). Despite major role plasmonics play in signal enhancement, electrostatics in SERS is yet…

细胞行为 · 定量生物学 2025-01-22 Jia Dong , Jeong Hee Kim , Isaac Pincus , Sujan Manna , Jennifer M. Podgorski , Yanmin Zhu , Loza F. Tadesse

The Scanning electron microscope (SEM) and Electron-Dispersive Spectroscope (EDS) are two highly effective instruments in the field of nanoscience and nanotechnology. The quality of these instruments is determined by various factors, with…

应用物理 · 物理学 2023-10-24 Hamidreza Moradi , Fatemeh Mehradnia

Noble-metal-free surface-enhanced Raman scattering (SERS) substrates have attracted great attention for their abundant sources, good signal uniformity, superior biocompatibility, and high chemical stability. However, the lack of…

应用物理 · 物理学 2022-04-14 Leilei Lan , Haorun Yao , Guoqun Li , Xingce Fan , Mingze Li , Teng Qiu

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

介观与纳米尺度物理 · 物理学 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

The experimental limitations in the signal enhancement and spatial resolution in spectroscopic imaging have been always a challenging task in the application of near-field spectroscopy for nanostructured materials in the sub-diffraction…

材料科学 · 物理学 2018-06-11 A. K. Sivadasan , Avinash Patsha , Achyut Maity , Tapas Kumar Chini , Sandip Dhara
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