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Linear scaling quantum chemical methods for Density Functional Theory are extended to the condensed phase at the $\Gamma$-point. For the two-electron Coulomb matrix, this is achieved with a tree-code algorithm for fast Coulomb summation [J.…

材料科学 · 物理学 2009-11-10 C. J. Tymczak , Matt Challacombe

The Coupled-Cluster theory is one of the most successful high precision methods used to solve the stationary Schr\"odinger equation. In this article, we address the mathematical foundation of this theory with focus on the advances made in…

化学物理 · 物理学 2019-09-04 Andre Laestadius , Fabian M. Faulstich

Stochastic simulation methods can be applied successfully to model exact spatio-temporally resolved reaction-diffusion systems. However, in many cases, these methods can quickly become extremely computationally intensive with increasing…

定量方法 · 定量生物学 2016-04-29 Jonathan U. Harrison , Christian A. Yates

A basic principle in crystal structure determination is that there should be proper distances between adjacent atoms. Therefore, detection of atom bumping is of fundamental significance in structure determination, especially in the direct…

材料科学 · 物理学 2017-09-06 Yu Liu

Evaluating multi-center molecular integrals with Cartesian Gaussian-type basis sets has been a long-standing bottleneck in electronic structure theory calculation for solids and molecules. We have developed a vector-coupling and…

量子物理 · 物理学 2024-05-17 Hang Hu , Gilles Peslherbe , Hsu Kiang Ooi , Anguang Hu

This paper presents a high-accuracy higher-order multiscale method for solving multi-continuum problems in in highly heterogeneous media. First, microscopic unit cell functions are defined, leading to the derivation of macroscopic…

数值分析 · 数学 2026-04-08 Hao Dong , Jiayuan Peng , Jian Huang

Porous structures are materials consisting of minuscule pores, where the microstructure morphology significantly impacts their macroscopic properties. Integrating different porous structures through a blending method is indispensable to…

图形学 · 计算机科学 2024-06-03 Depeng Gao , Yang Gao , Yuanzhi Zhang , Hongwei Lin

The 2D Euler equations is the basic example of fluid models for which a microcanical measure can be constructed from first principles. This measure is defined through finite-dimensional approximations and a limiting procedure. Creutz's…

统计力学 · 物理学 2015-06-11 Max Potters , Timothee Vaillant , Freddy Bouchet

In this work we analyze two classes of Density-Estimation techniques which can be used to consistently couple different kinetic models of the plasma-material interface, intended as the region of plasma immediately interacting with the first…

计算物理 · 物理学 2018-04-12 Shane Keniley , Davide Curreli

We propose a computationally lean, two-stage approach that reliably predicts self-assembly behavior of complex charged molecules on a metallic surfaces under electrochemical conditions. Stage one uses ab initio simulations to provide…

This paper presents the design and analysis of a Hybrid High-Order (HHO) approximation for a distributed optimal control problem governed by the Poisson equation. We propose three distinct schemes to address unconstrained control problems…

数值分析 · 数学 2025-01-14 Gouranga Mallik , Ramesh Chandra Sau

Rapid solidification leads to unique microstructural features, where a less studied topic is the formation of various crystalline defects, including high dislocation densities, as well as gradients and splitting of the crystalline…

In classical computational chemistry, the coupled-cluster ansatz is one of the most commonly used $ab~initio$ methods, which is critically limited by its non-unitary nature. The unitary modification as an ideal solution to the problem is,…

量子物理 · 物理学 2017-03-01 Yangchao Shen , Xiang Zhang , Shuaining Zhang , Jing-Ning Zhang , Man-Hong Yung , Kihwan Kim

Hybrid quantum-classical approaches offer potential solutions to quantum chemistry problems, yet they often manifest as constrained optimization problems. Here, we explore the interconnection between constrained optimization and generalized…

量子物理 · 物理学 2025-03-27 Muqing Zheng , Bo Peng , Ang Li , Xiu Yang , Karol Kowalski

The conformal method is a technique for finding Cauchy data in general relativity solving the Einstein constraint equations, and its parameters include a conformal class, a conformal momentum (as measured by a densitized lapse), and a mean…

广义相对论与量子宇宙学 · 物理学 2014-07-08 David Maxwell

The computational complexity and efficiency of the approximate mode component synthesis (ACMS) method is investigated for the two-dimensional heterogeneous Helmholtz equations, aiming at the simulation of large but finite-size photonic…

Circuit depth reduction is of critical importance for quantum chemistry simulations on current and near term quantum computers. This issue is tackled by introducing a chemically aware strategy for the Unitary Coupled Cluster ansatz. The…

In this work we propose and analyze a new Hybrid High-Order method for the Brinkman problem for fluids with power-law viscosity. The proposed method supports general meshes and arbitrary approximation orders and is robust in all regimes,…

Advanced metering infrastructure (AMI) has been widely used as an intelligent energy consumption measurement system. Electric power was the representative energy source that can be collected by AMI; most existing studies to detect abnormal…

机器学习 · 计算机科学 2023-05-05 Taehee Kim , Hyuk-Yoon Kwon

This paper is devoted to the derivation of a digital quantum algorithm for the Cauchy problem for symmetric first order linear hyperbolic systems, thanks to the reservoir technique. The reservoir technique is a method designed to avoid…

量子物理 · 物理学 2018-04-10 F. Fillion-Gourdeau , E. Lorin