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We propose a Jastrow factor for electron-electron correlations that interpolates between the radial symmetry of the Coulomb interaction at short inter-particle distance and the space-group symmetry of the simulation cell at large…

强关联电子 · 物理学 2016-08-10 T. M. Whitehead , M. H. Michael , G. J. Conduit

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

化学物理 · 物理学 2022-05-16 Jerry L. Whitten

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be…

化学物理 · 物理学 2009-11-10 Julien Toulouse , Francois Colonna , Andreas Savin

The analysis of correlation energy of the simplest first approximation of a variational method for the intrashell states of two-electron atoms is the purpose of the present work. This method allows to divide energy of atom on Coulomb and…

原子物理 · 物理学 2008-10-23 V. V. Kavera

Recent advances in the treatment of scattering of charged composite particles are reviewed. In a first part I report on developments of the theory. Specifically I describe the recent completion of the derivation of the co-ordinate space…

核理论 · 物理学 2011-04-15 E. O. Alt

A new method to determine electron correlation energy is described. This method is based on a better representation of the potential due to interacting electrons that is obtained by specifying both the average and standard deviation. The…

材料科学 · 物理学 2007-05-23 T. R. S. Prasanna

Continuum states of the Dirac equation are calculated numerically for the electrostatic field generated by the charge distribution of an atomic nucleus. The behavior of the wave functions of an incoming electron with a given asymptotic…

核理论 · 物理学 2007-05-23 Andreas Aste , Cyrill von Arx , Dirk Trautmann

The account of electron correlation and its efficient separation into dynamic and nondynamic parts plays a key role in the development of computational methods. In this paper we suggest a physically-sound matrix formulation to split…

化学物理 · 物理学 2016-08-16 Eloy Ramos-Cordoba , Pedro Salvador , Eduard Matito

Investigation of electronic waves with high coherence in photodetachment of a negative ion gives a physical basis to develop the holographic electronic microscopy with high resolution. The interference pattern is considered in the framework…

仪器与探测器 · 物理学 2011-11-08 P. A. Golovinski , A. A. Drobyshev

The trajectory of motion of a scattering electron in the Coulomb potential from the wave function of the Schroedinger equation is presented in two ways, spherical polar coordinates and Temple coordinates, and is compared with each other and…

量子物理 · 物理学 2014-08-04 Yoshio Nishiyama , Fumiaki Tajima

Coulomb dissociation is an especially simple and important reaction mechanism. Since the perturbation due to the electric field of the (target) nucleus is exactly known, firm conclusions can be drawn from such measurements. Electromagnetic…

核理论 · 物理学 2011-07-19 Gerhard Baur , Kai Hencken , Dirk Trautmann

The author suggests an approach based on the separation of total energy of multielectron systems into the semi-classical Coulomb part and the non-classical additional part. This approach allows on the one hand to simplify calculations and…

原子物理 · 物理学 2008-11-04 Vadim Kavera

A technique to deal with Coulomb electron distortions in the analysis of (e,e'p) reactions is presented. Thereby, no approximations are made. The suggested technique relies on a partial-wave expansion of the electron wave functions and a…

核理论 · 物理学 2008-11-26 V. Van der Sluys , K. Heyde , J. Ryckebusch , M. Waroquier

One approximation is made to describe a M+1 electron many-body wavefunction by a M electron many-body wavefunction and a single electron wavefunction. Under this approximation, we have derived the Coulomb energy which relates the exciton…

材料科学 · 物理学 2007-05-23 Lin-Wang Wang

Coulomb dissociation is an especially simple and important reaction mechanism. Since the perturbation due to the electric field of the nucleus is exactly known, firm conclusions can be drawn from such measurements. Electromagnetic matrix…

核理论 · 物理学 2009-11-06 Gerhard Baur , Kai Hencken , Dirk Trautmann , Stefan Typel , Hermann H. Wolter

New method for ab initio calculations of the properties of large size system based on phase-amplitude functional is presented. It is shown that Schrodinger equation for many electrons complex system including large size molecules, or…

计算物理 · 物理学 2019-10-10 Pawel Strak , Konrad Sakowski , Pawel Kempisty , Stanislaw Krukowski

We proposed a distributed approximating functional method for efficiently describing the electronic dynamics in atoms and molecules in the presence of the Coulomb singularities, using the kernel of a grid representation derived by using the…

计算物理 · 物理学 2016-04-05 Zhigang Sun

A form of Jastrow factor is introduced for use in quantum Monte Carlo simulations of finite and periodic systems. Test data are presented for atoms, molecules, and solids, including both all-electron and pseudopotential atoms. We…

计算物理 · 物理学 2008-01-03 N. D. Drummond , M. D. Towler , R. J. Needs

The many-body Coulomb repulsive energy of strictly correlated electrons provides direct information of the exact Hohenberg-Kohn exchange-correlation functional in the strong interaction limit. Until now the treatment of strictly correlated…

化学物理 · 物理学 2013-03-13 Christian B. Mendl , Lin Lin

We outline a rigorous method which can be used to solve the many-body Schroedinger equation for a Coulomb interacting electronic system in an external classical magnetic field as well as a quantized electromagnetic field. Effects of the…

介观与纳米尺度物理 · 物理学 2012-10-11 Olafur Jonasson , Chi-Shung Tang , Hsi-Sheng Goan , Andrei Manolescu , Vidar Gudmundsson
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