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The differential polarizability, due to near-infrared light at 1126 nm, of the 27Al+ 1S0 -> 3P0 clock transition is measured to be 4\pi\epsilon_0 x (1.6 +/- 0.5) x 10^{-31} m^3. This measurement is combined with experimental oscillator…

We consider a narrow magneto-dipole transition in the $^{169}$Tm atom at the wavelength of $1.14\,\mu$m as a candidate for a 2D optical lattice clock. Calculating dynamic polarizabilities of the two clock levels $[\text{Xe}]4f^{13}6s^2…

The electric dipole-forbidden, quadrupole 6S1/2 <-> 5D3/2 transition in Ba+ near 2051 nm, with a natural linewidth of 13 mHz, is attractive for potential observation of parity non-conservation, and also as a clock transition for a barium…

We identify Ba$^{4+}$ (Te-like) as a promising candidate for a high-accuracy optical clock. The lowest-lying electronic states are part of a $^3P_J$ fine structure manifold with anomalous energy ordering, being non-monotonic in $J$. We…

原子物理 · 物理学 2020-10-26 Kyle Beloy , Vladimir A. Dzuba , Samuel M. Brewer

Frequency shifts of the ^199Hg^+ 5d^10 6s ^2S_1/2 (F=0, M_F=0) to 5d^9 6s^2 ^2D_5/2 (F=2, M_F=0) electric-quadrupole transition at 282 nm due to external fields are calculated, based on a combination of measured atomic parameters and ab…

原子物理 · 物理学 2007-05-23 W. M. Itano

The systematic shifts of the transition frequencies in the molecular hydrogen ions are of relevance to ultra-high-resolution radio-frequency, microwave and optical spectroscopy of these systems, performed in ion traps. We develop the…

原子物理 · 物理学 2015-06-16 Dimitar Bakalov , Stephan Schiller

Molecular hydrogen ions are of metrological relevance due to the possibility of precise theoretical evaluation of their spectrum and of external-field-induced shifts. In homonuclear molecular ions the electric dipole $E1$ transitions are…

原子物理 · 物理学 2021-01-20 P. Danev , D. Bakalov , V. I. Korobov , S. Schiller

We report a measurement of the radium ion's $7p$ ${}^{2}P_{3/2}$ state lifetime, $\tau=4.78(3)$ ns. The measured lifetime is in good agreement with theoretical calculations, and will enable a determination of the differential scalar…

原子物理 · 物理学 2024-02-16 M. Fan , C. A. Holliman , A. Contractor , C. Zhang , S. F. Gebretsadkan , A. M. Jayich

We demonstrate a method for precision spectroscopy on trapped ions in the limit of unresolved motional sidebands. By sympathetic cooling of a chain of crystallized ions we suppress adverse temperature variations induced by the spectroscopy…

原子物理 · 物理学 2009-11-13 M. Herrmann , V. Batteiger , S. Knünz , G. Saathoff , Th. Udem , T. W. Hänsch

Accurate values of electric dipole (E1) amplitudes along with their uncertainties for a number of transitions among low-lying states of Mg$^+$, Ca$^+$, Sr$^+$, and Ba$^+$ are listed by carrying out calculations using a relativistic…

原子物理 · 物理学 2020-12-30 Mandeep Kaur , Danish Furekh Dar , B. K. Sahoo , Bindiya Arora

We report on a theoretical analysis of the suitability of the 7s 2S1/2 <-> 6d 2D3/2 transition in singly ionized radium to measure parity nonconservation, in the light of an experiment planned at the KVI of the University of Groningen.…

原子物理 · 物理学 2008-08-04 L. W. Wansbeek , B. K. Sahoo , R. G. E. Timmermans , K. Jungmann , B. P. Das , D. Mukherjee

We performed accurate calculation of $\alpha$-dependence ($\alpha=e^2/hc$) of the transition frequencies for ions, which are used in a search for the variation of the fine structure constant $\alpha$ in space-time. We use Dirac-Hartree-Fock…

原子物理 · 物理学 2009-08-18 V. A. Dzuba , V. V. Flambaum , M. G. Kozlov , M. Marchenko

Motivated by recent experimental advances, including the ongoing development of an optical atomic clock in singly ionised radium, we perform a detailed theoretical characterisation of Ra+ and its lighter analogue, Ba+. Both ions are of…

原子物理 · 物理学 2025-09-30 Robin B. Cserveny , Benjamin M. Roberts

We evaluate the electric quadrupole moments of the ${^1}\!S_0$ and ${^3}\!P_0$ clock states of $^{27}$Al$^+$ and $^{115}$In$^+$. To capture all dominant contributions, our analysis extends through third order of perturbation theory and…

原子物理 · 物理学 2017-04-11 K. Beloy , D. R. Leibrandt , W. M. Itano

We consider transitions of electron holes (vacancies in otherwise filled shells of atomic systems) in multiply-charged ions that, due to level-crossing of the holes, have frequencies within the range of optical atomic clocks. Strong E1…

原子物理 · 物理学 2011-07-21 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We measure the complete set of transition frequencies necessary to laser cool and trap MgF molecules. Specifically, we report the frequency of multiple low $J$ transitions of the $X^2\Sigma^+(v^{\prime\prime}=0,1) \rightarrow…

Isotope shifts of $^{223-226,228}$Ra$^{19}$F were measured for different vibrational levels in the electronic transition $A^{2}{}{\Pi}_{1/2}\leftarrow X^{2}{}{\Sigma}^{+}$. The observed isotope shifts demonstrate the particularly high…

We report on spectroscopic results on the $^2S_{1/2} \rightarrow\,^2P_{3/2}$ transition in single trapped Yb$^+$ ions. We measure the isotope shifts for all stable Yb$^+$ isotopes except $^{173}$Yb$^+$, as well as the hyperfine splitting of…

原子物理 · 物理学 2018-03-28 Thomas Feldker , Henning Fürst , Norman Ewald , Jannis Joger , Rene Gerritsma

We demonstrate an optical single qubit based on 6S1/2 to 5D5/2 quadrupole transition of a single Ba+ ion operated by diode based lasers only. The resonance wavelength of the 6S1/2 to 5D5/2 quadrupole transition is about 1762 nm which…

原子物理 · 物理学 2017-08-21 Dahyun Yum , Debashis De Munshi , Tarun Dutta , Manas Mukherjee

We present spectroscopic data for four metastable state clear-out transitions between 399 nm and 412 nm for all even long-lived isotopes of Yb$^+$ as well as their hyperfine structure in $^{171}$Yb$^+$. The strong $^2 \rm{D}_{3/2}…