相关论文: Spectroscopy of electric dipole and quadrupole tra…
Highly charged ions (HCIs) are promising candidates for the next generation of atomic clocks, owing to their tightly bound electron cloud, which significantly suppresses the common environmental disturbances to the quantum oscillator. Here…
The optical manipulation of Ba$^{+}$ ions is mainly performed by a 493 nm laser for the S$_{1/2}$-P$_{1/2}$ transition and a 650 nm laser for the P$_{1/2}$-D$_{3/2}$ transition. Since the branching ratio between the 493 nm and 650 nm…
We describe experimental investigations on an optical frequency standard based on a laser cooled 171Yb+ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the 2S1/2(F=0) ground state to the 2D3/2(F=2) state…
We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the…
We report a precise measurement of the isotope shifts in the $4^2$S$_{1/2} \rightarrow 3^2$D$_{3/2}$ electric quadrupole transition at 732~nm in $^{40 - 42,44,48}$Ca$^+$ via high-resolution laser spectroscopy of co-trapped ions, finding…
In this paper we present a technique for the precise measurement of electric dipole allowed transitions in trapped ions. By applying a probe and a cooling laser in quick succession, the full transition can be probed without causing…
We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…
In hot plasmas, a temperature of a few tens of eV is sufficient for producing highly stripped ions where multipole transitions become important. At low density, the transitions from tightly bound inner shells lead to electric-quadrupole…
Our study is motivated by the prospect of several metastable states in the Sb$ ^{+} $, Au$ ^{+} $, and Hg$ ^{2+} $ ions being used as possible candidates for optical clocks. We calculate several atomic properties relevant to the development…
Quadrupole shifts for three prominent clock transitions, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{3/2}$, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{5/2}$ and $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{13} 6s^2]…
Recent theoretical works have proposed atomic clocks based on narrow optical transitions in highly charged ions. The most interesting candidates for searches of new physics are those which occur at rare orbital crossings where the shell…
$^{133}\text{Ba}^+$ has been identified as an attractive ion for quantum information processing due to the unique combination of its spin-1/2 nucleus and visible wavelength electronic transitions. Using a microgram source of radioactive…
Optical frequency comparison of the 40Ca+ clock transition \nu_{Ca} (2S1/2-2D5/2, 729nm) against the 87Sr optical lattice clock transition \nu_{Sr}(1S0-3P0, 698nm) has resulted in a frequency ratio \nu_{Ca} / \nu_{Sr} = 0.957 631 202 358…
We report on improved isotope shift measurements of the isotopes $^{40,42,44,48}$Ca in the $4s\,^2 \rm{S}_{\frac{1}{2}} \rightarrow 4p\,^2\rm{P}_{\frac{3}{2}}$ (D2) transition using collinear laser spectroscopy. Accurately known isotope…
We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition 2S1/2(F=0) -> F7/2(F=3) in a single trapped 171Yb+ ion. The extraordinary features of this transition result…
An atom exposed to an electric field will experience Stark shifts of its internal energy levels, proportional to their polarizabilities. In optical frequency metrology, the Stark shift due to background black-body radiation (BBR) modifies…
We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock…
The blackbody radiation shift of the Ga$^+$ $4s^2 \ ^1S^e_0 \to 4s4p \ ^3P^o_0$ clock transition is computed to be $-$$0.0140 \pm 0.0048$ Hz at 300 K. The small shift is consistent with the blackbody shifts of the clock transitions of other…
We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the…
Motivated by recent measurements for several alkali-metal atoms and alkali-metal-like ions, we perform a detailed study of electric dipole (E1) transition amplitudes in K, Ca+, Rb, Sr+, Cs, Ba+, Fr, and Ra+, which are of interest for…