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The layered structure of 2D metal halide perovskites (MHPs) consisting of an ionic metal halide octahedral layer electronically separated by an organic cation, exhibits strong coupling between high-binding-energy excitons and low-energy…

Self-assembled hybrid perovskite quantum wells have attracted attention due to their tunable emission properties, ease of fabrication and device integration. However, the dynamics of excitons in these materials, especially how they couple…

Metal halide perovskites exhibit a materials physics that is distinct from traditional inorganic and organic semiconductors. While materials such as CH3NH3PbI3 are non-magnetic, the presence of heavy elements (Pb and I) in a…

2D Ruddlesden-Popper perovskites are compelling platforms for quantum-confined optoelectronics. However, polar order in iodide composition remains rare under ambient conditions, and the mechanistic origin of anomalous photoluminescence in…

There is a growing consensus that the exceptional optoelectronic properties of metal halide perovskites (MHPs) are largely due to the peculiar interplay between the inorganic cage lattice, composed of a labile network of corner-sharing…

材料科学 · 物理学 2026-05-21 Alejandro R. Goñi

The exceptional optoelectronic properties of metal halide perovskites (MHPs) are presumed to arise, at least in part, from the peculiar interplay between the inorganic metal-halide sublattice and the atomic or molecular cations enclosed in…

Metal halide perovskites have shown great performance as solar energy materials, but their outstanding optoelectronic properties are paired with unusually strong anharmonic effects. It has been proposed that this intriguing combination of…

The organic-inorganic hybrid perovskite CH3NH3PbI3 has attracted significant interest for its high performance in converting solar light into electrical power with an efficiency exceeding 20%. Unfortunately, chemical stability is one major…

材料科学 · 物理学 2018-03-02 Yue-Yu Zhang , Shiyou Chen , Peng Xu , Hongjun Xiang , Xin-Gao Gong , Aron Walsh , Su-Huai Wei

Halide perovskites, such as methylammonium lead bromide (MAPbBr$_3$), host tightly bound three-dimensional excitons which are robust at room temperature. Excellent optical properties of MAPbBr$_3$ allow for designing of optical single-mode…

Two-dimensional (2D) hybrid organic--inorganic perovskites (HOIPs) are promising candidates for next-generation optoelectronic and spintronic applications. This work systematically investigates the relationship between structural…

材料科学 · 物理学 2026-04-10 Yue Zhao , Fu Li , Vikrant Chaudhary , Hongbin Zhang , Gaoyang Gou , Niuzhuang Yang , Yue Hao , Wenyi Liu

Epitaxial III-V semiconductor heterostructures are key components in modern microelectronics, electro-optics and optoelectronics. With superior semiconducting properties, halide perovskite materials are rising as promising candidates for…

材料科学 · 物理学 2016-08-23 Yiping Wang , Zhizhong Chen , Felix Deschler , Xin Sun , Toh-Ming Lu , Esther Wertz , Jia-Mian Hu , Jian Shi

Halide perovskite materials raised tremendous interest in recent years since their cheap fabrication, superior performance in both solar cell and light emitting diode (LED). Due to the existence of layered quantum well structure, quasi…

材料科学 · 物理学 2021-11-23 Wei Tang , Liting Tao , Tian Zhang , Yanjun Fang , Deren Yang , Linjun Li

The MAPbI$_3$ halide perovskite single crystals are studied at 5 K temperature using the photoluminescence excitation spectroscopy. Two non-interacting types of states are determined: bound excitons and defect-related states. Excitation of…

介观与纳米尺度物理 · 物理学 2020-05-07 A. O. Murzin , N. I. Selivanov , V. O. Kozlov , I. I. Ryzhov , A. V. Emeline , Yu. V. Kapitonov

Optically active defects often play a crucial role in governing the light emission as well as the electronic properties of materials. Moreover, defect-mediated states in the mid-gap region can trap electrons, thus opening a path for the…

材料科学 · 物理学 2025-01-03 Aprajita Joshi , Sajid Saikia , Shalini Badola , Angshuman Nag , Surajit Saha

Strain is an effective strategy to modulate the optoelectronic properties of 2D materials, but it has been almost unexplored in layered hybrid organic-inorganic metal halide perovskites (HOIPs) due to their complex band structure and…

Under external stimuli, lead halide perovskites exhibit large atomic fluctuations, impacting optical and electron transport properties that affect device performance in operational settings. However, a thorough understanding of the atomic…

In recent years, metal halide perovskites have generated tremendous interest for optoelectronic applications and their underlying fundamental properties. Due to the large electron-phonon coupling characteristic of soft lattices,…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

材料科学 · 物理学 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

State-of-the-art hybrid perovskites have demonstrated excellent functionality in photovoltaics and light-emitting applications, and have emerged as a promising candidate for exciton-polariton (polariton) optoelectronics. In the strong…

In pursuit of an all-inorganic non-toxic perovskite solar cell (PSC) with enhanced performance, we have investigated the rhombohedral phase of the germanium-based rubidium halide perovskites RbGeX$_3$ (X = Cl, Br, I). The structural…

材料科学 · 物理学 2025-05-15 Piyush Kumar Dash , Palash Banarjee , Anupriya Nyayban , Subhasis Panda