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CuInP2S6 (CIPS) is an emerging layered material that exhibits ferrielectric ordering well above room temperature (Curie temperature TC ~ 315 K). When synthesized with Cu deficiencies, CIPS spontaneously segregates into CuInP2S6 and…

材料科学 · 物理学 2021-11-02 Rahul Rao , Ryan Selhorst , Benjamin S. Conner , Michael A. Susner

An analytical theory is developed for predicting the nonlinear susceptibility of ionic polarization to continuous electromagnetic waves in both bulk and strained thin film ferroelectrics. Using a perturbation method for solving the…

The temperature behaviour in the range 22\degree C to 500\degree C of the dielectric permittivity in the infrared range is investigated for CaF2, BaF2 and Al2O3 through reflectivity measurements. The dielectric permittivity is retrieved by…

Piezoelectric and ferroelectric properties in the two dimensional (2D) limit are highly desired for nanoelectronic, electromechanical, and optoelectronic applications. Here we report the first experimental evidence of out-of-plane…

Ferroelectrics that are also ionic conductors offer possibilities for novel applications with high tunability, especially if the same atomic species causes both phenomena. In particular, at temperatures just below the Curie temperature,…

材料科学 · 物理学 2022-03-04 Andrew O'Hara , Nina Balke , Sokrates T. Pantelides

Identifying intrinsic low-dimensional ferromagnets with high transition temperature and electrically tunable magnetism is crucial for the development of miniaturized spintronics and magnetoelectrics. Recently long-range 2D ferromagnetism…

材料科学 · 物理学 2020-08-27 Hua Wang , Jingshan Qi , Xiaofeng Qian

Nanoscaled room-temperature ferroelectricity is ideal for developing advanced non-volatile high-density memories. However, reaching the thin film limit in conventional ferroelectrics is a long-standing challenge due to the possible critical…

材料科学 · 物理学 2018-10-15 Siyuan Wan , Yue Li , Wei Li , Xiaoyu Mao , Wenguang Zhu , Hualing Zeng

In this study, we investigate the underlying mechanisms of the negative piezoelectricity in low--dimensional materials by carrying out first--principles calculations. Two--dimensional ferroelectric CuInP$_2$S$_6$ is analyzed in detail as a…

材料科学 · 物理学 2021-06-02 Yubo Qi , Andrew M. Rappe

Coherent ferrons, the quanta of polarization waves, can potentially be hybridized with many other quasiparticles for achieving novel control modalities in quantum communication, computing, and sensing. Here, we theoretically demonstrate a…

Multiferroic materials are potential to be applied in novel magnetoelectric devices, for example, high-density non-volatile storage. Last decades, research on multiferroic materials was focused on three-dimensional (3D) materials. However,…

材料科学 · 物理学 2019-02-25 Youfang Lai , Zhigang Song , Yi Wan , Mingzhu Xue , Yu Ye , Lun Dai , Wenyun Yang , Honglin Du , jinbo Yang

The appearance of spontaneous polarization in CuInP$_{2}$S$_{6}$ ferrielectrics is related to the second order Jahn-Teller effect for copper cations located in a double-well local potential, the stereoactivity of indium cations located in a…

软凝聚态物质 · 物理学 2024-03-25 R. Yevych , V. Liubachko , V. Hryts , M. Medulych , A. Kohutych , Yu. Vysochanskii

VO2 is well known for its dual phase transitions; electrical as well as structural, at a single temperature of 340K. The low temperature structural phases of VO2 are different from its high temperature counterpart by means of structural…

材料科学 · 物理学 2021-09-16 Raktima Basu , G. Mangamma , Sandip Dhara

The so-called interlayer-sliding ferroelectricity was recently proposed as an unconventional route to pursuit electric polarity in van der Waals multi-layers, which was already experimentally confirmed in WTe$_2$ bilayer even though it is…

材料科学 · 物理学 2021-08-17 Ning Ding , Jun Chen , Churen Gui , Haipeng You , Xiaoyan Yao , Shuai Dong

Twistronics has received much attention as a new method to manipulate the properties of 2D van der Waals structures by introducing moir\'e patterns through a relative rotation between two layers. Here we begin a theoretical exploration of…

In recent years, sliding ferroelectricity has emerged as a topic of significant interest due to its possible application in non-volatile, reconfigurable storage devices. This phenomenon is unique to two-dimensional van der Waals materials,…

The layered van der Waals (vdW) ferroelectric CuInP2S6 (CIPS) exhibits unique cation hopping-driven phenomena that bring about unconventional properties with intriguing mechanisms and hold promises for advanced applications in…

Van der Waals layered chalcogenide-based flexible thermoelectric devices show great potential for applications in wearable electronics. However, materials that are both highly deformable and exhibit superior thermoelectric performance are…

材料科学 · 物理学 2024-10-10 Qi Ren , Yingzhuo Lun , Bonan Zhu , Gang Tang , Jiawang Hong

Magnetic order in van der Waals magnets can strongly influence their lattice dynamics, yet how this interaction manifests across different phonon length scales remains unclear. Optical phonons probe bond-scale exchange modulation and…

Two-dimensional (2D) van der Waals ferroelectrics provide an unprecedented architectural freedom for the creation of artificial multiferroics and non-volatile electronic devices based on vertical and co-planar heterojunctions of 2D ferroic…

We address the sliding thermodynamics of van der Waals-bonded bilayers by the continuum elasticity theory. We attribute the robustness of the ferroelectricity recently observed in h-BN and WTe2 bilayers to large monolayer in-plane…

介观与纳米尺度物理 · 物理学 2023-05-10 Ping Tang , Gerrit E. W. Bauer