相关论文: Virial Equation of State for a Granular System
The ideal gas law of physics and chemistry says that PV = nRT. This law is a statement of the relationship between four variables (P, V, n, and T) that reflect properties of a quantity of gas in a container. The law enables us to make…
A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…
Simulation results of dense granular gases with particles of different size are compared with theoretical predictions concerning the pair-correlation functions, the collison rate, the energy dissipation, and the mixture pressure. The…
The departure from ideal gas behavior is described by several known equations of state (EoS), developed from a combination of theoretical considerations and experimental correlations. In this work a different approach is proposed, in which…
Realistic equations of state valid in the whole state space of a multi-component mixture should satisfy at least three important constraints: (i) The Gibbs phase rule holds. (ii) At low densities, one can deduce a virial equation of state…
Two-component, ideal, self-gravitating fluids are conceived as macrogases, and the related equation of state is expressed using the virial theorem for subsystems, under the restriction of homeoidally striated density profiles. Shallower…
The properties of plasmas in the low-density limit are described by virial expansions. Analytical expressions are known from Green's function approaches only for the first three virial coefficients. Accurate path integral Monte Carlo (PIMC)…
The virial expansion of a gas is a correction to the ideal gas law that is usually discussed in advanced courses in statistical mechanics. In this note we outline this derivation in a manner suitable for advanced undergraduate and…
By using exact Path Integral Monte Carlo methods we calculate the equation of state of an interacting Bose gas as a function of temperature both below and above the superfluid transition. The universal character of the equation of state for…
We present an example counter to the widely-accepted concept on equilibrium states that "Any thermodynamic equilibrium state of two component systems is determined by specifying 4 thermodynamic variables that include at least 1 extensive…
A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…
We investigate how an equation of state for matter is affected when a gravity is present. For this purpose, we consider a box of ideal gas in the presence of Newtonian gravity. In addition to the ordinary thermodynamic quantities, a…
We report experimental results on the behavior of an ensemble of inelastically colliding particles, excited by a vibrated piston in a vertical cylinder. When the particle number is increased, we observe a transition from a regime where the…
We have considered a model of a small finite system with internal particles and surface degrees of freedom. All the main statistical distributions were explicitly obtained, on a pre thermodynamic limit basis. The concept of temperature or…
Despite its importance in geological sciences, our understanding of interactions between gas and condensed phases (comprising solids and liquids) remains clouded by the fact that, often, only indirect evidence remains for their occurrence.…
Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes…
The equation of state for a two-dimensional hard-sphere gas is difficult to calculate by usual methods. In this paper we develop an approach for calculating the equation of state of hard-sphere gases, both for two- and three-dimensional…
A recently suggested equation of state with the induced surface tension is generalized to the case of quantum gases with mean-field interaction. The self-consistency conditions of such a model and the necessary one to obey the Third Law of…
In this paper, we consider an optimal control problem in equilibrium thermodynamics of gases. Thermodynamic state of the gas is given by a Legendrian submanifold in a contact thermodynamic space. Using Pontryagin's maximum principle we find…
Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…