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The alloy strategy through A- or X-site is a common method for experimental preparation of high-performance and stable lead-based perovskite solar cells. As one of the important candidates for lead-free and stable photovoltaic absorber, the…

Nitride perovskites are an emerging class of materials predicted to exhibit diverse functional properties, yet remain underexplored due to synthesis challenges of oxygen-free nitrides. Recently, LaMoN$_3$ has been reported as an oxygen-free…

Since perovskite solar cells have attracted a lot of attentions over the past years, the enhancement of their optical absorption and current density are among the basic coming challenges. For this reason, first, we have studied structural…

Solar cells based on organic-inorganic metal halide perovskites show efficiencies close to highly-optimized silicon solar cells. However, ion migration in the perovskite films leads to device degradation and impedes large scale commercial…

Metal halide perovskite solar cells have achieved dramatic improvements in their power conversion efficiency in the recent past. Since compositional engineering plays an important role in optimizing material properties, we investigate the…

Silicon oxide (SiOx) has been widely used in many electronic systems as a supportive and insulating medium. Here we demonstrate various electrical phenomena such as negative differential resistance, resistive switching and current…

材料科学 · 物理学 2011-02-17 Jun Yao , Lin Zhong , Douglas Natelson , James M. Tour

As a possible alternative to organic-inorganic hybrid perovskite halide, inorganic Cs2SnI6 has drawn more and more research attention recently. In order to find more Cs2SnI6 derivatives as the potential solar cell absorber materials, I-…

材料科学 · 物理学 2021-08-10 Wang Xuan , Tang Yehua , Nairui Xiao , Wang Ke-Fan

Two-dimensional (2D) layered lead iodide (PbI2) is an important precursor and common residual species during the synthesis of lead-halide perovskites. There currently exist some debates and uncertainties about the effect of excess PbI2 on…

材料科学 · 物理学 2022-04-20 Hongfei Chen , Hejin Yan , Yongqing Cai

Lead halide perovskite solar cells have recently emerged as a very promising photovoltaic technology due to their excellent power conversion efficiencies; however, the toxicity of lead and the poor stability of perovskite materials remain…

Perovskite photovoltaics has witnessed an unprecedented increase in power conversion efficiency over the last decade. The choice of transport layers, through which photo-generated electrons and holes are transported to the electrodes, is a…

应用物理 · 物理学 2020-07-10 Eline M. Hutter , Thomas Kirchartz , Bruno Ehrler , David Cahen , Elizabeth von Hauff

Organic or inorganic (A) metal (M) halide (X) perovskites (AMX3) are semiconductor materials setting the basis for the development of highly efficient, low-cost and multijunction solar energy conversion devices. The best efficiencies…

材料科学 · 物理学 2018-10-17 Frederike Lehmann , Silvia Binet , Alexandra Franz , Andreas Taubert , Susan Schorr

The recent reaching of 20% of conversion efficiency by solar cells based on metal hybrid perovskites (MHP), e.g., the methylammonium (MA) lead iodide, CH3NH3PbI3 (MAPbI3), has excited the scientific community devoted to the photovoltaics…

化学物理 · 物理学 2018-12-14 Diego Guedes-Sobrinho , Ivan Guilhon , Marcelo Marques , Lara K. Teles

To be able to increase the efficiency of perovskite solar cells which is one of the most substantial challenges ahead in photovoltaic industry, the structural and optical properties of perovskite CH3NH3PbI3-xBrx for values x=1-3 have been…

A little addition of Cl to \ce{MAPbI3} has been reported to improve the material stability as well as light harvesting and carrier conducting properties of organometal trihalide perovskites, the key component of perovskite solar cell (PSC).…

材料科学 · 物理学 2017-09-22 Un-Gi Jong , Chol-Jun Yu , Yong-Man Jang , Gum-Chol Ri , Song-Nam Hong , Yong-Hyon Pae

The hybrid halide perovskite CH$_{3}$NH$_{3}$PbI$_{3}$ has enabled solar cells to reach an efficiency of about 18\%, demonstrating a pace for improvements with no precedents in the solar energy arena. Despite such explosive progress, the…

材料科学 · 物理学 2015-05-20 Carlo Motta , Fedwa El Mellouhi , Sabre Kais , Nouar Tabet , Fahhad Alharbi , Stefano Sanvito

Ionic migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. However, a major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial…

Photochemical stability of encapsulated films of mixed halide perovskites with a range of MAPb(I1-xBrx)3 compositions (solid solutions) was investigated under accelerated stressing using concentrated sunlight. Evolution of light absorption…

Negative capacitance at the low-frequency domain and inverted hysteresis are familiar features in perovskite solar cells, where the origin is still under discussion. Here we use Impedance Spectroscopy to analyse these responses in…

Recently, superconductivity at about 9-15K was discovered in Nd$_{1-x}$Sr$_x$NiO$_2$ infinite-layer thin films, which has stimulated enormous interests in related rare-earth nickelates. Usually, the first step to synthesize this 112 phase…

超导电性 · 物理学 2021-11-23 Chengping He , Xue Ming , Qing Li , Xiyu Zhu , Jin Si , Hai-Hu Wen

In the present study, we report the synthesis and characterization of a low-temperature solution-processable monodispersed nickel cobaltite (NiCo2O4) nanoparticles via a combustion synthesis using tartaric acid as fuel and demonstrate its…