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Magnetic and dielectric properties on a polycrystalline La0.7Bi0.3CrO3 have been investigated. A canted antiferromagnetic (CAF) phase transition giving weak ferromagnetism at TN = 230K has been observed. M-H at 10K shows non-saturating…

强关联电子 · 物理学 2014-03-17 Aga Shahee , Dhirendra kumar , N. P. Lalla

We have measured near normal incidence far infrared (FIR) reflectivity spectra of a single crystal of TbMnO3 from 10K to 300K in the spectral range of 50 cm$^{-1}$ to 700 cm$^{-1}$. Fifteen transverse optic (TO) and longitudinal optic (LO)…

材料科学 · 物理学 2015-05-13 Pradeep Kumar , Surajit Saha , C. R. Serrao , A. K. Sood , C. N. R. Rao

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

统计力学 · 物理学 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

We measured the temperature dependent infrared reflectivity spectra of MnF2 between 4 K and room temperature. We show that the phonon spectrum undergoes a strong renormalization at TN. The ab-initio calculation we performed on this compound…

材料科学 · 物理学 2010-10-20 R. Schleck , Y. Nahas , R. P. S. M. Lobo , J. Varignon , M. B. Lepetit , C. S. Nelson , R. L. Moreira

Historically, the soft mode theory of ferroelectric phase transitions has been developed for the high-temperature (paraelectric) phase, where the phonon mode softens upon decreasing the temperature. In the low-temperature ferroelectric…

材料科学 · 物理学 2021-03-19 Luigi Casella , Alessio Zaccone

Raman scattering in relaxor ferroelectric PbMg1/3Ta2/3O3 (PMT) was investigated in the single crystalline form in the temperature range of 20 - 295 K. Anomalous temperature dependence of the integrated intensity and the Raman line contours…

材料科学 · 物理学 2007-05-23 S. G. Lushnikov , S. N. Gvasaliya , R. S. Katiyar

We report structural, magnetic, and Raman studies of the disordered double perovskite GdSrCoMnO$_{6}$~(GSCM). DC magnetization shows a ferromagnetic transition at $T_{C} \approx 153$~K. The inverse susceptibility exhibits a downturn above…

We study from first-principles calculations the ferroelectric structural phase transition of Pb$_5$Ge$_3$O$_{11}$ crystal. The calculations of phonons and Born effective charges of the paraelectric phase allow us to identify a polar…

材料科学 · 物理学 2024-01-18 Mauro Fava , William Lafargue-Dit-Hauret , Aldo H. Romero , Eric Bousquet

The authors of paper commented claim that trimethylammonium tetrachlorozincate crystal shows at 282 K the ferroelectric-paraelectric phase transition. But no ferroelectric hysteresis loop was observed below this temperature. Moreover, in…

材料科学 · 物理学 2016-04-07 Zbigniew Tylczynski

Measurements of ferroelectric polarization and dielectric constant were done on $R$Mn$_2$O$_5$ ($R$=Tb, Dy, and Ho) with applied hydrostatic pressures of up to 18 kbar. At ambient pressure, distinctive anomalies were observed in the…

强关联电子 · 物理学 2009-11-13 C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Wang , S. Park , S-W. Cheong , M. M. Gospodinov , C. W. Chu

We have investigated dielectric properties in a series of crystals of $R$MnO$_{3}$ ($R$ is a rare earth ion) under magnetic fields and quasihydrostatic pressure. We have found that ferroelectric phase appeared in GdMnO$_3$ crystal below…

强关联电子 · 物理学 2009-11-10 H. Kuwahara , K. Noda , J. Nagayama , S. Nakamura

Microwave measurements have recently been successfully applied to measure ferroelectric materials on the nanoscale, including detection of polarization switching and ferroelectric domain walls. Here we discuss the question whether scanning…

材料科学 · 物理学 2021-11-24 Mykola Yelisieiev , Petro Maksymovych , Anna N. Morozovska

Neutron diffraction studies have been carried out on a single crystal of oxygen-deficient perovskite TbBaCo2O5.5 in the temperature range of 7-370 K. There have been observed several magnetic or structural transitions. Among these, the…

强关联电子 · 物理学 2009-11-10 Minoru Soda , Yukio Yasui , Toshiaki Fujita , Takeshi Miyashita , Masatoshi Sato , Kazuhisa Kakurai

We provide a detailed study of the reflectivity of multiferroic TbMnO_3 for wave numbers from 40 cm^{-1} to 1000 cm^{-1} and temperatures 5 K < T < 300 K. Excitations are studied for polarization directions E || a, the polarization where…

强关联电子 · 物理学 2010-01-22 M. Schmidt , Ch. Kant , T. Rudolf , F. Mayr , A. A. Mukhin , A. M. Balbashov , J. Deisenhofer , A. Loidl

Dielectric measurements on 0.65[Pb(Ni_1/3Nb_2/3)O_3]-0.35PbTiO_3 ceramic in the temperature range 90K to 470K shows a relaxor ferroelectric transition around 350K with a Vogel-Fulcher freezing temperature of 338K and appearance of a…

材料科学 · 物理学 2007-06-08 Satendra Pal Singh , Akhilesh Kumar Singh , Dhananjai Pandey , S. M. Yusuf

Commencing from the centrosymmetric MnRMnSbO$_6$ compound, we explore the realm of magnetic polar double-double perovskite oxides characterized by significant ferroelectric polarization. Employing symmetry operations, first-principles…

材料科学 · 物理学 2024-03-11 Monirul Shaikh , Duo Wang , Saurabh Ghosh

The halide double perovskite Cs$_2$AgBiBr$_6$ has been proposed as a potential replacement for organic halide perovskites for photovoltaic applications. Further investigation of its dielectric response, optical properties and structural…

The dielectric constant of multiferroic hexagonal HoMnO_3 exhibits an unprecedented diversity of anomalies at low temperatures (1.8 K< T <10 K) and under external magnetic fields related to magnetic phase transitions in the coupled system…

强关联电子 · 物理学 2009-11-11 F. Yen , C. R. dela Cruz , B. Lorenz , Y. Y. Sun , Y. Q. Wang , M. M. Gospodinov , C. W. Chu

In this letter we investigated the temperature-dependent Raman spectra of CaMn7O12 helimagnet from room temperature down to 10 K. The temperature dependence of the Raman mode parameters show remarkable anomalies for both antiferromagnetic…

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

材料科学 · 物理学 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen