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相关论文: Two Displacive Ferroelectric Phase Transitions in …

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We report complex dielectric and Raman spectroscopy measurements in four samples of $\alpha$- Fe$_2$O$_3$, consisting of crystallites which are either hexagonal shaped plates or cuboids. All four samples exhibit the spin reorientation…

强关联电子 · 物理学 2019-04-17 Namrata Pattanayak , Jitender Kumar , Partha Pratim Patra , G. V. Pavan Kumar , Ashna Bajpai

Simple perovskite crystals undergo structural phase transitions on cooling to low temperatures, which significantly change the material properties of the crystal. In this work we rigorously characterize the temperature evolution of…

材料科学 · 物理学 2025-06-18 Zijun C. Zhao , Maxim Goryachev , Jerzy Krupka , Michael E. Tobar

The ferroelectric to paraelectric phase transition of multiferroic CaMnTi$_2$O$_6$ has been investigated at high pressures and ambient temperature by second harmonic generation (SHG), Raman spectroscopy, and powder and single-crystal x-ray…

Using first-principles density functional calculations, we study the electronic and magnetic properties of ferromagnetic insulating double-perovskite compound La2NiMnO6, which has been reported to exhibit interesting magnetic field…

材料科学 · 物理学 2008-05-09 Hena Das , Umesh V. Waghmare , T. Saha-Dasgupta , D. D. Sarma

Infrared reflectivity spectra of cubic SrMnO$_{3}$ ceramics reveal 18 % stiffening of the lowest-frequency phonon below the antiferromagnetic phase transition occurring at T$_{N}$ = 233 K. Such a large temperature change of the polar phonon…

The Griffiths phase-like features and the spin-phonon coupling effects observed in Tb$_2$NiMnO$_6$ are reported. The double perovskite compound crystallizes in monoclinic $P2_1/n$ space group and exhibits a magnetic phase transition at $T_c…

In this paper, we present the spin-phonon coupling and dielectric response of nano-crystalline Pr$_2$CoMnO$_6$ employing Raman and dielectric spectroscopic study. Pr$_2$CoMnO$_6$ is a manganite compound , it undergoes a paramagnetic to…

强关联电子 · 物理学 2021-04-13 Ilyas Noor Bhatti , Imtiaz Noor Bhatti

The infrared (IR) active phonons in multiferroic TbMn$_2$O$_5$ are studied as a function of temperature. Most of the symmetry allowed IR modes polarized along the \textit{a} and \textit{b} crystal axes are observed and the behavior of…

材料科学 · 物理学 2007-10-23 R. Valdés Aguilar , A. B. Sushkov , S. Park , S-W. Cheong , H. D. Drew

Polarized Raman scattering spectra of the K_xCo_{2-y}Se_2 single crystals reveal the presence of two phonon modes, assigned as of the A_{1g} and B_{1g} symmetry. Absence of additional modes excludes the possibility of vacancy ordering,…

Microwave (MW) transmission, absorption, and reflection loss spectra of the ferrimagnetic U-type hexaferrite Sr$_4$CoZnFe$_{36}$O$_{60}$ ceramics were studied from 100 MHz to 35 GHz at temperatures between 10 and 390 K. 9 MW magnetic…

材料科学 · 物理学 2024-08-08 M. Kempa , V. Bovtun , D. Repček , J. Buršík , C. Kadlec , S. Kamba

Dielectric response e*(f,T) and polar phonon spectra of coarse grain (grain size ~ 4 mkm) and fine grain (grain size ~ 150 nm) ceramics of PbMg_(1/3)Nb_(2/3)O3-35%PbTiO3 were investigated at temperatures 10 - 900 K. e*(f,T) in coarse-grain…

材料科学 · 物理学 2009-04-28 V. Bovtun , S. Kamba , S. Veljko , D. Nuzhnyy , J. Kroupa , M. Savinov , P. Vanek , J. Petzelt , J. Holc , M. Kosec , H. Amorin , M. Alguero

In this paper the structural, magnetic, and dielectric properties of langasite compound Pb$_3$TeMn$_3$P$_2$O$_{14}$ have been investigated as a candidate of short-range magnetic correlations driven development of dielectric anomaly above…

材料科学 · 物理学 2021-07-01 Rafikul Ali Saha , Desheng Fu , Mitsuru Itoh , Sugata Ray

We have carried out temperature-dependent inelastic neutron scattering measurements of YMnO3 over the temperature range 50 - 1303 K, covering both the antiferromagnetic to paramagnetic transition (70 K), as well as the ferroelectric to…

Neutron scattering measurements of the lowest-energy TO phonons in the relaxor Pb(Mg1/3Nb2/3)O3 (PMN) are reported for 10<=T<=750 K. The soft mode, which is overdamped by the polar nanoregions below the Burns temperature T_d = 620 K,…

材料科学 · 物理学 2009-11-07 S. Wakimoto , C. Stock , R. J. Birgeneau , Z. -G. Ye , W. Chen , W. J. L. Buyers , P. M. Gehring , G. Shirane

We report a detailed high-resolution powder neutron diffraction investigation of the structural behaviour of the multiferroic hexagonal polymorph of YMnO3 between room temperature and 1403 K. The study was aimed at resolving previous…

材料科学 · 物理学 2015-05-19 Alexandra S. Gibbs , Kevin S. Knight , Philip Lightfoot

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

Structural phase transitions drive several unconventional phenomena including some illustrious ferroic attributes which are relevant for technological advancements. With this note, we have investigated the structural transition of…

BFO3 ceramics were investigated by means of infrared reflectivity and time domain THz transmission spectroscopy at temperatures 20 - 950 K, and the magnetodielectric effect was studied at 10 - 300 K, with the magnetic field up to 9 T. Below…

材料科学 · 物理学 2015-06-25 S. Kamba , D. Nuzhnyy , M. Savinov , J. Sebek , J. Petzelt , J. Prokleska , R. Haumont , J. Kreisel

We have investigated the dielectric properties of Gd$_{1-x}$Tb$_{x}$MnO$_{3}$ crystals in magnetic fields to clarify the crossover between two distinct ferroelectric phases, GdMnO$_{3}$-type (first-order displacive) and TbMnO$_{3}$-type…

强关联电子 · 物理学 2009-11-11 K. Noda , S. Nakamura , H. Kuwahara

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…