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A long-standing problem in quantum optimal control is finding an optimal pulse structure that leads to an efficient exploration of the unitary space with a minimal number of optimization parameters. We solve this problem by constructing…

We theoretically explore the precise control of a molecular polariton by strongly coupling the lowest three rotational states of a single molecule with a single-mode cavity. We examine two distinct cavity resonance configurations: a…

量子物理 · 物理学 2025-02-17 Li-Bao Fan , Hai-Ji Li , Qi Chen , Hang Zhou , Heng Liu , Chuan-Cun Shu

We discuss the commonly encountered problem when optimizing NMR pulses using optimal control that the otherwise very precise NMR theory does not provide as excellent agreement with experiments. We hypothesize that this disagreement is due…

We consider covariance control problems for nonlinear stochastic systems. Our objective is to find an optimal control strategy to steer the state from an initial distribution to a terminal one with specified mean and covariance. This…

系统与控制 · 电气工程与系统科学 2019-11-22 Zeji Yi , Zhefeng Cao , Evangelos Theodorou , Yongxin Chen

Structured decompositions of a desired unitary operator are employed to derive control schemes that achieve certain control objectives for finite-level quantum systems using only sequences of simple control pulses such as square waves with…

量子物理 · 物理学 2007-05-23 S. G. Schirmer , A. D. Greentree , V. Ramakrishna , H. Rabitz

A common way to manipulate a quantum system, for example spins or artificial atoms, is to use properly tailored control pulses. In order to accomplish quantum information tasks before coherence is lost, it is crucial to implement the…

In this article, we develop a numerical method to find optimal control pulses that accounts for the separation of timescales between the variation of the input control fields and the applied Hamiltonian. In traditional numerical…

量子物理 · 物理学 2011-09-19 F. Motzoi , J. M. Gambetta , S. T. Merkel , F. K. Wilhelm

The soft character of organic materials leads to strong coupling between molecular nuclear and electronic dynamics. This coupling opens the way to control charge transport in organic electronic devices by inducing molecular vibrational…

Within the Franck-Condon approximation, the single ionization of H$_2$ leaves H$_2^+$ in a coherent superposition of 19 nuclear vibrational states. We numerically design an optimal laser pulse train to transfer such a coherent nuclear wave…

光学 · 物理学 2015-06-15 Jun Zhang , Feng He

In many mechatronic applications, controller input costs are negligible and time optimality is of great importance to maximize the productivity by executing fast positioning maneuvers. As a result, the obtained control input has mostly a…

系统与控制 · 电气工程与系统科学 2025-01-28 Joe Ismail , Steven Liu

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

原子物理 · 物理学 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

Laser induced ultrafast demagnetization is the process whereby the magnetic moment of a ferromagnetic material is seen to drop significantly on a timescale of $10-100$s of femtoseconds due to the application of a strong laser pulse. If this…

材料科学 · 物理学 2016-01-20 P. Elliott , K. Krieger , J. K. Dewhurst , S. Sharma , E. K. U. Gross

Optimal pulse patterns (OPPs) are a modulation method in which the switching angles and levels of a switching signal are computed via an offline optimization procedure to minimize a performance metric, typically the harmonic distortions of…

系统与控制 · 电气工程与系统科学 2025-12-09 Jared Miller , Petros Karamanakos

Linear and nonlinear resonant states can be restrictive: they exist at particular discrete states in frequency and/or elasticity, under particular (e.g., simple-harmonic) waveforms. In forced oscillators, this restrictiveness is an obstacle…

系统与控制 · 电气工程与系统科学 2022-11-16 Arion Pons , Tsevi Beatus

Relaxation effects impose fundamental limitations on our ability to coherently control quantum mechanical phenomena. In this letter, we establish physical limits on how closely can a quantum mechanical system be steered to a desired target…

量子物理 · 物理学 2009-11-10 N. Khaneja , B. Luy , S. J. Glaser

Numerically optimised microwave pulses are used to increase excitation efficiency and modulation depth in electron spin resonance experiments performed on a spectrometer equipped with an arbitrary waveform generator. The optimisation…

化学物理 · 物理学 2018-10-19 David L. Goodwin , William K. Myers , Christiane R. Timmel , Ilya Kuprov

The shape of a few-cycle terahertz (THz) laser pulse can be optimized to provide control over conduction band populations in graphene. To demonstrate this control in a theoretical way, a spectral parametrization of the driving pulse using…

介观与纳米尺度物理 · 物理学 2018-12-31 Denis Gagnon , Joey Dumont , François Fillion-Gourdeau , Steve MacLean

Taking inspiration from NMR spectroscopy, periodic irradiation schemes have recently shown remarkable performance when implemented into pulsed dynamic nuclear polarization (DNP) sequences. This has prompted considerable interest in…

In recent experiments on ultracold matter, molecules have been produced from ultracold atoms by photoassociation, Feshbach resonances, and three-body recombination. The created molecules are translationally cold, but vibrationally highly…

量子物理 · 物理学 2007-05-23 Christiane P. Koch , José P. Palao , Ronnie Kosloff , Françoise Masnou-Seeuws

We evaluate the shifts imparted to vibrational and rotational levels of a linear molecule by a nonresonant laser field at intensities of up to 10^12 W/cm^2. Both types of shift are found to be either positive or negative, depending on the…

化学物理 · 物理学 2015-03-14 Mikhail Lemeshko , Bretislav Friedrich