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In this paper, we derive the Jarzynski equality (JE) for an isolated quantum system in three different cases: (i) the full evolution is unitary with no intermediate measurements, (ii) with intermediate measurements of arbitrary observables…

统计力学 · 物理学 2015-06-03 Shubhashis Rana , Sourabh Lahiri , A. M. Jayannavar

Most non-equilibrium processes in thermodynamics are quantified only by inequalities, however the Jarzynski relation presents a remarkably simple and general equality relating non-equilibrium quantities with the equilibrium free energy, and…

量子物理 · 物理学 2018-04-04 T. P. Xiong , L. L. Yan , F. Zhou , K. Rehan , D. F. Liang , L. Chen , W. L. Yang , Z. H. Ma , M. Feng , V. Vedral

The Jarzynski equality (JE) is known as an exact identity for nonequillibrium systems. The JE was originally formulated for isolated and isothermal systems, while Adib reported an JE extended to an isoenergetic process. In this paper, we…

统计力学 · 物理学 2015-05-27 Hitoshi Katsuda , Masayuki Ohzeki

The Jarzynski equality (JE) is analyzed in regard to its validity for both quasi-static transformations in the thermodynamic limit and Hamiltonian evolutions of the work protocol. In the first case, we show that the JE holds for isothermal…

统计力学 · 物理学 2020-05-15 Amilcare Porporato , Salvatore Calabrese

The past two decades witnessed important developments in the field of non-equilibrium statistical mechanics. Among these developments, the Jarzynski equality, being a milestone following the landmark work of Clausius and Kelvin, stands out.…

量子物理 · 物理学 2015-06-22 Shuoming An , Jing-Ning Zhang , Mark Um , Dingshun Lv , Yao Lu , Junhua Zhang , Zhang-qi Yin , H. T. Quan , Kihwan Kim

The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…

统计力学 · 物理学 2026-01-06 Dani R. Castellanos , Petr Jizba

The Jarzynski equality (JE), which relates works of non-equilibrium trajectories to the free energy difference of the initial and final states of the non-equilibrium process, provides an efficient way to calculate free energies of systems…

软凝聚态物质 · 物理学 2016-04-20 Biao Wan , Cheng Yang , Yanting Wang , Xin Zhou

A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…

统计力学 · 物理学 2009-10-31 Satoshi Yukawa

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum…

量子物理 · 物理学 2020-08-10 Akira Sone , Yi-Xiang Liu , Paola Cappellaro

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two…

The well-known Jarzynski equality, often written in the form $e^{-\beta\Delta F}=\langle e^{-\beta W}\rangle$, provides a non-equilibrium means to measure the free energy difference $\Delta F$ of a system at the same inverse temperature…

统计力学 · 物理学 2017-08-22 Jiawen Deng , Juan D. Jaramillo , Peter Hanggi , Jiangbin Gong

We combine the formalisms of diagonal entropy and Jarzynski Equality to study the thermodynamic properties of closed quantum systems. Applying this approach to a quantum harmonic oscillator, the diagonal entropy offers a notion of…

量子物理 · 物理学 2013-07-09 Van A. Ngo , Stephan Haas

We study the statistics of energy fluctuations in a three-level quantum system subject to a sequence of projective quantum measurements. We check that, as expected, the quantum Jarzynski equality holds provided that the initial state is…

量子物理 · 物理学 2020-03-25 Guido Giachetti , Stefano Gherardini , Andrea Trombettoni , Stefano Ruffo

Exact results for the Jarzynski equality are derived for Ising spin glass models. The Jarzynski equality is an equality that connects the work in nonequilibrium and the difference between free energies. The work is performed in switching an…

无序系统与神经网络 · 物理学 2012-03-30 Chiaki Yamaguchi

The nonequilibrium work relation, or Jarzynski equality, establishes a statistical relationship between a series of nonequilibrium experiments on a system subjected to thermal fluctuations and a hypothetical experiment at thermodynamic…

统计力学 · 物理学 2024-11-19 Jean-Luc Garden

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

统计力学 · 物理学 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

统计力学 · 物理学 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

Jarzynski's equality (JE) allows us to compute free energy differences from distributions of work. In molecular dynamics simulations, the traditional way of constructing work distributions is to perform as many pulling simulations as…

计算物理 · 物理学 2012-05-07 Van Ngo

The central quantity in the celebrated quantum Jarzynski equality is $e^{-\beta W}$, where $W$ is work and $\beta$ is the inverse temperature. The impact of quantum randomness on the fluctuations of $e^{-\beta W}$ and hence on the…

量子物理 · 物理学 2023-10-24 Wei Cheng , Wenquan Liu , Yang Wu , Zhibo Niu , Chang-Kui Duan , Jiangbin Gong , Xing Rong , Jiangfeng Du
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