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Understanding the response of the surface of metallic solids to external electric field sources is crucial to characterize electrode-electrolyte interfaces. Continuum electrostatics offer a simple description of the induced charge density…

化学物理 · 物理学 2021-12-14 Giovanni Pireddu , Laura Scalfi , Benjamin Rotenberg

Surface waves on a liquid air interface excited by a vertical vibration of a fluid layer (Faraday waves) are employed to investigate the phase relaxation of ideally ordered patterns. By means of a combined frequency-amplitude modulation of…

斑图形成与孤子 · 物理学 2009-11-07 A. V. Kityk , C. Wagner , K. Knorr , H. W. Mueller

Continuum electrolyte models represent a practical tool to account for the presence of the diffuse layer at electrochemical interfaces. However, despite the increasing popularity of these in the field of materials science it remains unclear…

计算物理 · 物理学 2019-01-18 Francesco Nattino , Matthew Truscott , Nicola Marzari , Oliviero Andreussi

In this work we theoretically study the differential capacitance of an aqueous electrolyte in contact with a planar electrode, using classical Density Functional Theory, and show how this measurable quantity can be used as a probe to better…

软凝聚态物质 · 物理学 2021-09-16 Peter Cats , René van Roij

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions we consider the so-called civilized model, in which all species present are treated…

软凝聚态物质 · 物理学 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

Graphene's structure bears on both the material's electronic properties and fundamental questions about long range order in two-dimensional crystals. We present an analytic calculation of selected area electron diffraction from multi-layer…

介观与纳米尺度物理 · 物理学 2015-03-20 Brian Shevitski , Matthew Mecklenburg , William A. Hubbard , E. R. White , Ben Dawson , M. S. Lodge , Masa Ishigami , B. C. Regan

Conducting Polymer Dendrites (CPD) are truly inspiring for unconventional electronics that shapes topological circuitries evolving upon an application. Driven by electrochemical processes, an electrochemical impedance rules signal…

应用物理 · 物理学 2024-07-02 Antoine Baron , Enrique Hernández-Balaguera , Sébastien Pecqueur

The electrical double layer (EDL) is fundamental to the operation of devices for electrochemical energy storage and conversion. Existing models of EDL in solid electrolytes focus predominantly on the space charge layer and lack a complete…

材料科学 · 物理学 2025-08-12 Zeeshan Ahmad

We use Monte Carlo simulations to examine the simplest model of an ionic liquid, called the restricted primitive model, at a metal surface. We find that at moderately low temperatures the capacitance of the metal/ionic liquid interface is…

化学物理 · 物理学 2010-11-19 M. S. Loth , Brian Skinner , B. I. Shklovskii

Using molecular dynamics simulations, we reveal emergent properties of hydrated electrode interfaces that while molecular in origin are integral to the behavior of the system across long times scales and large length scales. Specifically,…

材料科学 · 物理学 2015-05-20 David T. Limmer , Adam P. Willard

Quantum energy teleportation (QET) is a proposed protocol related to the quantum vacuum. The edge channels in a quantum Hall system is well suited for the experimental verification of QET. For this purpose, we examine a charge density wave…

介观与纳米尺度物理 · 物理学 2018-03-14 Masahiro Matsuura , Takaaki Mano , Takeshi Noda , Naokazu Shibata , Masahiro Hotta , Go Yusa

The electric double layer (EDL) that forms at the interface between a polyelectrolyte gel and a salt bath is studied using asymptotic and numerical methods. Specifically, matched asymptotic expansions, based on the smallness of the Debye…

软凝聚态物质 · 物理学 2022-01-28 Matthew G. Hennessy , Giulia L. Celora , Andreas Münch , Barbara Wagner , Sarah L. Waters

Surface electronic properties of undoped hydrogen terminated diamond covered with adsorbates or in electrolyte solutions are summarized. The formation of a conductive layer at the surface of diamond is discussed based on Hall effect,…

材料科学 · 物理学 2020-05-11 Christoph E. Nebel

High impedance connecting links and cables are modeled at low frequency in terms of their impedance to ground and to neigbouring connecting links. The impedance is usually considered to be the parallel combination of a resistance and a…

仪器与探测器 · 物理学 2013-07-18 Andrea Giachero , Claudio Gotti , Matteo Maino , Gianluigi Pessina

Electrostatic interactions between point charges embedded into interfaces separating dielectric media are omnipresent in soft matter systems and often control their stability. Such interactions are typically complicated and do not resemble…

软凝聚态物质 · 物理学 2020-09-09 Alexander Morozov , Iain Muntz , Job H. J. Thijssen , Davide Marenduzzo

The finding of droplet-based electricity generator (DEG), based on the moving boundary of electrical double layer, has triggered great research enthusiasm, and a breakthrough in instantaneous electric power density was achieved recently.…

材料科学 · 物理学 2020-09-15 Xiang Wang , Sunmiao Fang , Jin Tan , Tao Hu , Weicun Chu , Jun Yin , Jianxin Zhou , Wanlin Guo

We present an improved approach to the impedance spectroscopy of conductive liquid samples using four-electrode measurements. Our method enables impedance measurements of conductive liquids down to the sub-Hertz frequencies, avoiding the…

软凝聚态物质 · 物理学 2011-07-28 Damjan Pelc , Sanjin Marion , Mario Basletic

A theoretical analysis of Coulomb systems on lattices in general dimensions is presented. The thermodynamics is developed using Debye-Huckel theory with ion-pairing and dipole-ion solvation, specific calculations being performed for 3D…

统计力学 · 物理学 2009-11-07 Vladimir Kobelev , Anatoly B. Kolomeisky , Michael E. Fisher

Using molecular dynamics simulations with recently developed importance sampling methods, we show that the differential capacitance of a model ionic liquid based double-layer capacitor exhibits an anomalous dependence on the applied…

Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode-surface film interface in response to the voltage, which adds complexity to…

材料科学 · 物理学 2015-07-10 Kevin Leung , Andrew Leenheer