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The demonstration of strong and ultrastrong coupling regimes of cavity QED with polyatomic molecules has opened new routes to control chemical dynamics at the nanoscale. We show that strong resonant coupling of a cavity field with an…

量子物理 · 物理学 2016-06-09 Felipe Herrera , Frank C. Spano

Cavity polaritonics is capturing the imagination of the chemistry community because of the novel opportunities it creates to direct chemistry. Electron transfer (ET) reactions are among the simplest reactions, and they also underpin…

量子物理 · 物理学 2022-08-12 Sutirtha N. Chowdhury , Peng Zhang , David N. Beratan

The ground-state properties and excitation energies of a quantum emitter can be modified in the ultrastrong coupling regime of cavity quantum electrodynamics (QED) where the light-matter interaction strength becomes comparable to the cavity…

介观与纳米尺度物理 · 物理学 2023-05-30 Yuto Ashida , Atac Imamoglu , Eugene Demler

Cavity quantum electrodynamics (QED), the study of the interaction between quantized emitters and photons confined in an optical cavity, is an important tool for quantum science in computing, networking, and synthetic matter. In atomic…

Cavity quantum electrodynamics (QED) manipulates the coupling of light with matter, and allows for several emitters to couple coherently with one light mode. However, even in a many-body system, the light-matter coupling mechanism was so…

量子气体 · 物理学 2021-11-10 Hideki Konishi , Kevin Roux , Victor Helson , Jean-Philippe Brantut

Here we present a fundamental study on how the ground-state chemical reactivity of a molecule can be modified in a QED scenario, i.e., when it is placed inside a cavity and there is strong coupling between the cavity field and vibrational…

量子物理 · 物理学 2019-06-25 Javier Galego , Clàudia Climent , Francisco J. Garcia-Vidal , Johannes Feist

Plasmonic nanocavities are a promising platform for strong light-matter coupling and enhanced spectroscopies at the single-molecule level. These nanoscale environments are challenging to model due to their strongly multimodal character and…

化学物理 · 物理学 2026-03-16 Jonathan H. Fetherolf , Tao E. Li , Sharon Hammes-Schiffer

Achieving control over chemical reaction's rate and stereoselectivity realizes one of the Holy Grails in chemistry that can revolutionize chemical and pharmaceutical industries. Strong light-matter interaction in optical or nanoplasmonic…

化学物理 · 物理学 2022-11-29 Fabijan Pavošević , Robert L. Smith , Angel Rubio

We develop a rigorous theoretical framework for interaction-induced phenomena in the waveguide quantum electrodynamics (QED) driven by mechanical oscillations of the qubits. Specifically, we predict that the simplest set-up of two qubits,…

介观与纳米尺度物理 · 物理学 2020-11-04 Ivan Iorsh , Alexander Poshakinskiy , Alexander Poddubny

Waveguide quantum electrodynamics (wQED) has become a central platform for studying collective light-matter interactions in low-dimensional photonic environments. While conventional wQED systems rely on uniform chirality or reciprocal…

量子物理 · 物理学 2026-04-07 I Gusti Ngurah Yudi Handayana , Ya-Tang Yu , Wei-Hsuan Chung , H. H. Jen

A reduced-density-matrix (RDM)-based approach to {\em ab initio} cavity quantum electrodynamics (QED) is developed. The expectation value of the Pauli-Fierz Hamiltonian is expressed in terms of one- and two-body electronic and photonic…

化学物理 · 物理学 2022-11-23 Joel D. Mallory , A. Eugene DePrince

Proton transfer is ubiquitous in many fundamental chemical and biological processes, and the ability to modulate and control the proton transfer rate would have a major impact on numerous quantum technological advances. One possibility to…

化学物理 · 物理学 2021-12-07 Fabijan Pavošević , Sharon Hammes-Schiffer , Angel Rubio , Johannes Flick

Waveguide quantum electrodynamics (wQED) with underlying collective and long-range atom-atom interactions has led to many distinct dynamical phenomena, including modified collective radiations and intriguing quantum correlations. It stands…

量子物理 · 物理学 2026-03-24 Ya-Tang Yu , I Gusti Ngurah Yudi Handayana , Wei Chen , H. H. Jen

Understanding physical properties of quantum emitters strongly interacting with quantized electromagnetic modes is one of the primary goals in the emergent field of waveguide quantum electrodynamics (QED). When the light-matter coupling…

量子物理 · 物理学 2023-05-30 Yuto Ashida , Takeru Yokota , Atac Imamoglu , Eugene Demler

Cavity quantum electrodynamics (cQED) harnesses light-matter interactions to produce nonclassical light states. However, a fundamental challenge lies in simultaneously achieving Purcell enhancement and tailored wavefront control within a…

Cavity quantum electrodynamics (cavity QED) describes the coherent interaction between matter and an electromagnetic field confined within a resonator structure, and is providing a useful platform for developing concepts in quantum…

The creation of light-matter hybrid states, polaritons, in a cavity offers new intriguing opportunities to manipulate the electronic structure and electron dynamics of atoms and molecules. Here, we investigate the effect of electronic…

量子物理 · 物理学 2025-07-30 Paul A. Albrecht , Eric W. Fischer , Tillmann Klamroth , Peter Saalfrank

Condensed matter physics and quantum electrodynamics (QED) have been long considered as distinct disciplines. This situation is changing by the progress in cavity QED materials. Motivated by these advances we aim to bridge these fields by…

量子物理 · 物理学 2022-01-06 Vasil Rokaj

We develop a quantum description of the resonant interaction between electromagnetic (EM) and gravitational waves (GW). We first show that Lorentz invariance together with polarization selection rules forbids any photon-graviton mixing in…

量子物理 · 物理学 2026-03-31 Fateme Shojaei Arani , Brahim Lamine , Jiro Soda

Strong light-matter coupling within an optical cavity leverages the collective interactions of molecules and confined electromagnetic fields, giving rise to the possibilities of modifying chemical reactivity and molecular properties. While…

化学物理 · 物理学 2025-05-29 Shravan Kumar Sharma , Hsing-Ta Chen
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